Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
352 words
A siloxane copolymer having alkenyl groups and contains (a) siloxane units of the formula ##STR13## in which R is selected from the group consisting of hydrocarbon radicals having from 1 to 18 carbon atom(s) per radical and halogenated hydrocarbon radicals having from 1 to 18 carbon atom(s) per radical, R 1 is an alkyl radical having from 1 to 4 carbon atom(s) per radical which can be substituted by an ether oxygen atom; a is 0, 1, 2 or 3; b is 0, 1, or 3; and the sum of a+b is not greater than 3; (b) at least one siloxane unit per molecule of the formula ##STR14## in which R is the same as above, c is 0, 1 or 2, G is a radical of the formula --CH.sub.2 CHR.sup.2 CHR.sup.2 OY(OCHR.sup.2 CR.sup.2 ═CH.sub.2).sub.x-1 in which R 2 is selected from the group consisting of a hydrogen atom and a methyl radical; Y is a trivalent, tetravalent, pentavalent or hexavalent hydrocarbon radical which has from 2 to 20 carbon atoms per radical which can be substituted by groups of the formula --OH; --OCR 3 ; --OSiR 4 3 ; ##STR15## or --X; or can be interrupted by at least one oxygen atom or sulfur atom or one carbonyl group, or Y represents a trivalent radical of the formula .tbd.P, .tbd.P═O or SiR.sup.5, in which R 3 is an alkyl radical having from 1 to 6 carbon atom(s) per radical, R 4 is selected from the group consisting of a methyl, ethyl, isopropyl, tert-butyl and phenyl radical, X is a halogen atom and R 5 is a monovalent hydrocarbon radical having from 1 to 8 carbon atoms(s) per radical, or Y represents a tetravalent element selected from the group consisting of ##STR16## and x is 3, 4, 5 or 6, and optionally (c) at least one unit per molecule selected from the group consisting of units of the formulas ##STR17## in which R and c are the same as above, G 1 is a radical of the formula ##STR18## in which R 2 , Y and x are the same as above.
Claim 2
Dependent Claim
352 words
A siloxane copolymer having alkenyl groups and contains (a) siloxane units of the formula ##STR13## in which R is selected from the group consisting of hydrocarbon radicals having from 1 to 18 carbon atom(s) per radical and halogenated hydrocarbon radicals having from 1 to 18 carbon atom(s) per radical, R 1 is an alkyl radical having from 1 to 4 carbon atom(s) per radical which can be substituted by an ether oxygen atom; a is 0, 1, 2 or 3; b is 0, 1, or 3; and the sum of a+b is not greater than 3; (b) at least one siloxane unit per molecule of the formula ##STR14## in which R is the same as above, c is 0, 1 or 2, G is a radical of the formula --CH.sub.2 CHR.sup.2 CHR.sup.2 OY(OCHR.sup.2 CR.sup.2 ═CH.sub.2).sub.x-1 in which R 2 is selected from the group consisting of a hydrogen atom and a methyl radical; Y is a trivalent, tetravalent, pentavalent or hexavalent hydrocarbon radical which has from 2 to 20 carbon atoms per radical which can be substituted by groups of the formula --OH; --OCR 3 ; --OSiR 4 3 ; ##STR15## or --X; or can be interrupted by at least one oxygen atom or sulfur atom or one carbonyl group, or Y represents a trivalent radical of the formula .tbd.P, .tbd.P═O or SiR.sup.5, in which R 3 is an alkyl radical having from 1 to 6 carbon atom(s) per radical, R 4 is selected from the group consisting of a methyl, ethyl, isopropyl, tert-butyl and phenyl radical, X is a halogen atom and R 5 is a monovalent hydrocarbon radical having from 1 to 8 carbon atoms(s) per radical, or Y represents a tetravalent element selected from the group consisting of ##STR16## and x is 3, 4, 5 or 6, and optionally (c) at least one unit per molecule selected from the group consisting of units of the formulas ##STR17## in which R and c are the same as above, G 1 is a radical of the formula ##STR18## in which R 2 , Y and x are the same as above.
Claim 3
Dependent Claim
44 words
The siloxane copolymer of claim 1, which contains siloxane units of formula (I), at least one siloxane unit of formula (II) per molecule and at least one unit selected from the group consisting of units of the formulas (III), (IV) and (V) per molecule.
Claim 4
Dependent Claim
265 words
The siloxane copolymer of claim 1, which contains (a) siloxane units of the formula R.sub.2 SiO (I'), (b) at least two siloxane units of the formula per molecule GR.sub.2 SiO.sub.1/2 (II') and (c) at least one unit of the formula O.sub.1/2 R.sub.2 SiG.sup.1 SiR.sub.2 O.sub.178 (III') per molecule in which R is selected from the group consisting of hydrocarbon radicals having from 1 to 18 carbon atom(s) per radical and halogenated hydrocarbon radicals having from 1 to 18 carbon atom(s) per radical, G is a radical of the formula --CH.sub.2 CHR.sup.2 CHR.sup.2 OY(OCHR.sup.2 CR.sup.2 ═CH.sub.2).sub.x-1 G 1 is a radical of the formula ##STR19## which R 2 is selected from the group consisting of a hydrogen atom and a methyl radical, x is 3, 4, 5 or 6 and Y is a trivalent, tetravalent, pentavalent or hexavalent hydrocarbon radical which has 2 to 20 carbon atoms per radical which can be substituted by groups of the formula --OH, --OR 3 , --OSiR 4 3 , ##STR20## or --X, or can be interrupted by at least one oxygen atom or sulfur atom or one carbonyl group, or Y represents a trivalent radical of the formula .tbd.P, .tbd.P═O or .tbd.SiR.sup.5 , R 3 is an alkyl radical having from 1 to 6 carbon atom(s) per radical, R 4 is selected from the group consisting of a methyl, ethyl, isopropyl, tert-butyl and phenyl radical, X is a halogen atom and R 5 a monovalent hydrocarbon radical having from 1 to 8 carbon atom(s) per radical, or Y represents a tetravalent element selected from the group consisting of ##STR21##
Claim 5
Dependent Claim
266 words
The siloxane copolymer of claim 2, which contains (a) siloxane units of the formula R.sub.2 SiO (I'), (b) at least two siloxane units of the formula per molecule GR.sub.2 SiO.sub.1/2 (II') and (c) at least one unit of the formula O.sub.1/2 R.sub.2 SiG.sup.1 SiR.sub.2 O.sub.178 (III') per molecule in which R is selected from the group consisting of hydrocarbon radicals having from 1 to 18 carbon atom(s) per radical and halogenated hydrocarbon radicals having from 1 to 18 carbon atom(s) per radical, G is a radical of the formula --CH.sub.2 CHR.sup.2 CHR.sup.2 OY(OCHR.sup.2 CR.sup.2 ═CH.sub.2).sub.x-1 G1 is a radical of the formula ##STR22## in which R 2 is selected from the group consisting of a hydrogen atom and a methyl radical, x is 3, 4, 5 or 6 and Y is a trivalent, tetravalent, pentavalent or hexavalent hydrocarbon radical which has 2 to 20 carbon atoms per radical which can be substituted by groups of the formula --OH, --OR 3 , --OSiR 4 3 , ##STR23## or --X, or can be interrupted by at least one oxygen atom or sulfur atom or one carbonyl group, or Y represents a trivalent radical of the formula .tbd.P, .tbd.P═O or .tbd.SiR.sup.5 , R 3 is an alkyl radical having from 1 to 6 carbon atom(s) per radical, R 4 is selected from the group consisting of a methyl, ethyl, isopropyl, tert-butyl and phenyl radical, X is a halogen atom and R 5 is a monovalent hydrocarbon radical having from 1 to 8 carbon atom(s) per radical, or Y represents a tetravalent element selected from the group consisting of ##STR24##
Claim 6
Dependent Claim
289 words
A process for preparing the siloxane copolymer of claim 1, which comprises reacting an organic compound (1) containing more than two aliphatic double bonds, of the general formula Y(OCHR.sup.2 CR.sup.2 ═CH.sub.2).sub.x in which R 2 is selected from the group consisting of a hydrogen atom and a methyl radical, x is 3, 4, 5 or 6 and Y is a trivalent, tetravalent, pentavalent or hexavalent hydrocarbon radical which has from 2 to 20 carbon atoms per radical and can be substituted by groups of the formula --OH, --OR 3 , --OSiR 4 3 , ##STR25## or --X, or can be interrupted by at least one oxygen atom or sulfur atom or one carbonyl group, or Y represents a trivalent radical of the formula .tbd.P, .tbd.P═O or .tbd.SiR.sup.5 , in which R 3 is an alkyl radical having from 1 to 6 carbon atom(s) per radical, R 4 is selected from the group consisting of a methyl, ethyl, isopropyl, tert butyl and phenyl radical, X is a halogen atom and R5 is a monovalent hydrocarbon radical having from 1 to 8 carbon atom(s) per radical, or Y represents a tetravalent element selected from the group consisting of ##STR26## an organopolysiloxane (2) containing at least one Si-bonded hydrogen atom per molecule in the presence of a catalyst (3) which promotes the addition of Si-bonded hydrogen to an aliphatic double bond, in which the ratio of the aliphatic double bond in the organic compound (1) to the Si-bonded hydrogen in the organopolysiloxane (2) is such that siloxane copolymers are formed which contain alkenyl groups having an average of more than two alkenyl groups of the formula --OCHR 2 CR 2 ═CH 2 , in which R 2 is the same as above.
Claim 7
Dependent Claim
289 words
A process for preparing the siloxane copolymer of claim 2, which comprises reacting an organic compound (1) containing more than two aliphatic double bonds of the general formula Y(OCHR.sup.2 CR.sup.2 ═CH.sub.2).sub.x in which R 2 is selected from the group consisting of a hydrogen atom and a methyl radical, x is 3, 4, 5 or 6 and Y is a trivalent, tetravalent, pentavalent or hexavalent hydrocarbon radical which has from 2 to 20 carbon atoms per radical and can be substituted by groups of the formula --OH, --OR 3 , --OSiR 4 3 , ##STR27## or --X, or can be interrupted by at least one oxygen atom or sulfur atom or one carbonyl group, or Y represents a trivalent radical of the formula .tbd.P, .tbd.P═O or .tbd.SiR.sup.5 , in which R 3 is an alkyl radical having from 1 to 6 carbon atom(s) per radical, R 4 is selected from the group consisting of a methyl, ethyl, isopropyl, tert-butyl and phenyl radical, X is a halogen atom and R 5 is a monovalent hydrocarbon radical having from 1 to 8 carbon atom(s) per radical or Y represents a tetravalent element selected from the group consisting of ##STR28## an organopolysiloxane (2) containing at least one Si-bonded hydrogen atom per molecule in the presence of a catalyst (3) which promotes the addition of Si-bonded hydrogen to an aliphatic double bond, in which the ratio of the aliphatic double bond in the organic compound (1) to the Si-bonded hydrogen in the organopolysiloxane (2) is such that siloxane copolymers are formed which contain alkenyl groups having an average of more than two alkenyl groups of the formula --OCHR 2 CR 2 ═CH 2 , in which R 2 is the same as above.
Claim 8
Dependent Claim
52 words
The process of claim 5, wherein the organic compound (1) is selected from the group consisting of tetraallyloxyethane and a compound of the formula (R.sup.6 OCH.sub.2).sub.4-k C(CH.sub.2 OCH.sub.2 CH═CH.sub.2).sub.k in which R 6 is selected from the group consisting of hydrogen and a radical of the formula ##STR29## and k is 3.
Claim 9
Dependent Claim
92 words
The process of claim 5, wherein the organopolysiloxane (2) having at least one Si-bonded hydrogen atom per molecule is of the general formula H.sub.d R.sub.3-d SiO(SiR.sub.2 O).sub.o (SiRHO).sub.p SiR.sub.3-d H.sub.d(VII) in which R is selected from the group consisting of hydrocarbon radicals having from 1 to 18 carbon atom(s) per radical and halogenated hydrocarbon radicals having from 1 to 18 carbon atom(s) per radical; d is 0 or 1; o is 0 or an integer of from 1 to 1000; and p is 0 or an integer of from 1 to 6.
Claim 10
Dependent Claim
46 words
The process of claim 5, wherein the resulting siloxane copolymer containing alkenyl groups is equilibrated with an organopolysiloxane (4) selected from the group consisting of linear organopolysiloxanes containing terminal triorganosiloxy groups, linear organopolysiloxanes containing terminal hydroxyl groups, cyclic organopolysiloxanes and copolymers of diorganosiloxane and monoorganosiloxane units.
Claim 11
Dependent Claim
36 words
A composition comprising (A) the siloxane copolymer containing alkenyl groups of claim 1; (B) an organopolysiloxane containing Si-bonded hydrogen atoms; and (C) a catalyst which promotes the addition of Si-bonded hydrogen to an aliphatic double bond.
Claim 12
Dependent Claim
36 words
A composition comprising (A) the siloxane copolymer containing alkenyl groups of claim 2; (B) an organopolysiloxane containing Si-bonded hydrogen atoms; and (C) a catalyst which promotes the addition of Si-bonded hydrogen to an aliphatic double bond.
Claim 13
Dependent Claim
36 words
A composition comprising (A) the siloxane copolymer containing alkenyl groups of claim 3; (B) an organopolysiloxane containing Si-bonded hydrogen atoms; and (C) a catalyst which promotes the addition of Si-bonded hydrogen to an aliphatic double bond.
Claim 14
Dependent Claim
18 words
A coating composition which repels tacky substances which comprises applying the composition of claim 10 to a substrate.