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US5159075A Expired / Lapsed US ⏱️ 0.0 years remaining

Substituted chlorotriazines useful for reactive capping of polyphenylene ethers

Assignee: General Electric Co
•
Filing: 1991-02-11
•
Granted: 1992-10-27
•
Expires: 2011-02-11
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Abstract

Abstract Substituted alkoxy- or alkylthiochlorotriazines wherein the substituents on the alkoxy groups are chlorine, bromine or dialkylphosphato are useful as capping agents for polyphenylene ethers. The capped polyphenylene ethers form copolymers with other polymers containing nucleophilic groups, including polyesters, polyamides and functionalized olefin polymers. Such copolymers serve as compatibilizers in the formation of blends having high impact strength.

Inventors

  • 👤 Otto Phanstiel
  • 👤 Sterling B. Brown

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 10:43
CPC Classifications
C; C08; C08G; C08G65/00; C08G65/34; C08G65/48; C08G65/485; C07; C07D; C07D251/00; C07D251/02; C07D251/12; C07D251/26; C08L; C08L71/00; C08L71/08; C08L71/10; C08L71/12; C08L71/126; C08L67/00; C08L71/02; C08L71/03; C08L75/00; C08L77/00; C08L81/00; C08L81/04

Claims Analysis

Total Claims: 26
Claim 1
Independent Claim 138 words
A substituted alkoxy- or alkylthiochlorotriazine having the formula ##STR13## wherein: X 1 is an alkyl, cycloalkyl or aromatic radical or ##STR14## X 2 is chlorine, bromine or ##STR15## wherein each R 4 is a C 1-30 primary or secondary alkyl, aromatic or alkaryl radical or both R 4 radicals together with the P and Z atoms form a cyclic structure; each Z is independently oxygen or sulfur; each R 1 is independently hydrogen or C 1-4 primary or secondarly alkyl; R 2 is a C 1-3 alkylene radical which is unsubstituted or is substituted with moieties selected from the group consisting of C 1-4 primary or secondary alkyl radicals and non-hydrocarbon substituents as defined for R 1 ; each R 3 is independently R 1 or X 2 ; m is 0 or 1; and n is 1-3.
Claim 2
Dependent Claim 138 words
A substituted alkoxy- or alkylthiochlorotriazine having the formula ##STR13## wherein: X 1 is an alkyl, cycloalkyl or aromatic radical or ##STR14## X 2 is chlorine, bromine or ##STR15## wherein each R 4 is a C 1-30 primary or secondary alkyl, aromatic or alkaryl radical or both R 4 radicals together with the P and Z atoms form a cyclic structure; each Z is independently oxygen or sulfur; each R 1 is independently hydrogen or C 1-4 primary or secondarly alkyl; R 2 is a C 1-3 alkylene radical which is unsubstituted or is substituted with moieties selected from the group consisting of C 1-4 primary or secondary alkyl radicals and non-hydrocarbon substituents as defined for R 1 ; each R 3 is independently R 1 or X 2 ; m is 0 or 1; and n is 1-3.
Claim 3
Dependent Claim 17 words
A substitutes chlorotriazine according to claim 1 wherein X 1 is an alkyl, cycloalkyl or aromatic radical.
Claim 4
Dependent Claim 15 words
A substituted chlorotriazine according to claim 2 wherein m is 0 and n is 1.
Claim 5
Dependent Claim 12 words
A substituted chlorotriazine according to claim 3 wherein each Z is oxygen.
Claim 6
Dependent Claim 13 words
A substituted chlorotriazine according to claim 4 wherein each R 3 is hydrogen.
Claim 7
Dependent Claim 13 words
A substituted chlorotriazine according to claim 5 wherein each R 1 is hydrogen
Claim 8
Dependent Claim 18 words
A substituted chlorotriazine according to claim 6 wherein X 1 is a primary or secondary lower alkyl radical.
Claim 9
Dependent Claim 19 words
A substituted chlorotriazine according to claim 6 wherein X 1 is a monocyclic aromatic radical containing 6-10 carbon atoms.
Claim 10
Dependent Claim 12 words
A substituted chlorotriazine according to claim 7 wherein X 1 is 2,4,6-trimethylphenyl.
Claim 11
Dependent Claim 12 words
A substituted chlorotriazine according to claim 8 wherein X 1 is 2,6-xylyl.
Claim 12
Dependent Claim 12 words
A substituted chlorotriazine according to claim 6 wherein X 2 is chlorine.
Claim 13
Dependent Claim 12 words
A substituted chlorotriazine according to claim 6 wherein X 2 is bromine.
Claim 14
Dependent Claim 12 words
A substituted chlorotriazine according to claim 6 wherein X 2 is ##STR16##
Claim 15
Dependent Claim 15 words
A substituted chlorotriazine according to claim 13 wherein R 4 is C 1-4 primary alkyl.
Claim 16
Dependent Claim 12 words
A substituted chlorotriazine according to claim 14 wherein R 4 is n-butyl.
Claim 17
Dependent Claim 33 words
2-Chloro-4-(2-chloroethoxy)-6-(2,4,6-trimethylphenoxy)-1,3,5-triazine, the compound of formula I wherein R 1 and R 3 are each hydrogen, X 1 is 2,4,6-trimethylphenyl, X 2 is chlorine, Z is oxygen, m is 0 and n is 1.
Claim 18
Dependent Claim 33 words
2-Chloro-4-(2-chloroethoxy)-6-(2,4,6-trimethylphenoxy)-1,3,5-triazine, the compound of formula I wherein R 1 and R 3 are each hydrogen, X 1 is 2,4,6-trimethylphenyl, X 2 is chlorine, Z is oxygen, m is 0 and n is 1.
Claim 19
Dependent Claim 1 words
2-Chloro-4-(2-chloroethoxy)-6-(2,4,6-trimethylphenoxy)-1,3,5-triazine.
Claim 20
Dependent Claim 1 words
2-Chloro-4-(2-chloroethoxy)-6-(2,4,6-trimethylphenoxy)-1,3,5-triazine.
Claim 21
Dependent Claim 1 words
2-Chloro-4-(2-chloroethoxy)-6-(2,4,6-trimethylphenoxy)-1,3,5-triazine.
Claim 22
Dependent Claim 1 words
2-Chloro-4-(2-chloroethoxy)-6-(2,4,6-trimethylphenoxy)-1,3,5-triazine.
Claim 23
Dependent Claim 1 words
2-Chloro-4-(2-chloroethoxy)-6-(2,4,6-trimethylphenoxy)-1,3,5-triazine
Claim 24
Dependent Claim 1 words
2-Chloro-4-(2-chloroethoxy)-6-(2,4,6-trimethylphenoxy)-1,3,5-triazine
Claim 25
Dependent Claim 1 words
2-Chloro-4-(2-chloroethoxy)-6-(2,4,6-trimethylphenoxy)-1,3,5-triazine.
Claim 26
Dependent Claim 1 words
2-Chloro-4-(2-chloroethoxy)-6-(2,4,6-trimethylphenoxy)-1,3,5-triazine.

References Cited (Backward Citations)

US4407748A Cited
US4895945A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-10-27 1996-04-27 1996-10-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-10-27 2000-04-27 2000-10-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-10-27 2004-04-27 2004-10-27 $7700.00 Window Closed / Lapsed

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