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US5156677A Expired / Lapsed US ⏱️ 0.0 years remaining

Treatment of aluminum flake pigment for use in organic coating compositions

Assignee: BASF Corp
•
Filing: 1992-05-15
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Granted: 1992-10-20
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Expires: 2012-05-15
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Abstract

Abstract A compound is described that is useful for metal surface modification, particularly aluminum flake pigment surface modification, having the formula: ##STR1## where X, R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , D 1 , D 2 , D 3 , j, k, m, and n are as defined herein. A method for surface modification of a metallic flake pigment with the compound and compositions containing the surface modified metallic flake pigment is also described.

Inventors

  • 👤 Clint W. Carpenter
  • 👤 Lynne G. Bemer
  • 👤 Glenn E. Martin

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 00:29
CPC Classifications
C; C09; C09D; C09D5/00; C09D5/38; C09C; C09C1/00; C09C1/62; C09C1/64; C09C1/644; C09C1/646; C09C3/00; C09C3/08; C09C3/12; C09D17/00; C09D17/004; C09D7/00; C09D7/40; C09D7/45; C01; C01P; C01P2004/00; C01P2004/20; C01P2004/60; C01P2004/61; C01P2004/80; C01P2004/82; C01P2004/84; C01P2006/00; C01P2006/12; C01P2006/22; C01P2006/80; C01P2006/90

Claims Analysis

Total Claims: 26
Claim 1
Independent Claim 291 words
A composition, comprising a metal surface modified with at least one compound; wherein the compound is of the formula: ##STR12## wherein A 1 , A 2 , A 3 , and A 4 are each independently hydroxy, alkyl of one to ten carbon atoms, alkoxy of one to ten carbon atoms, alkoxyalkoxy of two to ten carbon atoms, alkanoyloxy of two to ten carbon atoms, or halogen, with the proviso that A 1 , A 2 , and A 3 may not all be alkyl; R 1 is a divalent radical selected from straight or branched alkylenes of one to twelve carbon atoms; D 1 is either a divalent radical selected from the group consisting of --O--, --NA 5 --, and --S--, or a trivalent radical of the formula ##STR13## wherein A 5 , A 6 , A 7 and A 8 are each independently hydrogen or alkyl of one to twelve carbon atoms; R 2 is hydrogen or a covalent bond with D 1 , with the proviso that R 2 is only a covalent bond with D 1 when D 1 is a trivalent radical; R 3 is a polymeric backbone; D 2 and D 3 are divalent radicals, each independently --O-- or --NA 9 --, wherein A 9 is hydrogen or alkyl of one to twelve carbon atoms; R 4 is a divalent radical selected from straight or branched alkylenes of three to thirty carbon atoms; R 5 is hydrogen or a mixture of hydrogen and alkyl of one to eight carbon atoms; R 6 is an alkyl of one to thirty carbon atoms; m and n are integers, each independently being one to one thousand, and j and k are integers, each independently being one to fifty.
Claim 2
Dependent Claim 291 words
A composition, comprising a metal surface modified with at least one compound; wherein the compound is of the formula: ##STR12## wherein A 1 , A 2 , A 3 , and A 4 are each independently hydroxy, alkyl of one to ten carbon atoms, alkoxy of one to ten carbon atoms, alkoxyalkoxy of two to ten carbon atoms, alkanoyloxy of two to ten carbon atoms, or halogen, with the proviso that A 1 , A 2 , and A 3 may not all be alkyl; R 1 is a divalent radical selected from straight or branched alkylenes of one to twelve carbon atoms; D 1 is either a divalent radical selected from the group consisting of --O--, --NA 5 --, and --S--, or a trivalent radical of the formula ##STR13## wherein A 5 , A 6 , A 7 and A 8 are each independently hydrogen or alkyl of one to twelve carbon atoms; R 2 is hydrogen or a covalent bond with D 1 , with the proviso that R 2 is only a covalent bond with D 1 when D 1 is a trivalent radical; R 3 is a polymeric backbone; D 2 and D 3 are divalent radicals, each independently --O-- or --NA 9 --, wherein A 9 is hydrogen or alkyl of one to twelve carbon atoms; R 4 is a divalent radical selected from straight or branched alkylenes of three to thirty carbon atoms; R 5 is hydrogen or a mixture of hydrogen and alkyl of one to eight carbon atoms; R 6 is an alkyl of one to thirty carbon atoms; m and n are integers, each independently being one to one thousand, and j and k are integers, each independently being one to fifty.
Claim 3
Dependent Claim 14 words
A composition according to claim 1, wherein the metal is a metallic flake pigment.
Claim 4
Dependent Claim 11 words
A composition according to claim 2, further comprising an organic solvent.
Claim 5
Dependent Claim 9 words
A composition according to claim 2, further comprising water.
Claim 6
Dependent Claim 16 words
A composition according to claim 2, wherein the metallic flake pigment is an aluminum flake pigment.
Claim 7
Dependent Claim 33 words
A composition according to claim 5, wherein the aluminum flake pigment is surface modified with at least one compound wherein X is ##STR14## and at least one other compound wherein X is ##STR15##
Claim 8
Dependent Claim 26 words
A composition according to claim 5, wherein the D 1 is either --O-- or --NH--, and wherein the D 2 and D 3 are each --O--.
Claim 9
Dependent Claim 15 words
A composition according to claim 5, wherein the R 3 is an acrylic polymeric backbone.
Claim 10
Dependent Claim 20 words
A composition according to claim 8, wherein the molecular weight of the acrylic polymeric backbone is from 2000 to 50,000.
Claim 11
Dependent Claim 22 words
A composition according to claim 5, wherein the m is from 20 to 50 and the n is from 40 to 70.
Claim 12
Dependent Claim 18 words
A composition according to claim 5, wherein the R 5 is hydrogen and the R 6 is methyl.
Claim 13
Dependent Claim 18 words
A composition according to claim 5, wherein the j and k are each independently from 1 to 10.
Claim 14
Dependent Claim 16 words
A composition according to claim 5, wherein R 4 is --CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.2 --.
Claim 15
Dependent Claim 28 words
A composition, comprising a polymeric network; wherein the polymeric network comprises a residue of a compound according to claim 1 and the metal surface modified with the compound.
Claim 16
Dependent Claim 14 words
A composition according to claim 14, wherein the metal is a metallic flake pigment.
Claim 17
Dependent Claim 26 words
A coated article, comprising a substrate with a coating thereon; wherein said coating comprises a composition according to any of claims 2, 5, 6, or 15.
Claim 18
Dependent Claim 29 words
A method for producing a metallic flake pigment surface modified with at least one compound as described in claim 1, comprising mixing the metallic flake pigment with the compound.
Claim 19
Dependent Claim 16 words
A method according to claim 17, wherein the metallic flake pigment is an aluminum flake pigment.
Claim 20
Dependent Claim 23 words
A method according to claim 17, wherein the compound is first dissolved in an organic solvent before mixing with the metallic flake pigment.
Claim 21
Dependent Claim 19 words
A method according to claim 19, wherein the organic solvent is a glycol ether or a glycol ether acetate.
Claim 22
Dependent Claim 18 words
A method as recited in claim 19, wherein the metallic flake pigment is also mixed with tris (p-isocyanato-phenyl)thiophosphate.
Claim 23
Dependent Claim 18 words
A method as put forth in claim 21 wherein the metallic flake pigment is an aluminum flake pigment.
Claim 24
Dependent Claim 52 words
A method of making an aqueous composition, comprising the steps of: A. Producing a metallic flake pigment surface modified with at least one compound as described in claim 1, by mixing the metallic flake pigment with the compound; B. Combining the surface-modified metallic flake pigment, water, and at least one water-compatible polymer.
Claim 25
Dependent Claim 25 words
A method for producing a metallic flake pigment, comprising forming the metallic flake pigment in the presence of a compound as described in claim 1.
Claim 26
Dependent Claim 16 words
A method according to claim 24, wherein the metallic flake pigment is an aluminum flake pigment.

References Cited (Backward Citations)

US4213886A Cited
US4350535A Cited
US4565716A Cited
US4675358A Cited
US4750940A Cited
US5057156A Cited
US5039343A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-10-20 1996-04-20 1996-10-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-10-20 2000-04-20 2000-10-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-10-20 2004-04-20 2004-10-20 $7700.00 Window Closed / Lapsed

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