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US5155144A Expired / Lapsed US ⏱️ 0.0 years remaining

Polysaccharide-based porous sheets

Assignee: FMC Corp
•
Filing: 1990-10-29
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Granted: 1992-10-13
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Expires: 2010-10-29
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Abstract

Abstract A microporous sheet comprising a polymeric matrix having a liquid insoluble, particulate, activated polysaccharide media dispersed therein; use of the sheet in affinity chromatography or ion-exchange chromatography or as a biochemical reactor or battery separator; processes for manufacturing the sheet; apparatus containing the microporous sheet as its active element; and methods for using such sheet.

Inventors

  • 👤 James L. Manganaro
  • 👤 Bruce S. Goldberg
  • 👤 George E. Raynor, Jr.
  • 👤 Charles A. Gray

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 10:17
CPC Classifications
B; B01; B01J; B01J20/00; B01J20/28; B01J20/28014; B01J20/28026; B01D; B01D15/00; B01D15/08; B01J20/28033; B01J20/28054; B01J20/28078; B01J20/28085; C; C08; C08J; C08J9/00; C08J9/26; C08J9/28; H; H01; H01M; H01M50/00; H01M50/40; H01M50/403; H01M50/409; H01M50/411; H01M50/414; H01M50/429; B01D15/26; B01D15/36; B01D15/361; B01D15/38; B01D15/3804; C08J2201/00; C08J2201/04; C08J2201/054; Y; Y02; Y02E; Y02E60/00; Y02E60/10

Claims Analysis

Total Claims: 23
Claim 1
Independent Claim 57 words
A sheet article of manufacture having a network of pores throughout formed from (1) a polymeric resinous matrix and (2) a particulate, releasably-binding, liquid-media insoluble, activated polysaccharide selected from the group consisting of agar, agarose, alginate, carrageenan, cellulose, chitosan, konjac, and mixtures thereof fixedly dispersed throughout said matrix, wherein said pores allow access to the activated polysaccharide.
Claim 2
Dependent Claim 57 words
A sheet article of manufacture having a network of pores throughout formed from (1) a polymeric resinous matrix and (2) a particulate, releasably-binding, liquid-media insoluble, activated polysaccharide selected from the group consisting of agar, agarose, alginate, carrageenan, cellulose, chitosan, konjac, and mixtures thereof fixedly dispersed throughout said matrix, wherein said pores allow access to the activated polysaccharide.
Claim 3
Dependent Claim 13 words
The composition of claim 1 wherein the polymeric resin is a thermoplastic resin.
Claim 4
Dependent Claim 14 words
The composition of claim 1 wherein the activated polysaccharide contains ion exchange chromatography sites.
Claim 5
Dependent Claim 13 words
The composition of claim 1 wherein the activated polysaccharide contains affinity chromatography sites.
Claim 6
Dependent Claim 18 words
The composition of claim 1 wherein the activated polysaccharide contains sites capable of binding biological materials or organisms.
Claim 7
Dependent Claim 16 words
The composition of claim 1 wherein the polysaccharide is an activated cellulose, agarose, or mixtures thereof.
Claim 8
Dependent Claim 11 words
The composition of claim 6 wherein the polysaccharide is diethylaminoethyl cellulose.
Claim 9
Dependent Claim 12 words
The composition of claim 6 wherein the polysaccharide is cross-linked diethylaminoethyl agarose.
Claim 10
Dependent Claim 19 words
The composition of claim 1 wherein the weight ratio of activated polysaccharide to matrix comprises about 0.3:1 to 3:1.
Claim 11
Dependent Claim 17 words
The composition of claim 1 wherein the pores average about from 1 to 40 microns in diameter.
Claim 12
Dependent Claim 17 words
The composition of claim 1 wherein the pores average about from 10 to 30 microns in diameter.
Claim 13
Dependent Claim 29 words
The composition of claim 1 wherein the resinous matrix is formed from at least one polyvinyl chloride resin, polyvinyl chloride/monoethylenic monomer copolymer, polyolefin, polysulfone, latex, or water-insoluble cellulose ester.
Claim 14
Dependent Claim 18 words
The composition of claim 1 wherein the polysaccharide is at least one activated carrageenan, alginate, chitosan, or konjac.
Claim 15
Dependent Claim 18 words
The sheet of claim 1 adapted for use as a battery separator in separating electrodes in storage batteries.
Claim 16
Dependent Claim 101 words
A process for the preparation of a sheet according to claim 1 comprising: a. mixing: (i) a matrix-forming material which is a polymeric resin, (ii) a solvent or dispersant for said polymeric resin; (iii) a media-forming material which is a particulate, releasably-binding, carrier liquid insoluble, activated polysaccharide, and (iv) a volatile non-solvent pore former; b. extruding or molding the mixture to form a substantially flattened sheet; c. passing the flattened sheet through an extraction medium to replace the solvent in the sheet, when present, with the extraction medium; and d. removing the extraction medium and non-solvent pore former from the sheet.
Claim 17
Dependent Claim 17 words
The process of claim 15 wherein the matrix-forming material is a latex and said dispersant is water.
Claim 18
Dependent Claim 14 words
The process of claim 15 wherein the matrix-forming material is plasticized in said solvent.
Claim 19
Dependent Claim 18 words
The process of claim 17 wherein the weight ratio of solvent to resin comprises from 1:1 to 3:1.
Claim 20
Dependent Claim 18 words
The process of claim 15 wherein the weight ratio of media to matrix is about 0.3:1 to 3:1.
Claim 21
Dependent Claim 22 words
The process of claim 15 wherein the polysaccharide is an activated: agar, agarose, alginate, carrageenan, cellulose, chitosan, konjac, or a mixture thereof.
Claim 22
Dependent Claim 27 words
The process of claim 15 wherein the polymeric resin is at least one polyvinyl chloride resin, polyvinyl chloride/monoethylenic monomer copolymer, polyolefin, polysulfone, latex, or water-insoluble cellulose ester.
Claim 23
Dependent Claim 20 words
The process of claim 16 wherein the mixing is carried out in the added presence of an alkali metal carbonate.

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Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-10-13 1996-04-13 1996-10-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-10-13 2000-04-13 2000-10-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-10-13 2004-04-13 2004-10-13 $7700.00 Window Closed / Lapsed

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