US5151479A
Expired / Lapsed
US
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Dental adhesive composition
Assignee: Mitsubishi Chemical Corp
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Filing: 1990-04-20
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Granted: 1992-09-29
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Expires: 2010-04-20
Abstract
Abstract This invention provides dental adhesive compositions consisting essentially of (a) an aliphatic amine salt of a polymerizable phosphoric ester, as represented by the formula ##STR1## where R and R' are specific radicals; (b) at least one radical-polymerizable unsaturated monomer; and (c) a radical polymerization initiator. These compositions are useful in bonding living dental tissue restoration materials to living tooth tissues, particularly to dentin.
Inventors
- 👤 Nobuhiro Mukai
- 👤 Hitoshi Ige
- 👤 Takayuki Makino
- 👤 Junko Atarashi
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 16:03
CPC Classifications
A; A61; A61K; A61K6/00; A61K6/30
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
152 words
A dental adhesive composition consisting essentially of (a) an aliphatic amine salt of a polymerizable phosphoric ester represented by the following formula ##STR7## where R is CH 2 ═CHCO 2 (CH 2 ) n O(CH 2 )--, CH 2 ═C(CH 3 )CO 2 (CH 2 ) n --, CH 2 ═CHCO 2 (CH 2 ) n --, CH 2 ═C(CH 3 )CO 2 )(CH 2 ) n O(CH 2 )-- or hydrogen, n is a whole number of 1 to 5, the two R radicals are not hydrogen at the same time, R' is a hydrocarbon radical having 1 to 5 carbon atoms or any of the radicals described above for R, the three R' radicals are not all hydrogen at the same time, the three R' radicals do not all contain an unsaturated bond at the same time; (b) at least one radical-polymerizable unsaturated monomer, and (c) a radical polymerization initiator.
Claim 2
Dependent Claim
152 words
A dental adhesive composition consisting essentially of (a) an aliphatic amine salt of a polymerizable phosphoric ester represented by the following formula ##STR7## where R is CH 2 ═CHCO 2 (CH 2 ) n O(CH 2 )--, CH 2 ═C(CH 3 )CO 2 (CH 2 ) n --, CH 2 ═CHCO 2 (CH 2 ) n --, CH 2 ═C(CH 3 )CO 2 )(CH 2 ) n O(CH 2 )-- or hydrogen, n is a whole number of 1 to 5, the two R radicals are not hydrogen at the same time, R' is a hydrocarbon radical having 1 to 5 carbon atoms or any of the radicals described above for R, the three R' radicals are not all hydrogen at the same time, the three R' radicals do not all contain an unsaturated bond at the same time; (b) at least one radical-polymerizable unsaturated monomer, and (c) a radical polymerization initiator.
Claim 3
Dependent Claim
42 words
A dental adhesive composition as claimed in claim 1 wherein the aliphatic amine salt of polymerizable phosphoric ester (a) is used in an amount of 0.1 to 30 parts by weight per 100 parts by weight of the radical-polymerizable unsaturated monomer (b).
Claim 4
Dependent Claim
18 words
A dental adhesive composition as claimed in claim 1 wherein the radical polymerization initiator is a photopolymerization initiator.
Claim 5
Dependent Claim
19 words
A dental adhesive composition as claimed in claim 1 wherein the radical polymerization initiator is a redox polymerization initiator.
Claim 6
Dependent Claim
30 words
A dental adhesive composition as claimed in claim 3 wherein the photopolymerization initiator is used in an amount of 0.005 to 30% by weight based on the radical-polymerizable unsaturated monomer.
Claim 7
Dependent Claim
72 words
A dental adhesive composition as claimed in claim 4 wherein the redox polymerization initiator comprises a combination of an aromatic amine and an organic peroxide, a combination of a sulfinic acid salt and an organic peroxide, or a combination of an aromatic amine, a sulfinic acid salt and an organic peroxide, and the organic peroxide is used in an amount of 0.01 to 10% by weight based on the radical-polymerizable unsaturated monomer.
Claim 8
Dependent Claim
37 words
A dental adhesive composition as claimed in claim 1 wherein the aliphatic amine salt of polymerizable phosphoric ester is a monoethanolamine, dimethylaminoethyl methacrylate or diethylaminoethyl methacrylate salt of (meth)acryloyloxyethyl phosphate, (meth)acryloyloxypropyl phosphate, (meth)acryloyloxyethyloxyethyl phosphate or bis phosphate.
Claim 9
Dependent Claim
23 words
A dental adhesive composition as claimed in claim 1 wherein the aliphatic amine salt of polymerizable phosphoric ester is methacryloyloxyethyl phosphate dimethylaminoethyl methacrylate.
Claim 10
Dependent Claim
39 words
A dental adhesive composition as claimed in claim 1 wherein the radical-polymerizable unsaturated monomer is a compound selected from the group consisting of the compound having the formula ##STR8## 2,2-bis propane, triethylene glycol dimethacrylate, 2,2-bis propane and 2-hydroxyethyl methacrylate.
Claim 11
Dependent Claim
29 words
A dental adhesive composition as claimed in claim 3 wherein the radical polymerization initiator is a visible light polymerization initiator comprising a combination of camphorquinone and a tertiary amine.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1995-09-29 | 1996-03-30 | 1996-09-29 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1999-09-29 | 2000-03-30 | 2000-09-29 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2003-09-29 | 2004-03-30 | 2004-09-29 | $7700.00 | Window Closed / Lapsed |