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US5149722A Expired / Lapsed US ⏱️ 0.0 years remaining

Dispersant for carbon black-filled foam

Assignee: IP Rights LLC
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Filing: 1991-08-28
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Granted: 1992-09-22
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Expires: 2011-08-28
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Abstract

Abstract A closed cell, rigid, polymer foam comprising the reaction product of a polyisocyanate and an isocyanate-reactive compound in the presence of (a) a foaming agent, (b) at least about 2 percent by weight of carbon black, based on the weight of the polymer in the foam, and (c) a capped polyoxyalkylene compound which helps bring about a uniform dispersion of the carbon black throughout the foam so that the aged k-factor of the foam is below the aged k-factor of the corresponding unfilled foam.

Inventors

  • 👤 Thomas G. Soukup

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 19:40
CPC Classifications
C; C08; C08J; C08J9/00; C08J9/0061; C08J9/0066; C08J2375/00; C08J2375/04; C08J2471/00; Y; Y10; Y10S; Y10S521/00; Y10S521/917

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 180 words
A process for producing a closed cell, rigid, isocyanate-based polymer foam which comprises (a) providing in an isocyanate-based polymer foam-forming composition a dispersion of carbon black, the carbon black being present in an amount of at least about 2 percent by weight, based on the weight of the polymer in the foam, an end-capped polyoxyalkylene compound which is nonreactive with isocyanate groups being incorporated in the foam-forming composition, and (b) thereafter foaming and curing the resultant filled foam-forming composition, wherein the polyoxyalkylene compound is present in an amount sufficient to help bring about a uniform dispersion of the carbon black throughout the foam so that there is present in the cell walls of the foam an amount of predominantly non-agglomerated carbon black which reduces the aged k-factor of the foam to below the aged k-factor of the corresponding unfilled foam having the same density and prepared from the same foam-forming composition as the filled foam except that the carbon black is omitted and the amount of foaming agent is adjusted to equalize the densities of the filled and unfilled foams.
Claim 2
Dependent Claim 180 words
A process for producing a closed cell, rigid, isocyanate-based polymer foam which comprises (a) providing in an isocyanate-based polymer foam-forming composition a dispersion of carbon black, the carbon black being present in an amount of at least about 2 percent by weight, based on the weight of the polymer in the foam, an end-capped polyoxyalkylene compound which is nonreactive with isocyanate groups being incorporated in the foam-forming composition, and (b) thereafter foaming and curing the resultant filled foam-forming composition, wherein the polyoxyalkylene compound is present in an amount sufficient to help bring about a uniform dispersion of the carbon black throughout the foam so that there is present in the cell walls of the foam an amount of predominantly non-agglomerated carbon black which reduces the aged k-factor of the foam to below the aged k-factor of the corresponding unfilled foam having the same density and prepared from the same foam-forming composition as the filled foam except that the carbon black is omitted and the amount of foaming agent is adjusted to equalize the densities of the filled and unfilled foams.
Claim 3
Dependent Claim 27 words
The process of claim 1 wherein the foam-forming composition comprises a mixture for forming a polymer foam selected from the group consisting of polyurethane and polyisocyanurate foams.
Claim 4
Dependent Claim 28 words
The process of claim 2 wherein the foam-forming composition comprises carbon black, the polyoxyalkylene compound, a polyisocyanate, an isocyanate-reactive compound, a foaming agent, a catalyst, and a surfactant.
Claim 5
Dependent Claim 54 words
The process of claim 3 wherein an initial dispersion of the carbon black in the polyisocyanate is provided, the polyoxyalkylene compound being incorporated in the dispersion to help disperse the carbon black, and thereafter the initial dispersion is mixed with the other foam-forming ingredients to form the total dispersion which is foamed and cured.
Claim 6
Dependent Claim 39 words
The process of claim 4 wherein the carbon black is a standard rubber-grade type falling under the classification of ASTM-550, and is ground to a Hegman level of 8 during the formation of the initial dispersion in the polyisocyanate.
Claim 7
Dependent Claim 51 words
The process of claim 4 wherein about 4 to about 10 percent by weight of carbon black, based on-the weight of the polymer in the foam, is dispersed in the foam-forming composition in step (a), the carbon black having a mean particle diameter of from about 20 to about 100 nanometers.
Claim 8
Dependent Claim 17 words
The process of claim 4 wherein the foam-forming composition comprises a mixture for forming a polyisocyanurate foam.
Claim 9
Dependent Claim 61 words
The process of claim 4 wherein about 4 to about 10 percent by weight of carbon black, based on the weight of the polymer in the foam, is dispersed in the foam-forming composition in step (a), and the polyoxyalkylene compound is a capped ethoxylated nonyl phenol which contains about 1 to 4 moles of ethylene oxide per mole of nonyl phenol.
Claim 10
Dependent Claim 19 words
The process of claim 8 wherein the polyisocyanate is aromatic, and the isocyanate-reactive compound is an aromatic polyester polyol.
Claim 11
Dependent Claim 17 words
The process of claim 9 wherein the foam-forming composition comprises a mixture for forming a polyisocyanurate foam.
Claim 12
Dependent Claim 39 words
The process of claim 10 wherein the carbon black is a standard rubber-grade type falling under the classification of ASTM-550, and is ground to a Hegman level of 8 during the formation of the initial dispersion in the polyisocyanate.
Claim 13
Dependent Claim 30 words
The process of claim 11 wherein the ethoxylated nonyl phenol contains about 1.5 to 2 moles of ethylene oxide per mole of nonyl phenol and is capped by acetic anhydride.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-09-22 1996-03-23 1996-09-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-09-22 2000-03-23 2000-09-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-09-22 2004-03-23 2004-09-22 $7700.00 Window Closed / Lapsed

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