US5140003A
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US
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Method for manufacturing layers from an oxide-ceramic superconductor material on a substrate using a cvd-process
Assignee: Siemens AG
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Filing: 1989-12-22
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Granted: 1992-08-18
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Expires: 2009-12-22
Abstract
Abstract At least one layer from an oxide-ceramic superconductor material with a high transition temperature is produced on a substrate using a CVD-process. As parent materials, at least one vaporizable composition of each of the metallic components of the superconductor material is provided respectively, and these parent compositions are vaporized respectively at a predetermined temperature and with a predetermined partial pressure. In addition, at least one gaseous coreactant is provided, which is reactive with the parent compositions, the parent compositions as well as a minimum of one coreactant are dosed respectively by means of a carrier gas stream and united in a gas mixture with a predetermined mixture ratio, and to form the superconductor material, the conditions of reaction are adjusted using the energy supply for a reaction of or with the parent compositions and a minimum of one coreactant. A gaseous coreactant containing at least ammonia or organic amines is fed to the gas mixture. Gaseous water is advantageously admixed with this coreactant.
Inventors
- 👤 Alfred Mueller
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 16:15
CPC Classifications
H; H10; H10N; H10N60/00; H10N60/01; H10N60/0268; H10N60/0296; H10N60/0436; H10N60/0464; C; C04; C04B; C04B35/00; C04B35/01; C04B35/45; C23; C23C; C23C16/00; C23C16/22; C23C16/30; C23C16/40; C23C16/408; Y; Y10; Y10S; Y10S505/00; Y10S505/725; Y10S505/734
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
223 words
A method for manufacturing at least one layer from an oxide-ceramic superconductor material on a substrate by means of a CVD-process, said superconductor material containing a crystalline superconducting phase with a transition temperature of at least 77 K and comprising a substance system containing metallic components and oxygen, said CVD-process comprising the steps of: providing as parent materials, at least one vaporizable composition of each of the metallic components of the substance system respectively, vaporizing each of the parent compositions at a predetermined temperature and with a predetermined partial pressure, providing in addition, at least one gaseous coreactant which is reactive with the vaporized parent compositions, dosing the vaporized parent compositions and the at least one gaseous coreactant with respective carrier gas streams, so that when the thus formed gas streams are subsequently united in a gas mixture, a metallic component ratio is adjusted, which is adapted to the composition of the superconductive phase, and to from the desired superconducting phase via a hydrolytic reaction, adjusting the conditions of reaction using an energy supply for a reaction of or with the vaporized parent compositions and the at least one coreactant, and feeding to the gas mixture as the coreactant a gaseous coreactant containing at least one of ammonia and an organic amine, said ammonia or amine being a catalyst for the hydrolytic reaction.
Claim 2
Independent Claim
223 words
A method for manufacturing at least one layer from an oxide-ceramic superconductor material on a substrate by means of a CVD-process, said superconductor material containing a crystalline superconducting phase with a transition temperature of at least 77 K and comprising a substance system containing metallic components and oxygen, said CVD-process comprising the steps of: providing as parent materials, at least one vaporizable composition of each of the metallic components of the substance system respectively, vaporizing each of the parent compositions at a predetermined temperature and with a predetermined partial pressure, providing in addition, at least one gaseous coreactant which is reactive with the vaporized parent compositions, dosing the vaporized parent compositions and the at least one gaseous coreactant with respective carrier gas streams, so that when the thus formed gas streams are subsequently united in a gas mixture, a metallic component ratio is adjusted, which is adapted to the composition of the superconductive phase, and to from the desired superconducting phase via a hydrolytic reaction, adjusting the conditions of reaction using an energy supply for a reaction of or with the vaporized parent compositions and the at least one coreactant, and feeding to the gas mixture as the coreactant a gaseous coreactant containing at least one of ammonia and an organic amine, said ammonia or amine being a catalyst for the hydrolytic reaction.
Claim 3
Dependent Claim
16 words
The method recited in claim 1, wherein the reaction takes place while oxygen is being supplied.
Claim 4
Dependent Claim
14 words
The method according to claim 1, further comprising admixing gaseous water with the coreactant.
Claim 5
Dependent Claim
14 words
The method recited in claim 1, further comprising admixing oxygen gas with the coreactant.
Claim 6
Dependent Claim
24 words
The method recited in claim 1, wherein the step of providing as parent materials comprises providing chelates as parent compositions for the metallic components.
Claim 7
Dependent Claim
14 words
The method recited in claim 1, further comprising providing argon as the carrier gas.
Claim 8
Dependent Claim
23 words
The method recited in claim 1, wherein the reaction of or with the parent components is initiated by means of a temperature increase.
Claim 9
Dependent Claim
33 words
The method recited in claim 1, further comprising providing the energy supply in a single stage, whereby the vaporized parent compositions and the coreactant are converted directly while the superconducting phase is formed.
Claim 10
Dependent Claim
60 words
The method recited in claim 1, further comprising providing the energy supply in several stages, whereby in a first stage, the vaporized parent compositions and the coreactant are converted into basic oxides of the metallic components of the substance system and then in a further stage, these oxides of the metallic components are converted while the superconducting phase is formed.
Claim 11
Dependent Claim
21 words
The method recited in claim 9, wherein, in the further stage, a higher temperature is provided than for the first stage.
Claim 12
Dependent Claim
17 words
The method recited in claim 5, wherein the step of providing as parent materials comprises providing β-diketones.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1995-08-18 | 1996-02-17 | 1996-08-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1999-08-18 | 2000-02-17 | 2000-08-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2003-08-18 | 2004-02-17 | 2004-08-18 | $7700.00 | Window Closed / Lapsed |