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US5135843A Expired / Lapsed US ⏱️ 0.0 years remaining

Silver halide photographic element

Assignee: Konica Minolta Inc
•
Filing: 1990-07-27
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Granted: 1992-08-04
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Expires: 2010-07-27
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Abstract

Abstract The improved silver halide photographic material comprises a support having an antistatic coating thereon that contains a water-soluble conductive polymer, hydrophobic polymer particles and a curing agent which is a bifunctional ethylene oxide type curing agent that is to be cured by exposure to electron beams or X-rays. This silver halide photographic material may contain a tetrazolium compound or a hydrazine compound in order to prevent desensitization due to aging. At least one hydrophilic colloidal layer may be provided on the antistatic coating, which colloidal layer contains an epoxy curing agent having a hydroxy group.

Inventors

  • 👤 Yasuhiko Takamuki
  • 👤 Takatoshi Yamada
  • 👤 Takeshi Habu
  • 👤 Toshiharu Nagashima

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 09:36
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/76; G03C1/85; G03C1/89; G03C1/895; G03C1/005; G03C1/06; G03C1/30; G03C1/306

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 280 words
A silver halide photographic element comprising a support having provided, on a first side thereof, at least one light sensitive silver halide emulsion layer containing a hydrazine compound or tetrazolium compound and, on a second side thereof, an antistatic coating layer having a backing layer formed thereon, said hydrazine compound being represented by the following formula ##STR23## wherein R 1 is a monovalent organic residue; R 2 is hydrogen or a monovalent organic residue; Q 1 and Q 2 are each independently hydrogen, optionally substituted alkylsulfonyl, or optionally substituted arylsulfonyl; and X 1 is oxygen or sulfur; said tetrazolium compound being represented by the following formula ##STR24## wherein R 1 , R 2 and R 3 are each independently substituted or unsubstituted phenyl; and X⊖ is an anion; said antistatic coating layer containing (1) a water soluble conductive polymer having a molecular weight of 3,000-100,000 and, in an amount of at least 5 wt % per mol of polymer, a group selected from the class consisting of sulfonic acid, sulfate ester, quaternary ammonium salt, tertiary ammonium salt, carboxyl and polyethylene oxide, (2) hydrophobic polymer particles obtained by polymerizing a monomer selected from the group consisting of styrene, a styrene derivative, alkyl acrylate, alkyl methacrylate, an olefinic derivative, a halogenated ethylene derivative, an acrylamide derivative, a methacrylamide derivative, a vinyl ester derivative, and acrylonitrile, and (3) an electron-beam or an X-ray radiation curable polyalkylene oxide compound or a polyfunctional aziridine compound in an amount of 1-1,000 mg/m 2 ; said backing layer containing gelatin as a binder and an aliphatic epoxy curing agent having a hydroxyl group and a plurality of epoxy groups in an amount of 1-1,000 mg/m 2 .
Claim 2
Dependent Claim 280 words
A silver halide photographic element comprising a support having provided, on a first side thereof, at least one light sensitive silver halide emulsion layer containing a hydrazine compound or tetrazolium compound and, on a second side thereof, an antistatic coating layer having a backing layer formed thereon, said hydrazine compound being represented by the following formula ##STR23## wherein R 1 is a monovalent organic residue; R 2 is hydrogen or a monovalent organic residue; Q 1 and Q 2 are each independently hydrogen, optionally substituted alkylsulfonyl, or optionally substituted arylsulfonyl; and X 1 is oxygen or sulfur; said tetrazolium compound being represented by the following formula ##STR24## wherein R 1 , R 2 and R 3 are each independently substituted or unsubstituted phenyl; and X⊖ is an anion; said antistatic coating layer containing (1) a water soluble conductive polymer having a molecular weight of 3,000-100,000 and, in an amount of at least 5 wt % per mol of polymer, a group selected from the class consisting of sulfonic acid, sulfate ester, quaternary ammonium salt, tertiary ammonium salt, carboxyl and polyethylene oxide, (2) hydrophobic polymer particles obtained by polymerizing a monomer selected from the group consisting of styrene, a styrene derivative, alkyl acrylate, alkyl methacrylate, an olefinic derivative, a halogenated ethylene derivative, an acrylamide derivative, a methacrylamide derivative, a vinyl ester derivative, and acrylonitrile, and (3) an electron-beam or an X-ray radiation curable polyalkylene oxide compound or a polyfunctional aziridine compound in an amount of 1-1,000 mg/m 2 ; said backing layer containing gelatin as a binder and an aliphatic epoxy curing agent having a hydroxyl group and a plurality of epoxy groups in an amount of 1-1,000 mg/m 2 .
Claim 3
Dependent Claim 31 words
The element of claim 1 wherein said polyalkylene oxide compound is represented by the following general formula (C): CH.sub.2 ═CH--L--CH═CH.sub.2 (C) wherein L is a substituted or unsubstituted alkylene oxide chain.
Claim 4
Dependent Claim 37 words
The element of claim 1 wherein said polyalkylene oxide compound contained in said antistatic coating layer is cured by exposure to electron beams or X-rays at an energy of 10 -2 to 10 6 kW/m 2 .
Claim 5
Dependent Claim 34 words
The element according to claim 1 wherein the water-soluble conductive polymer has at least one conductive group selected from among a sulfonic acid group, a sulfate ester group, and a quarternary ammonium salt group.
Claim 6
Dependent Claim 23 words
The element according to claim 1 wherein the antistatic coating contains the water-soluble conductive polymer in an amount of 0.01-10 g/m 2 .
Claim 7
Dependent Claim 31 words
The element according to claim 1 wherein the hydrazine compound is contained in the light-sensitive emulsion layer in an amount of 10 -5 to 10 -1 mole per mole of silver.
Claim 8
Dependent Claim 34 words
The element according to claim 1 wherein the tetrazolium compound is contained in the light-sensitive emulsion layer in an amount of from about 1 mg up to 10 g per mole of silver halide.

References Cited (Backward Citations)

GB2029978A Cited
US4225665A Cited
US4308332A Cited
US4294739A Cited
EP0032456B1 Cited
GB2078235A Cited
US4810624A Cited
US4908155A Cited
US4960688A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-08-04 1996-02-03 1996-08-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-08-04 2000-02-03 2000-08-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-08-04 2004-02-03 2004-08-04 $7700.00 Window Closed / Lapsed

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