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US5135571A Expired / Lapsed US ⏱️ 0.0 years remaining

Recording liquid

Assignee: Canon Inc
•
Filing: 1990-10-30
•
Granted: 1992-08-04
•
Expires: 2010-10-30
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Abstract

Abstract A recording liquid, comprising a recording agent which is a component that forms a recorded image and a liquid medium in which said recording agent is dissolved or dispersed, wherein said recording agent comprises a dye represented by the Formula (A) ##STR1## wherein R 1 and R 2 are selected from the group consisting of a hydrogen atom, a methyl group, a methoxy group, a chloro group, a sulfonic acid group; X represents a residual group of an organic acid; and M represents a base selected from the group consisting of an alkali metal group, an ammonium group, and an organic amine group and at least one dye selected from the group consisting of C.I. Acid Red 131, C.I. Acid Red 274, C.I. Direct Red 227 and C.I. Direct Red 9.

Inventors

  • 👤 Katsuhiro Shirota
  • 👤 Osamu Nishiwaki
  • 👤 Kazuo Iwata
  • 👤 Shinichi Tochihara

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 22:46
CPC Classifications
C; C09; C09D; C09D11/00; C09D11/30; C09D11/32; C09D11/328; C09B; C09B29/00; C09B29/24; C09B29/28; C09B29/30

Claims Analysis

Total Claims: 98
Claim 1
Independent Claim 153 words
A recording liquid, comprising a recording agent which is a component that forms a recorded image and a liquid medium in which said recording agent is dissolved or dispersed, wherein said recording agent comprises a dye represented by the Formula (A) ##STR6## wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, a methyl group, a methoxy group, a chloro group, a sulfonic acid group, ##STR7## X represents a residual group of an organic acid; and M represents a base selected from the group consisting of an alkali metal group, an ammonium group, and an organic amine group; and at least one dye selected from the group consisting of C.I. Acid Red 131, C.I. Acid Red 274, C.I. Direct Red 227 and C.I. Direct Red 9, and wherein said dye represented by Formula (A) comprises 20% to 80% of the total weight of the recording agents.
Claim 2
Dependent Claim 153 words
A recording liquid, comprising a recording agent which is a component that forms a recorded image and a liquid medium in which said recording agent is dissolved or dispersed, wherein said recording agent comprises a dye represented by the Formula (A) ##STR6## wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, a methyl group, a methoxy group, a chloro group, a sulfonic acid group, ##STR7## X represents a residual group of an organic acid; and M represents a base selected from the group consisting of an alkali metal group, an ammonium group, and an organic amine group; and at least one dye selected from the group consisting of C.I. Acid Red 131, C.I. Acid Red 274, C.I. Direct Red 227 and C.I. Direct Red 9, and wherein said dye represented by Formula (A) comprises 20% to 80% of the total weight of the recording agents.
Claim 3
Dependent Claim 23 words
The recording liquid according to claim 1, wherein said recording agent comprises the dye represented by Formula (A) and C.I. Direct Red 227.
Claim 4
Dependent Claim 35 words
The recording liquid according to claim 1, wherein said dye represented by Formula (A) is contained in an amount of from 30 to 70% by weight based on the total weight of the recording agents.
Claim 5
Dependent Claim 178 words
A recording liquid comprising a recording agent which is a component that forms a recorded image and a liquid medium in which said recording agent is dissolved or dispersed, wherein said recording agent comprises a magenta component and a yellow component, said magenta component being composed of a dye represented by the Formula (A), ##STR8## wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, a methyl group, a methoxy group, a chloro group, a sulfonic acid group, ##STR9## X represents a residual group of an organic acid; and M represents a base selected from the group consisting of an alkali metal group, an ammonium group, and an organic amine group; and C.I. Direct Red 227; said yellow component being composed of at least one of C.I. Direct Yellow 86 and C.I. Direct Yellow 142, wherein the dye represented by Formula (A) comprises 20% to 70% of the total weight of the recording agents and C.I. Direct Red 227 comprises 20% to 60% of the total weight of the recording agents.
Claim 6
Dependent Claim 178 words
A recording liquid comprising a recording agent which is a component that forms a recorded image and a liquid medium in which said recording agent is dissolved or dispersed, wherein said recording agent comprises a magenta component and a yellow component, said magenta component being composed of a dye represented by the Formula (A), ##STR8## wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, a methyl group, a methoxy group, a chloro group, a sulfonic acid group, ##STR9## X represents a residual group of an organic acid; and M represents a base selected from the group consisting of an alkali metal group, an ammonium group, and an organic amine group; and C.I. Direct Red 227; said yellow component being composed of at least one of C.I. Direct Yellow 86 and C.I. Direct Yellow 142, wherein the dye represented by Formula (A) comprises 20% to 70% of the total weight of the recording agents and C.I. Direct Red 227 comprises 20% to 60% of the total weight of the recording agents.
Claim 7
Dependent Claim 51 words
The recording liquid according to claim 4, which is used in a recording system in which recording is performed by applying a heat energy corresponding to a recording signal, to a recording solution in the room of a recording head, said energy causing ink droplets to fly onto a recording surface.
Claim 8
Dependent Claim 20 words
The recording liquid according to claim 4, wherein said liquid medium comprises a polyhydric alcohol or an aliphatic monovalent alcohol.
Claim 9
Dependent Claim 26 words
The recording liquid according to claim 6, wherein said polyhydric alcohol is at least one selected from the group consisting of ethylene glycol, thiodiglycol and glycerol.
Claim 10
Dependent Claim 28 words
The recording liquid according to claim 6, wherein said aliphatic monovalent alcohol is selected from the group consisting of methyl alcohol, ethyl alcohol, isopropyl alcohol and n-butyl alcohol.
Claim 11
Dependent Claim 188 words
A recording liquid comprising a recording agent which is a component that forms a recorded image and a liquid medium in which said recording agent is dissolved or dispersed, wherein said recording agent comprises a magenta component and a cyan component, said magenta component being composed of a dye represented by the Formula (A) ##STR10## wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, a methyl group, a methoxy group, a chloro group, a sulfonic acid group, ##STR11## X represents a residual group of an organic acid; and M represents a base selected from the group consisting of an alkali metal group, an ammonium group, and an organic amine group; and C.I. Direct Red 227; said cyan component being composed of at least one selected from the group consisting of C.I. Direct Blue 199, C.I. Direct Blue 86 and C.I. Acid Blue 198, wherein the dye represented by Formula (A) comprises 2% to 50% of the total weight of the recording agents, and wherein C.I. Direct Red 227 comprises 5% to 30% of the total weight of the recording agents.
Claim 12
Dependent Claim 188 words
A recording liquid comprising a recording agent which is a component that forms a recorded image and a liquid medium in which said recording agent is dissolved or dispersed, wherein said recording agent comprises a magenta component and a cyan component, said magenta component being composed of a dye represented by the Formula (A) ##STR10## wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, a methyl group, a methoxy group, a chloro group, a sulfonic acid group, ##STR11## X represents a residual group of an organic acid; and M represents a base selected from the group consisting of an alkali metal group, an ammonium group, and an organic amine group; and C.I. Direct Red 227; said cyan component being composed of at least one selected from the group consisting of C.I. Direct Blue 199, C.I. Direct Blue 86 and C.I. Acid Blue 198, wherein the dye represented by Formula (A) comprises 2% to 50% of the total weight of the recording agents, and wherein C.I. Direct Red 227 comprises 5% to 30% of the total weight of the recording agents.
Claim 13
Dependent Claim 51 words
The recording liquid according to claim 9, which is used in a recording system in which recording is performed by applying a heat energy corresponding to a recording signal, to a recording solution in the room of a recording head, said energy causing ink droplets to fly onto a recording surface.
Claim 14
Dependent Claim 26 words
The recording liquid according to claim 9, wherein said dye represented by Formula (A) holds from 5 to 40% by weight in the whole recording agents.
Claim 15
Dependent Claim 20 words
The recording liquid according to claim 9, wherein said liquid medium comprises a polyhydric alcohol or an aliphatic monovalent alcohol.
Claim 16
Dependent Claim 26 words
The recording liquid according to claim 12, wherein said polyhydric alcohol is at least one selected from the group consisting of ethylene glycol, thiodiglycol and glycerol.
Claim 17
Dependent Claim 28 words
The recording solution according to claim 12, wherein said aliphatic monovalent alcohol is selected from the group consisting of methyl alcohol, ethyl alcohol, isopropyl alcohol and n-butyl alcohol.
Claim 18
Dependent Claim 53 words
The recording liquid according to claim 1, in combination with a recording system for performing recording comprising: a recording head and means for applying heat energy corresponding to a recording signal, to the recording liquid in the recording head, said energy causing droplets of the recording liquid to fly onto a recording surface.
Claim 19
Dependent Claim 20 words
The recording liquid according to claim 1, wherein said liquid medium comprises a polyhydric alcohol or an aliphatic monovalent alcohol.
Claim 20
Dependent Claim 26 words
The recording liquid according to claim 16, wherein said polyhydric alcohol is at least one selected from the group consisting of ethylene glycol, thiodiglycol, and glycerol.
Claim 21
Dependent Claim 18 words
The recording liquid according to claim 1, wherein said liquid medium contains water and a water-soluble organic solvent.
Claim 22
Dependent Claim 25 words
The recording liquid according to claim 18, wherein the content of said water is in the range of 10-95% by weight of the recording liquid.
Claim 23
Dependent Claim 25 words
The recording liquid according to claim 18, wherein the content of said water is in the range of 70-95% by weight of the recording liquid.
Claim 24
Dependent Claim 27 words
The recording liquid according to claim 18, wherein the content of said water-soluble organic solvent is in the range of 1-50% by weight of the recording liquid.
Claim 25
Dependent Claim 27 words
The recording liquid according to claim 18, wherein the content of said water-soluble organic solvent is in the range of 5-30% by weight of the recording liquid.
Claim 26
Dependent Claim 18 words
The recording liquid according to claim 4, wherein said liquid medium contains water and a water-soluble organic solvent.
Claim 27
Dependent Claim 25 words
The recording liquid according to claim 23, wherein the content of said water is in the range of 10-95% by weight of the recording liquid.
Claim 28
Dependent Claim 25 words
The recording liquid according to claim 23, wherein the content of said water is in the range of 70-95% by weight of the recording liquid.
Claim 29
Dependent Claim 27 words
The recording liquid according to claim 23, wherein the content of said water-soluble organic solvent is in the range of 1-50% by weight of the recording liquid.
Claim 30
Dependent Claim 27 words
The recording liquid according to claim 23, wherein the content of said water-soluble organic solvent is in the range of 5-30% by weight of the recording liquid.
Claim 31
Dependent Claim 18 words
The recording liquid according to claim 9, wherein said liquid medium contains water and a water-soluble organic solvent.
Claim 32
Dependent Claim 25 words
The recording liquid according to claim 28, wherein the content of said water is in the range of 10-95% by weight of the recording liquid.
Claim 33
Dependent Claim 25 words
The recording liquid according to claim 28, wherein the content of said water is in the range of 70-95% by weight of the recording liquid.
Claim 34
Dependent Claim 27 words
The recording liquid according to claim 28, wherein the content of said water-soluble organic solvent is in the range of 1-50% by weight of the recording liquid.
Claim 35
Dependent Claim 27 words
The recording liquid according to claim 28, wherein the content of said water-soluble organic solvent is in the range of 5-30% by weight of the recording liquid.
Claim 36
Dependent Claim 134 words
An ink jet recording method for performing color recording, comprising the step of imparting liquid droplets of a recording liquid onto a recording medium, wherein said recording liquid comprises in combination: at least one of C. I. Acid Red 131, C. I. Acid Red 274, C. I. Direct Red 227 and C. I. Direct Red 9; and a dye represented by the formula (A) ##STR12## wherein R 1 and R 2 are independently selected from the group consisting a hydrogen atom, a methyl group, a methoxy group, a chloro group, a sulfonic acid group, ##STR13## X is a residual group of an organic acid; and M is a base selected from the group consisting of an alkali metal group, an ammonium group, and an organic amine group; and said recording medium is plain paper.
Claim 37
Dependent Claim 134 words
An ink jet recording method for performing color recording, comprising the step of imparting liquid droplets of a recording liquid onto a recording medium, wherein said recording liquid comprises in combination: at least one of C. I. Acid Red 131, C. I. Acid Red 274, C. I. Direct Red 227 and C. I. Direct Red 9; and a dye represented by the formula (A) ##STR12## wherein R 1 and R 2 are independently selected from the group consisting a hydrogen atom, a methyl group, a methoxy group, a chloro group, a sulfonic acid group, ##STR13## X is a residual group of an organic acid; and M is a base selected from the group consisting of an alkali metal group, an ammonium group, and an organic amine group; and said recording medium is plain paper.
Claim 38
Dependent Claim 23 words
The ink jet recording method according to claim 33, wherein said imparting step is performed with an on-demand type of ink jet system.
Claim 39
Dependent Claim 26 words
The ink jet recording method according to claim 33; further comprising the step of applying heat energy to the recording liquid to form the liquid droplets.
Claim 40
Dependent Claim 147 words
An ink jet recording method for performing color recording, comprising the step of imparting liquid droplets of a recording liquid onto a recording medium, wherein said recording liquid comprises: a magenta component and a yellow component, wherein said magenta component is composed of a dye represented by the formula (A) ##STR14## wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, a methyl group, a methoxy group, a chloro group, a sulfonic acid group, ##STR15## X is a residual group of an organic acid; and M is a base selected from the group consisting of an alkali metal group, an ammonium group, and an organic amine group; and C.I. Direct Red 227; wherein said yellow component is composed of at least one of C.I. Direct Yellow 86 and C.I. Direct Yellow 142; and wherein said recording medium is plain paper.
Claim 41
Dependent Claim 147 words
An ink jet recording method for performing color recording, comprising the step of imparting liquid droplets of a recording liquid onto a recording medium, wherein said recording liquid comprises: a magenta component and a yellow component, wherein said magenta component is composed of a dye represented by the formula (A) ##STR14## wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, a methyl group, a methoxy group, a chloro group, a sulfonic acid group, ##STR15## X is a residual group of an organic acid; and M is a base selected from the group consisting of an alkali metal group, an ammonium group, and an organic amine group; and C.I. Direct Red 227; wherein said yellow component is composed of at least one of C.I. Direct Yellow 86 and C.I. Direct Yellow 142; and wherein said recording medium is plain paper.
Claim 42
Dependent Claim 23 words
The ink jet recording method according to claim 36, wherein said imparting step is performed with an on-demand type of ink jet system.
Claim 43
Dependent Claim 26 words
The ink jet recording method according to claim 36, further comprising the step of applying heat energy to the recording liquid to form the liquid droplets.
Claim 44
Dependent Claim 150 words
An ink jet recording method for performing color recording, comprising the step of imparting liquid droplets of a recording liquid onto a recording medium, wherein said recording liquid comprises: a magenta component and a cyan component, wherein said magenta component is composed of a dye represented by the formula (A) ##STR16## wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, a methyl group, a methoxy group, a chloro group, a sulfonic acid group, ##STR17## X is a residual group of an organic acid; and M is a base selected from the group consisting of an alkali metal group, an ammonium group, and an organic amine group; and C.I. Direct Red 227; wherein said cyan component is composed of at least one of C.I. Direct Blue 199, C.I. Blue 86 and C.I. Acid Blue 198; and wherein said recording medium is plain paper.
Claim 45
Dependent Claim 150 words
An ink jet recording method for performing color recording, comprising the step of imparting liquid droplets of a recording liquid onto a recording medium, wherein said recording liquid comprises: a magenta component and a cyan component, wherein said magenta component is composed of a dye represented by the formula (A) ##STR16## wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, a methyl group, a methoxy group, a chloro group, a sulfonic acid group, ##STR17## X is a residual group of an organic acid; and M is a base selected from the group consisting of an alkali metal group, an ammonium group, and an organic amine group; and C.I. Direct Red 227; wherein said cyan component is composed of at least one of C.I. Direct Blue 199, C.I. Blue 86 and C.I. Acid Blue 198; and wherein said recording medium is plain paper.
Claim 46
Dependent Claim 23 words
The ink jet recording method according to claim 39, wherein said imparting step is performed with an on-demand type of ink jet system.
Claim 47
Dependent Claim 26 words
The ink jet recording method according to claim 39, further comprising the step of applying heat energy to the recording liquid to form the liquid droplets.
Claim 48
Dependent Claim 143 words
An ink jet device comprising an ink storing member impregnated with a recording liquid comprising in combination: at least one of C.I. Acid Red 131, C.I. Acid Red 274, C.I. Direct Red 227 and C.I. Direct Red 9; and a dye represented by the formula (A), ##STR18## wherein R 1 and R 2 are independently selected from the group consisting a hydrogen atom, a methyl group, a methoxy group, a chloro group, a sulfonic acid group, ##STR19## X is a residual group of an organic acid; and M is a base selected from the group consisting of an alkali metal group, an ammonium group, and an organic amine group; "wherein said dye represented by the Formula (A) comprises 20% to 80% of the total weight of the dyes;" and a head having a plurality of orifices for discharging said ink as ink droplets.
Claim 49
Dependent Claim 143 words
An ink jet device comprising an ink storing member impregnated with a recording liquid comprising in combination: at least one of C.I. Acid Red 131, C.I. Acid Red 274, C.I. Direct Red 227 and C.I. Direct Red 9; and a dye represented by the formula (A), ##STR18## wherein R 1 and R 2 are independently selected from the group consisting a hydrogen atom, a methyl group, a methoxy group, a chloro group, a sulfonic acid group, ##STR19## X is a residual group of an organic acid; and M is a base selected from the group consisting of an alkali metal group, an ammonium group, and an organic amine group; "wherein said dye represented by the Formula (A) comprises 20% to 80% of the total weight of the dyes;" and a head having a plurality of orifices for discharging said ink as ink droplets.
Claim 50
Dependent Claim 21 words
An ink jet device according to claim 42, wherein said ink storing member is an ink absorber or an ink bag.
Claim 51
Dependent Claim 27 words
An ink jet device according to claim 42, wherein said head has a heating head to provide to said ink a heat energy for discharging ink droplets.
Claim 52
Dependent Claim 175 words
An ink jet device comprising an ink storing member impregnated with a recording liquid comprising a magenta component and a yellow component, wherein said magenta component is composed of a dye represented by the formula (A), ##STR20## wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, a methyl group, a methoxy group, a chloro group, a sulfonic acid group, ##STR21## X is a residual group of an organic acid; and M is a base selected from the group consisting of an alkali metal group, an ammonium group, and an organic amine group; and C.I. Direct Red 227; wherein said yellow component is composed of at least one of C.I. Direct Yellow 86 and C.I. Direct Yellow 142; wherein the dye represented by the Formula (A) comprises 20% to 70% of the total weight of the dyes and C.I. Direct Red 227 comprises 20% to 60% of the total weight of the dyes; and a head having a plurality of orifices for discharging said ink as ink droplets.
Claim 53
Dependent Claim 175 words
An ink jet device comprising an ink storing member impregnated with a recording liquid comprising a magenta component and a yellow component, wherein said magenta component is composed of a dye represented by the formula (A), ##STR20## wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, a methyl group, a methoxy group, a chloro group, a sulfonic acid group, ##STR21## X is a residual group of an organic acid; and M is a base selected from the group consisting of an alkali metal group, an ammonium group, and an organic amine group; and C.I. Direct Red 227; wherein said yellow component is composed of at least one of C.I. Direct Yellow 86 and C.I. Direct Yellow 142; wherein the dye represented by the Formula (A) comprises 20% to 70% of the total weight of the dyes and C.I. Direct Red 227 comprises 20% to 60% of the total weight of the dyes; and a head having a plurality of orifices for discharging said ink as ink droplets.
Claim 54
Dependent Claim 20 words
An ink device according to claim 45, wherein said ink storing member is an ink absorber or an ink bag.
Claim 55
Dependent Claim 27 words
An ink jet device according to claim 45, wherein said head has a heating head to provide to said ink a heat energy for discharging ink droplets.
Claim 56
Dependent Claim 180 words
An ink jet device comprising an ink storing member impregnated with a recording liquid comprising a magenta component and a cyan component, wherein said magenta component is composed of a dye represented by the formula (A) ##STR22## wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, a methyl group, a methoxy group, a chloro group, a sulfonic acid group, ##STR23## X is a residual group of an organic acid; and M is a base selected from the group consisting of an alkali metal group, an ammonium group, and an organic amine group; and C.I. Direct Red 227; wherein said cyan component is composed of at least one of C.I. Direct Blue 199, C.I. Direct Blue 86 and C.I. Acid Blue 198; wherein the dye represented by the Formula (A) comprises 2% to 50% of the total weight of the dyes, and wherein C.I. Direct Red 227 comprises 5% to 30% of the total weight of the dyes; and a head having a plurality of orifices for discharging said ink as ink droplets.
Claim 57
Dependent Claim 180 words
An ink jet device comprising an ink storing member impregnated with a recording liquid comprising a magenta component and a cyan component, wherein said magenta component is composed of a dye represented by the formula (A) ##STR22## wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, a methyl group, a methoxy group, a chloro group, a sulfonic acid group, ##STR23## X is a residual group of an organic acid; and M is a base selected from the group consisting of an alkali metal group, an ammonium group, and an organic amine group; and C.I. Direct Red 227; wherein said cyan component is composed of at least one of C.I. Direct Blue 199, C.I. Direct Blue 86 and C.I. Acid Blue 198; wherein the dye represented by the Formula (A) comprises 2% to 50% of the total weight of the dyes, and wherein C.I. Direct Red 227 comprises 5% to 30% of the total weight of the dyes; and a head having a plurality of orifices for discharging said ink as ink droplets.
Claim 58
Dependent Claim 21 words
An ink jet device according to claim 48, wherein said ink storing member is an ink absorber or an ink bag.
Claim 59
Dependent Claim 27 words
An ink jet device according to claim 48, wherein said head has a heating head to provide to said ink a heat energy for discharging ink droplets.
Claim 60
Dependent Claim 150 words
An ink jet recording apparatus comprising an ink jet device comprising an ink storing member impregnated with a recording liquid comprising in combination: at least one of C.I. Acid Red 131, C.I. Acid Red 274, C.I. Direct Red 227 and C.I. Direct Red 9; and a dye represented by the formula (A) ##STR24## wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, a methyl group, a methoxy group, a chloro group, a sulfonic acid group, ##STR25## X is a residual group of an organic acid; and M is a base selected from the group consisting of an alkali metal group, an ammonium group, and an organic amine group; wherein said dye represented by the Formula (A) comprises 20% to 80% of the total weight of the dyes; and a head having a plurality of orifices for discharging said ink as ink droplets.
Claim 61
Dependent Claim 150 words
An ink jet recording apparatus comprising an ink jet device comprising an ink storing member impregnated with a recording liquid comprising in combination: at least one of C.I. Acid Red 131, C.I. Acid Red 274, C.I. Direct Red 227 and C.I. Direct Red 9; and a dye represented by the formula (A) ##STR24## wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, a methyl group, a methoxy group, a chloro group, a sulfonic acid group, ##STR25## X is a residual group of an organic acid; and M is a base selected from the group consisting of an alkali metal group, an ammonium group, and an organic amine group; wherein said dye represented by the Formula (A) comprises 20% to 80% of the total weight of the dyes; and a head having a plurality of orifices for discharging said ink as ink droplets.
Claim 62
Dependent Claim 22 words
An ink jet recording apparatus according to claim 51, wherein said ink storing member is an ink absorber or an ink bag.
Claim 63
Dependent Claim 28 words
An ink jet recording apparatus according to claim 51, wherein said head has a heating head to provide to said ink a heat energy for discharging ink droplets.
Claim 64
Dependent Claim 181 words
An ink jet recording apparatus comprising an ink jet device comprising an ink storing member impregnated with a recording liquid comprising a magenta component and a yellow component, wherein said magenta component is composed of a dye represented by the formula (A), ##STR26## wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, a methyl group, a methoxy group, a chloro group, a sulfonic acid group, ##STR27## X is a residual group of an organic acid; and M is a base selected from the group consisting of an alkali metal group, an ammonium group, and an organic amine group; and C.I. Direct Red 227; wherein said yellow component is composed of at least one of C.I. Direct Yellow 86 and C.I. Direct Yellow 142; wherein the dye represented by the Formula (A) comprises 20% to 70% of the total weight of the dyes and C.I. Direct Red 227 comprises 20% to 60% of the total weight of the dyes; and a head having a plurality of orifices for discharging said ink as ink droplets.
Claim 65
Dependent Claim 181 words
An ink jet recording apparatus comprising an ink jet device comprising an ink storing member impregnated with a recording liquid comprising a magenta component and a yellow component, wherein said magenta component is composed of a dye represented by the formula (A), ##STR26## wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, a methyl group, a methoxy group, a chloro group, a sulfonic acid group, ##STR27## X is a residual group of an organic acid; and M is a base selected from the group consisting of an alkali metal group, an ammonium group, and an organic amine group; and C.I. Direct Red 227; wherein said yellow component is composed of at least one of C.I. Direct Yellow 86 and C.I. Direct Yellow 142; wherein the dye represented by the Formula (A) comprises 20% to 70% of the total weight of the dyes and C.I. Direct Red 227 comprises 20% to 60% of the total weight of the dyes; and a head having a plurality of orifices for discharging said ink as ink droplets.
Claim 66
Dependent Claim 22 words
An ink jet recording apparatus according to claim 54, wherein said ink storing member is an ink absorber or an ink bag.
Claim 67
Dependent Claim 28 words
An ink jet recording apparatus according to claim 54, wherein said head has a heating head to provide to said ink a heat energy for discharging ink droplets.
Claim 68
Dependent Claim 186 words
An ink jet recording apparatus comprising an ink jet device comprising an ink storing member impregnated with a recording liquid comprising a magenta component and a cyan component, wherein said magenta component is composed of a dye represented by the formula (A), ##STR28## wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, a methyl group, a methoxy group, a chloro group, a sulfonic acid group, ##STR29## X is a residual group of an organic acid; and M is a base selected from the group consisting of an alkali metal group, an ammonium group, and an organic amine group; and C.I. Direct Red 227; wherein said cyan component is composed of at least one of C.I. Direct Blue 199, C.I. Direct Blue 86 and C.I. Acid Blue 198; wherein the dye represented by the Formula (A) comprises 2% to 50% of the total weight of the dyes, and wherein C.I. Direct Red 227 comprises 5% to 30% of the total weight of the dyes; and a head having a plurality of orifices for discharging said ink as ink droplets.
Claim 69
Dependent Claim 186 words
An ink jet recording apparatus comprising an ink jet device comprising an ink storing member impregnated with a recording liquid comprising a magenta component and a cyan component, wherein said magenta component is composed of a dye represented by the formula (A), ##STR28## wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, a methyl group, a methoxy group, a chloro group, a sulfonic acid group, ##STR29## X is a residual group of an organic acid; and M is a base selected from the group consisting of an alkali metal group, an ammonium group, and an organic amine group; and C.I. Direct Red 227; wherein said cyan component is composed of at least one of C.I. Direct Blue 199, C.I. Direct Blue 86 and C.I. Acid Blue 198; wherein the dye represented by the Formula (A) comprises 2% to 50% of the total weight of the dyes, and wherein C.I. Direct Red 227 comprises 5% to 30% of the total weight of the dyes; and a head having a plurality of orifices for discharging said ink as ink droplets.
Claim 70
Dependent Claim 22 words
An ink jet recording apparatus according to claim 57, wherein said ink storing member is an ink absorber or an ink bag.
Claim 71
Dependent Claim 28 words
An ink jet recording apparatus according to claim 57, wherein said head has a heating head to provide to said ink a heat energy for discharging ink droplets.
Claim 72
Dependent Claim 126 words
An ink cartridge comprising an ink bag impregnated with a recording liquid comprising in combination: at least one of C.I. Acid Red 131, C.I. Acid Red 274, C.I. Direct Red 227 and C.I. Direct Red 9; and a dye represented by the formula (A), ##STR30## wherein R 1 and R 2 are independently selected from the group consisting a hydrogen atom, a methyl group, a methoxy group, a chloro group, a sulfonic acid group, ##STR31## X is a residual group of an organic acid; and M is a base selected from the group consisting of an alkali metal group, an ammonium group, and an organic amine group wherein said dye represented by the Formula (A) comprises 20% to 80% of the total weight of the dyes.
Claim 73
Dependent Claim 126 words
An ink cartridge comprising an ink bag impregnated with a recording liquid comprising in combination: at least one of C.I. Acid Red 131, C.I. Acid Red 274, C.I. Direct Red 227 and C.I. Direct Red 9; and a dye represented by the formula (A), ##STR30## wherein R 1 and R 2 are independently selected from the group consisting a hydrogen atom, a methyl group, a methoxy group, a chloro group, a sulfonic acid group, ##STR31## X is a residual group of an organic acid; and M is a base selected from the group consisting of an alkali metal group, an ammonium group, and an organic amine group wherein said dye represented by the Formula (A) comprises 20% to 80% of the total weight of the dyes.
Claim 74
Dependent Claim 28 words
The ink cartridge according to claim 60, wherein said recording liquid comprises a liquid medium, and said liquid medium comprises a polyhydric alcohol or an aliphatic monovalent alcohol.
Claim 75
Dependent Claim 26 words
The ink cartridge according to claim 61, wherein said polyhydric alcohol is at least one selected from the group consisting of ethylene glycol, thiodiglycol, and glycerol.
Claim 76
Dependent Claim 18 words
The ink cartridge according to claim 62, wherein said liquid medium contains water and a water-soluble organic solvent.
Claim 77
Dependent Claim 25 words
The ink cartridge according to claim 63, wherein the content of said water is in the range of 10-95% by weight of the recording liquid.
Claim 78
Dependent Claim 25 words
The ink cartridge according to claim 63, wherein the content of said water is in the range of 70-95% by weight of the recording liquid.
Claim 79
Dependent Claim 27 words
The ink cartridge according to claim 63, wherein the content of said water-soluble organic solvent is in the range of 1-50% by weight of the recording liquid.
Claim 80
Dependent Claim 27 words
The ink cartridge according to claim 63, wherein the content of said water-soluble organic solvent is in the range of 5-30% by weight of the recording liquid.
Claim 81
Dependent Claim 159 words
An ink cartridge comprising an ink bag impregnated with a recording liquid comprising a magenta component and a yellow component, wherein said magenta component is composed of a dye represented by the formula (A), ##STR32## wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, a methyl group, a methoxy group, a chloro group, a sulfonic acid group, ##STR33## X is a residual group of an organic acid; and M is a base selected from the group consisting of an alkali metal group, an ammonium group, and an organic amine group; and C.I. Direct Red 227; wherein said yellow component is composed of at least one of C.I. Direct Yellow 86 and C.I. Direct Yellow 142 and wherein the dye represented by the Formula (A) comprises 20% to 70% of the total weight of the dyes and C.I. Direct Red 227 comprises 20% to 60% of the total weight of the dyes.
Claim 82
Dependent Claim 159 words
An ink cartridge comprising an ink bag impregnated with a recording liquid comprising a magenta component and a yellow component, wherein said magenta component is composed of a dye represented by the formula (A), ##STR32## wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, a methyl group, a methoxy group, a chloro group, a sulfonic acid group, ##STR33## X is a residual group of an organic acid; and M is a base selected from the group consisting of an alkali metal group, an ammonium group, and an organic amine group; and C.I. Direct Red 227; wherein said yellow component is composed of at least one of C.I. Direct Yellow 86 and C.I. Direct Yellow 142 and wherein the dye represented by the Formula (A) comprises 20% to 70% of the total weight of the dyes and C.I. Direct Red 227 comprises 20% to 60% of the total weight of the dyes.
Claim 83
Dependent Claim 28 words
The ink cartridge according to claim 68, wherein said recording liquid comprises a liquid medium, and said liquid medium comprises a polyhydric alcohol or an aliphatic monovalent alcohol.
Claim 84
Dependent Claim 26 words
The ink cartridge according to claim 69, wherein said polyhydric alcohol is at least one selected from the group consisting of ethylene glycol, thiodiglycol, and glycerol.
Claim 85
Dependent Claim 18 words
The ink cartridge according to claim 69, wherein said liquid medium contains water and a water-soluble organic solvent.
Claim 86
Dependent Claim 25 words
The ink cartridge according to claim 71, wherein the content of said water is in the range of 10-95% by weight of the recording liquid.
Claim 87
Dependent Claim 25 words
The ink cartridge according to claim 71, wherein the content of said water is in the range of 70-95% by weight of the recording liquid.
Claim 88
Dependent Claim 27 words
The ink cartridge according to claim 71, wherein the content of said water-soluble organic solvent is in the range of 1-50% by weight of the recording liquid.
Claim 89
Dependent Claim 27 words
The ink cartridge according to claim 71, wherein the content of said water-soluble organic solvent is in the range of 5-30% by weight of the recording liquid.
Claim 90
Dependent Claim 164 words
An ink cartridge comprising an ink bag impregnated with a recording liquid comprising a magenta component and a cyan component, wherein said magenta component is composed of a dye represented by the formula (A), ##STR34## wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, a methyl group, a methoxy group, a chloro group, a sulfonic acid group, ##STR35## X is a residual group of an organic acid; and M is a base selected from the group consisting of an alkali metal group, an ammonium group, and an organic amine group; and C.I. Direct Red 227; wherein said cyan component is composed of at least one of C.I. Direct Blue 199, C.I. Direct Blue 86 and C.I. Acid Blue 198 and wherein the dye represented by the Formula (A) comprises 2% to 50% of the total weight of the dyes, and wherein C.I. Direct Red 227 comprises 5% to 30% of the total weight of the dyes.
Claim 91
Dependent Claim 164 words
An ink cartridge comprising an ink bag impregnated with a recording liquid comprising a magenta component and a cyan component, wherein said magenta component is composed of a dye represented by the formula (A), ##STR34## wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, a methyl group, a methoxy group, a chloro group, a sulfonic acid group, ##STR35## X is a residual group of an organic acid; and M is a base selected from the group consisting of an alkali metal group, an ammonium group, and an organic amine group; and C.I. Direct Red 227; wherein said cyan component is composed of at least one of C.I. Direct Blue 199, C.I. Direct Blue 86 and C.I. Acid Blue 198 and wherein the dye represented by the Formula (A) comprises 2% to 50% of the total weight of the dyes, and wherein C.I. Direct Red 227 comprises 5% to 30% of the total weight of the dyes.
Claim 92
Dependent Claim 28 words
The ink cartridge according to claim 76, wherein said recording liquid comprises a liquid medium, and said liquid medium comprises a polyhydric alcohol or an aliphatic monovalent alcohol.
Claim 93
Dependent Claim 26 words
The ink cartridge according to claim 77, wherein said polyhydric alcohol is at least one selected from the group consisting of ethylene glycol, thiodiglycol, and glycerol.
Claim 94
Dependent Claim 18 words
The ink cartridge according to claim 77, wherein said liquid medium contains water and a water-soluble organic solvent.
Claim 95
Dependent Claim 25 words
The ink cartridge according to claim 79, wherein the content of said water is in the range of 10-95% by weight of the recording liquid.
Claim 96
Dependent Claim 25 words
The ink cartridge according to claim 79, wherein the content of said water is in the range of 70-95% by weight of the recording liquid.
Claim 97
Dependent Claim 27 words
The ink cartridge according to claim 79, wherein the content of said water-soluble organic solvent is in the range of 1-50% by weight of the recording liquid.
Claim 98
Dependent Claim 27 words
The ink cartridge according to claim 79, wherein the content of said water-soluble organic solvent is in the range of 5-30% by weight of the recording liquid.

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-08-04 1996-02-03 1996-08-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-08-04 2000-02-03 2000-08-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-08-04 2004-02-03 2004-08-04 $7700.00 Window Closed / Lapsed

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