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US5134183A Expired / Lapsed US ⏱️ 0.0 years remaining

Sterically hindered oxime color improvers for polyolefin processing

Assignee: Novartis Corp
•
Filing: 1990-10-22
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Granted: 1992-07-28
•
Expires: 2010-10-22
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Abstract

Abstract Sterically hindered oximes provide polyolefin compositions, including those also containing a phenolic antioxidant, with improved resistance to discoloration during processing at elevated temperatures.

Inventors

  • 👤 Stephen D. Pastor
  • 👤 Paul A. Odorisio

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 09:34
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/16; C08K5/32; C08K5/33; C07; C07C; C07C251/00; C07C251/32; C07C251/34; C07C251/36; C07C251/38

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 316 words
A polyolefin composition stabilized against discoloration during processing at elevated temperature which consists essentially of (a) polyethylene or polypropylene, and (b) an effective stabilizing amount of a compound of formula I ##STR2## wherein R 1 is a tert-alkyl group of 4 to 18 carbon atoms, aryl of 6 to 10 carbon atoms or said aryl substituted by one or two alkyl of 1 to 4 carbon atoms or by one or two alkoxy of 1 to 4 carbon atoms, R 2 and R 3 are independently alkyl of 1 to 18 carbon atoms, cycloalkyl of 5 to 12 carbon atoms, phenylalkyl of 7 to 9 carbon atoms, aryl of 6 to 10 carbon atoms, or said aryl or said phenylalkyl substituted on the phenyl ring by one or two alkyl of 1 to 4 carbon atoms or by one or two alkoxy of 1 to 4 carbon atoms; or R 2 and R 3 together are a straight or branched chain alkylene of 4 to 10 carbon atoms, n is an integer from 1 to 4, when n is 1, T is alkyl of 1 to 18 carbon atoms, cycloalkyl of 5 to 12 carbon atoms, phenylalkyl of 7 to 9 carbon atoms, aryl of 6 to 10 carbon atoms, or said aryl or said phenylalkyl substituted on the phenyl ring by one or two alkyl of 1 to 4 carbon atoms or by one or two alkoxy of 1 to 4 carbon atoms, when n is 2, T is alkylene of 2 to 12 carbon atoms, xylylene, arylene of 6 to 10 carbon atoms or said arylene substituted by one or two alkyl of 1 to 4 carbon atoms or by one or two alkoxy of 1 to 4 carbon atoms, and when n is 3 or 4, T is alkanetriyl of 3 to 10 carbon atoms, or alkanetetrayl of 4 to 10 carbon atoms.
Claim 2
Dependent Claim 316 words
A polyolefin composition stabilized against discoloration during processing at elevated temperature which consists essentially of (a) polyethylene or polypropylene, and (b) an effective stabilizing amount of a compound of formula I ##STR2## wherein R 1 is a tert-alkyl group of 4 to 18 carbon atoms, aryl of 6 to 10 carbon atoms or said aryl substituted by one or two alkyl of 1 to 4 carbon atoms or by one or two alkoxy of 1 to 4 carbon atoms, R 2 and R 3 are independently alkyl of 1 to 18 carbon atoms, cycloalkyl of 5 to 12 carbon atoms, phenylalkyl of 7 to 9 carbon atoms, aryl of 6 to 10 carbon atoms, or said aryl or said phenylalkyl substituted on the phenyl ring by one or two alkyl of 1 to 4 carbon atoms or by one or two alkoxy of 1 to 4 carbon atoms; or R 2 and R 3 together are a straight or branched chain alkylene of 4 to 10 carbon atoms, n is an integer from 1 to 4, when n is 1, T is alkyl of 1 to 18 carbon atoms, cycloalkyl of 5 to 12 carbon atoms, phenylalkyl of 7 to 9 carbon atoms, aryl of 6 to 10 carbon atoms, or said aryl or said phenylalkyl substituted on the phenyl ring by one or two alkyl of 1 to 4 carbon atoms or by one or two alkoxy of 1 to 4 carbon atoms, when n is 2, T is alkylene of 2 to 12 carbon atoms, xylylene, arylene of 6 to 10 carbon atoms or said arylene substituted by one or two alkyl of 1 to 4 carbon atoms or by one or two alkoxy of 1 to 4 carbon atoms, and when n is 3 or 4, T is alkanetriyl of 3 to 10 carbon atoms, or alkanetetrayl of 4 to 10 carbon atoms.
Claim 3
Dependent Claim 11 words
A composition according to claim 1 wherein the polyolefin is polypropylene.
Claim 4
Dependent Claim 50 words
A composition according to claim 1 where in the compound of formula I, R 1 is tert-alkyl of 4 to 8 carbon atoms, phenyl or phenyl substituted by one or two alkyl of 1 to 2 carbon atoms or by one or two alkoxy of 1 to 2 carbon atoms.
Claim 5
Dependent Claim 26 words
A composition according to claim 3 wherein R 1 is tert-butyl, phenyl or phenyl substituted by one or two methyl or by one or two methoxy.
Claim 6
Dependent Claim 27 words
A composition according to claim 1 where in the compound of formula I, R 2 and R 3 are independently alkyl of 1 to 8 carbon atoms.
Claim 7
Dependent Claim 14 words
A composition according to claim 5 wherein R 2 and R 3 are methyl.
Claim 8
Dependent Claim 18 words
A composition according to claim 1 where in the compound of formula I, n is 1 or 2.
Claim 9
Dependent Claim 28 words
A composition according to claim 1 where in the compound of formula I, when n is 1, T is alkyl of 8 to 18 carbon atoms or benzyl.
Claim 10
Dependent Claim 16 words
A composition according to claim 8 wherein T is alkyl of 12 to 18 carbon atoms.
Claim 11
Dependent Claim 10 words
A composition according to claim 9 wherein T is n-octadecyl.
Claim 12
Dependent Claim 26 words
A composition according to claim 1 where in the compound of formula I, when n is 2, T is alkylene of 2 to 10 carbon atoms.
Claim 13
Dependent Claim 16 words
A composition according to claim 11 wherein T is alkylene of 4 to 8 carbon atoms.
Claim 14
Dependent Claim 10 words
A composition according to claim 12 wherein T is hexamethylene.
Claim 15
Dependent Claim 23 words
A composition according to claim 1 wherein the compound of formula I is di-tert-butyl ketoxime; tert-butyl 2-methyleicosan-2-yl ketooxime; 2,2,4,4,11,11,13,13-octamethyl-3,12-dioximinotetradecane; or tert-butyl 3,4-dimethoxyphenyl ketooxime.

References Cited (Backward Citations)

US2497061A Cited
US3256331A Cited
US4152531A Cited
CA1053668A Cited
US4028412A Cited
US4316996A Cited
EP0052573A1 Cited
US4576628A Cited
US4566901A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-07-28 1996-01-27 1996-07-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-07-28 2000-01-27 2000-07-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-07-28 2004-01-27 2004-07-28 $7700.00 Window Closed / Lapsed

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