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US5122906A Expired / Lapsed US ⏱️ 0.0 years remaining

Thick/very thin multilayer reflective polymeric body

Assignee: 3M Innovative Properties Co
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Filing: 1990-01-17
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Granted: 1992-06-16
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Expires: 2010-01-17
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Abstract

Abstract A multilayered reflective body which is thermoformable and capable of being fabricated into films, sheets, and a variety of parts while maintaining a uniform reflective appearance is provided. The reflective polymeric body includes at least first and second diverse polymeric materials of a sufficient number of alternating layers of the first and second polymeric materials such that at least 30% of the light incident on the body is reflected. A substantial majority of the individual layers of the body have an optical thickness of not more than 0.09 micrometers or not less than 0.45 micrometers, with at least one of the individual layers having an optical thickness of not more than 0.09 micrometers, and adjacent layers of the first and second polymeric materials differ from each other in refractive index by at least about 0.03.

Inventors

  • 👤 John A. Wheatley

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 10:56
CPC Classifications
B; B32; B32B; B32B27/00; B32B27/06; B32B27/08; B32B27/18; B32B27/20; B32B27/34; B32B27/40; B32B33/00; B32B7/00; B32B7/02; B32B7/023; B44; B44C; B44C5/00; B44C5/08; G; G02; G02B; G02B1/00; G02B1/04; G02B1/08; G02B5/00; G02B5/08; G02B5/0816; G02B5/0825; G02B5/0841; G02B5/0883; G02B5/20; G02B5/26; G02B5/30; G02B5/3025; G02B5/3033; G02B5/3041; G02B5/305; H; H10; H10F; H10F77/00; H10F77/40; H10F77/42; H10F77/48; B32B2250/00; B32B2250/40; B32B2307/00; B32B2307/40; B32B2307/416; B32B2375/00; B32B2377/00; G02F; G02F1/00; G02F1/01; G02F1/13; G02F1/133; G02F1/1333; G02F1/1335; G02F1/133528; G02F1/133545; Y; Y02; Y02E; Y02E10/00; Y02E10/50; Y02E10/52; Y10; Y10T; Y10T428/00; Y10T428/24; Y10T428/24942; Y10T428/2495

Claims Analysis

Total Claims: 39
Claim 1
Independent Claim 167 words
A reflective polymeric body of first and second diverse polymeric materials, the body comprising a sufficient number of alternating layers of said first and second polymeric materials such that at least 30% of light incident on said body is reflected, where the intensity of the reflected light is governed by the equation R=(kr)/1+(k-1)r×100, where R is the amount of reflected light (%), k is the number of thick and very thin film layers, and r=((N 1 -N 2 )/(N 1 +N 2 )) 2 , and N 1 and N 2 are the refractive indices of said polymeric materials at each layer interface, a substantial majority of the individual layers of said body having an optical thickness of not more than 0.09 micrometers or not less than 0.45 micrometers, with at least one of said individual layers having an optical thickness of not more than 0.09 micrometers, and wherein said first and second polymeric materials differ from each other in refractive index by at least about 0.03.
Claim 2
Dependent Claim 167 words
A reflective polymeric body of first and second diverse polymeric materials, the body comprising a sufficient number of alternating layers of said first and second polymeric materials such that at least 30% of light incident on said body is reflected, where the intensity of the reflected light is governed by the equation R=(kr)/1+(k-1)r×100, where R is the amount of reflected light (%), k is the number of thick and very thin film layers, and r=((N 1 -N 2 )/(N 1 +N 2 )) 2 , and N 1 and N 2 are the refractive indices of said polymeric materials at each layer interface, a substantial majority of the individual layers of said body having an optical thickness of not more than 0.09 micrometers or not less than 0.45 micrometers, with at least one of said individual layers having an optical thickness of not more than 0.09 micrometers, and wherein said first and second polymeric materials differ from each other in refractive index by at least about 0.03.
Claim 3
Dependent Claim 116 words
A reflective polymeric body of at least first and second diverse polymeric materials, the body comprising a sufficient number of alternating layers of said first and second polymeric materials such that at least 30% of light incident on said body is reflected, but such that essentially no visibly perceived iridescence is reflected, a substantial majority of the individual layers of said body having an optical thickness of not more than 0.09 micrometers or not less than 0.45 micrometers, with at least one of said individual layers having an optical thickness of not more than 0.09 micrometers, and wherein said first and second polymeric materials differ from each other in refractive index by at least about 0.03.
Claim 4
Dependent Claim 116 words
A reflective polymeric body of at least first and second diverse polymeric materials, the body comprising a sufficient number of alternating layers of said first and second polymeric materials such that at least 30% of light incident on said body is reflected, but such that essentially no visibly perceived iridescence is reflected, a substantial majority of the individual layers of said body having an optical thickness of not more than 0.09 micrometers or not less than 0.45 micrometers, with at least one of said individual layers having an optical thickness of not more than 0.09 micrometers, and wherein said first and second polymeric materials differ from each other in refractive index by at least about 0.03.
Claim 5
Dependent Claim 23 words
The reflective polymeric body of claim 2 in which said first polymeric material is polycarbonate and said second polymeric material is polymethyl methacrylate.
Claim 6
Dependent Claim 25 words
The reflective polymeric body of claim 2 in which said first polymeric material is a rigid polyurethane and said second polymeric material is polymethyl methacrylate.
Claim 7
Dependent Claim 26 words
The reflective polymeric body of claim 2 in which said first polymeric material is a flexible polyurethane and said second polymeric material is a polyether amide.
Claim 8
Dependent Claim 16 words
The reflective polymeric body of claim 2 in which said body comprises at least 500 layers.
Claim 9
Dependent Claim 14 words
The reflective polymeric body of claim 2 in which said polymeric body is thermoformable.
Claim 10
Dependent Claim 21 words
The reflective polymeric body of claim 2 including a coloring agent incorporated into at least one layer of said polymeric body.
Claim 11
Dependent Claim 22 words
The reflective polymeric body of claim 8 in which said coloring agent is selected from a group consisting of pigments and dyes.
Claim 12
Dependent Claim 24 words
The reflective polymeric body of claim 9 in which said coloring agent is incorporated into at least one surface layer of said polymeric body.
Claim 13
Dependent Claim 24 words
The reflective polymeric body of claim 9 in which said coloring agent is incorporated into at least one interior layer of said polymeric body.
Claim 14
Dependent Claim 20 words
The reflective polymeric body of claim 2 in which a least one surface layer has a brushed or roughened surface.
Claim 15
Dependent Claim 24 words
The reflective polymeric body of claim 2 in which at least one surface layer has been etched to provide a matte or pewter finish.
Claim 16
Dependent Claim 17 words
The reflective polymeric body of claim 2 in which at least one surface layer has been embossed.
Claim 17
Dependent Claim 17 words
The reflective polymeric body of claim 2 in which said first and second polymeric materials are elastomers.
Claim 18
Dependent Claim 52 words
The reflective polymeric body of claim 2 in which a substantial majority of the individual layers of said first polymeric material have an optical thickness of at least 0.45 micrometers and a substantial majority of the individual layers of said second polymeric material have an optical thickness of 0.09 micrometers or less.
Claim 19
Dependent Claim 30 words
The reflective polymeric body of claim 16 in which at least 75% of said individual layers of said first polymeric material have an optical thickness of at least 0.45 micrometers.
Claim 20
Dependent Claim 30 words
The reflective polymeric body of claim 16 in which at least 75% of said individual layers of said second polymeric material have an optical thickness of 0.09 micrometers or less.
Claim 21
Dependent Claim 16 words
The reflective polymeric body of claim 2 in which said body is extruded as a profile.
Claim 22
Dependent Claim 18 words
The reflective polymeric body of claim 19 in which said body is in the form of a tube.
Claim 23
Dependent Claim 17 words
The reflective polymeric body of claim 2 in which said body is post formed into a profile.
Claim 24
Dependent Claim 15 words
The reflective polymeric body of claim 2 in which said body is a blow-molded container.
Claim 25
Dependent Claim 23 words
The reflective polymeric body of claim 2 in which said polymeric body is in the form of a sheet having two major surface.
Claim 26
Dependent Claim 24 words
The reflective polymeric body of claim 23 in which said body includes a permanent protective skin layer on at least one major surface thereof.
Claim 27
Dependent Claim 19 words
The reflective polymeric body of claim 2 which includes a barrier layer as an exterior layer of said body.
Claim 28
Dependent Claim 27 words
The reflective polymeric body of claim 2 in which said polymeric body includes first, second, and third diverse polymeric materials of alternating layers in a pattern ABCBA.
Claim 29
Dependent Claim 33 words
The reflective polymeric body of claim 26 in which said first polymeric material is polystyrene, said second polymeric material is a styrene hydroxy ethylacrylate copolymer, and said third polymeric material is polymethyl methacrylate.
Claim 30
Dependent Claim 19 words
The reflective polymeric body of claim 2 which includes a barrier layer as an interior layer of said body.
Claim 31
Dependent Claim 169 words
A reflective polymeric film of at least first and second diverse polymeric materials, the film comprising a sufficient number of alternating layers of said first and second polymeric materials such that at least 30% of light incident on said film is reflected, where the intensity of the reflected light is governed by the equation R=(kr)/(1+(k-1)r)×100, where R is the amount of reflected light (%), k is the number of thick and very thin film layers, and, r=((N 1 -N 2 )/(N 1 +N 2 )) 2 , and N 1 and N 2 are the refractive indices of said polymeric materials at each layer interface, a substantial majority of the individual layers of said film having an optical thickness of not more than 0.09 micrometers or not less than 0.45 micrometers, with at least one of said individual layers having an optical thickness of not more than 0.09 micrometers, and wherein said first and second polymeric materials differ from each other in refractive index by at least about 0.03.
Claim 32
Dependent Claim 169 words
A reflective polymeric film of at least first and second diverse polymeric materials, the film comprising a sufficient number of alternating layers of said first and second polymeric materials such that at least 30% of light incident on said film is reflected, where the intensity of the reflected light is governed by the equation R=(kr)/(1+(k-1)r)×100, where R is the amount of reflected light (%), k is the number of thick and very thin film layers, and, r=((N 1 -N 2 )/(N 1 +N 2 )) 2 , and N 1 and N 2 are the refractive indices of said polymeric materials at each layer interface, a substantial majority of the individual layers of said film having an optical thickness of not more than 0.09 micrometers or not less than 0.45 micrometers, with at least one of said individual layers having an optical thickness of not more than 0.09 micrometers, and wherein said first and second polymeric materials differ from each other in refractive index by at least about 0.03.
Claim 33
Dependent Claim 116 words
A mirror like polymeric article having at least first and second major surfaces, said article comprising a sufficient number of alternating layers of first and second polymeric materials such that at least 30% of light incident on said body is reflected, a substantial majority of the individual layers of said body having an optical thickness of not more than 0.09 micrometers or not less than 0.45 micrometers, with at least one of said individual layers having an optical thickness of not more than 0.09 micrometers, wherein said first and second polymeric materials differ from each other in refractive index by at least about 0.03, and wherein one of said major surfaces includes a light absorbent layer.
Claim 34
Dependent Claim 116 words
A mirror like polymeric article having at least first and second major surfaces, said article comprising a sufficient number of alternating layers of first and second polymeric materials such that at least 30% of light incident on said body is reflected, a substantial majority of the individual layers of said body having an optical thickness of not more than 0.09 micrometers or not less than 0.45 micrometers, with at least one of said individual layers having an optical thickness of not more than 0.09 micrometers, wherein said first and second polymeric materials differ from each other in refractive index by at least about 0.03, and wherein one of said major surfaces includes a light absorbent layer.
Claim 35
Dependent Claim 113 words
A mirror like polymeric article having at least first and second major surfaces, said article comprising a sufficient number of alternating layers of first and second polymeric materials such that at least 30% of light incident on said body is reflected, and at least one interior light absorbing layer, a substantial majority of the individual layers of said body having an optical thickness of not more than 0.09 micrometers or not less than 0.45 micrometers, with at least one of said individual layers having an optical thickness of not more than 0.09 micrometers, and wherein said first and second polymeric materials differ from each other in refractive index by at least about 0.03.
Claim 36
Dependent Claim 113 words
A mirror like polymeric article having at least first and second major surfaces, said article comprising a sufficient number of alternating layers of first and second polymeric materials such that at least 30% of light incident on said body is reflected, and at least one interior light absorbing layer, a substantial majority of the individual layers of said body having an optical thickness of not more than 0.09 micrometers or not less than 0.45 micrometers, with at least one of said individual layers having an optical thickness of not more than 0.09 micrometers, and wherein said first and second polymeric materials differ from each other in refractive index by at least about 0.03.
Claim 37
Dependent Claim 90 words
A birefringent light polarizer which reflects light anisotropically, comprising multiple layers of at least first and second diverse polymeric materials, a substantial majority of the individual layers of said polarizer having an optical thickness of not more than 0.09 micrometers or not less than 0.45 micrometers, with at least one of said individual layers having an optical thickness of not more than 0.09 micrometers, and wherein said first and second polymeric materials differ from each other in refractive index by at least about 0.03 in one plane of the polarizer.
Claim 38
Dependent Claim 90 words
A birefringent light polarizer which reflects light anisotropically, comprising multiple layers of at least first and second diverse polymeric materials, a substantial majority of the individual layers of said polarizer having an optical thickness of not more than 0.09 micrometers or not less than 0.45 micrometers, with at least one of said individual layers having an optical thickness of not more than 0.09 micrometers, and wherein said first and second polymeric materials differ from each other in refractive index by at least about 0.03 in one plane of the polarizer.
Claim 39
Dependent Claim 36 words
The birefringent light polarizer of claim 32 in which the difference in refractive index between said first and second polymeric materials is caused by stretching said materials in a uniaxial direction to orient said polymeric materials.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-06-16 1995-12-16 1996-06-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-06-16 1999-12-16 2000-06-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-06-16 2003-12-16 2004-06-16 $7700.00 Window Closed / Lapsed

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