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US5122484A Expired / Lapsed US ⏱️ 0.0 years remaining

Zinc phosphate low temperature glasses

Assignee: Corning Inc
•
Filing: 1991-05-23
•
Granted: 1992-06-16
•
Expires: 2011-05-23
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Abstract

Abstract This invention relates to a glass exhibiting a transistion temperature no higher than 425° C. and excellent resistance to attack by water consisting essentially, expressed in terms of weight percent on the oxide basis, of about: ______________________________________ P 2 O 5 38-50 MoO 3 0-10 Al 2 O 3 0-5 WO 3 0-10 Na 2 O 2-10 MoO 3 + WO 3 2-15 Li 2 O 0.75-5 SnO 2 0-10 K 2 O 2-10 Cl 0-8 (analyzed) Na 2 O + Li 2 O + 5-25 Sn 2 O + MoO 3 + 2-25 K 2 O WO 3 + Cl ZnO 28-40 ______________________________________ and being essentially free of PbO.

Inventors

  • 👤 George H. Beall
  • 👤 James E. Dickinson, Jr.
  • 👤 Robert M. Morena

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 17:49
CPC Classifications
C; C03; C03C; C03C3/00; C03C3/12; C03C3/16; C03C3/23; C03C3/21; C03C8/00; C03C8/24

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 88 words
A glass exhibiting a transition temperature no higher than 425° C. and excellent resistance to attack by water consisting essentially, expressed in terms of weight percent on the oxide basis, of about: ______________________________________ P.sub.2 O.sub.5 38-50 MoO.sub.3 0-10 Al.sub.2 O.sub.3 0-5 WO.sub.3 0-10 Na.sub.2 O 2-10 MoO.sub.3 + WO.sub.3 2-15 Li.sub.2 O 0.75-5 SnO.sub.2 0-10 K.sub.2 O 2-10 Cl 0-8 (analyzed) Na.sub.2 O + Li.sub.2 O + 5-25 Sn.sub.2 O + MoO.sub.3 + 2-25 K.sub.2 O WO.sub.3 + Cl ZnO 29-42 ______________________________________ and being essentially free of PbO.
Claim 2
Dependent Claim 88 words
A glass exhibiting a transition temperature no higher than 425° C. and excellent resistance to attack by water consisting essentially, expressed in terms of weight percent on the oxide basis, of about: ______________________________________ P.sub.2 O.sub.5 38-50 MoO.sub.3 0-10 Al.sub.2 O.sub.3 0-5 WO.sub.3 0-10 Na.sub.2 O 2-10 MoO.sub.3 + WO.sub.3 2-15 Li.sub.2 O 0.75-5 SnO.sub.2 0-10 K.sub.2 O 2-10 Cl 0-8 (analyzed) Na.sub.2 O + Li.sub.2 O + 5-25 Sn.sub.2 O + MoO.sub.3 + 2-25 K.sub.2 O WO.sub.3 + Cl ZnO 29-42 ______________________________________ and being essentially free of PbO.
Claim 3
Dependent Claim 15 words
A glass according to claim 1 containing at least 0.75% Al 1 O 3 .
Claim 4
Dependent Claim 59 words
A glass according to claim 1 consisting essentially of ______________________________________ P.sub.2 O.sub.5 40-50 MoO.sub.3 0-8 Al.sub.2 O.sub.3 0.75-3 WO.sub.3 0-10 Na.sub.2 O 2-7 MoO.sub.3 + WO.sub.3 2-10 Li.sub.2 O 1-4 SnO.sub.2 0-6 K.sub.2 O 4-8 Cl 0-7 (analyzed) Na.sub.2 O + 9-15 Sn.sub.2 O + 4-20 Li.sub.2 O + K.sub.2 O MoO.sub.3 + WO.sub.3 + Cl ZnO 30-40. ______________________________________
Claim 5
Dependent Claim 22 words
A glass according to claim 1 which, in the form of frit, exhibits good flow at temperatures not exceeding about 475° C.
Claim 6
Dependent Claim 26 words
A glass according to claim 1 also containing up to 15% by weight of a mill addition to lower the linear coefficient of thermal expansion thereof.
Claim 7
Dependent Claim 47 words
A glass according to claim 5 wherein said mill addition is selected from the group consisting of β-quartz solid solution, β-spodumene solid solution, 64% iron/36% nickel alloy, β-eucryptite solid solution, fused quartz, 96% SiO 2 glass, and pyrophosphate crystalline materials having the crystalline structure of magnesium pyrophosphate.
Claim 8
Dependent Claim 44 words
A glass according to claim 6 wherein said pyrophosphate crystalline materials consist of magnesium pyrophosphate wherein a portion of the magnesium cations may optionally be replaced by at least one cation selected from the group consisting of aluminum, arsenic, cobalt, iron, zinc, and zirconium.

References Cited (Backward Citations)

US4476233A Cited
US4874724A Cited
US4920081A Cited
US5071795A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-06-16 1995-12-16 1996-06-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-06-16 1999-12-16 2000-06-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-06-16 2003-12-16 2004-06-16 $7700.00 Window Closed / Lapsed

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