Patent US1368007A successfully refreshed from Google Patents.
US5114611A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Bleach activation
Assignee: Lever Brothers Co
•
Filing: 1990-04-09
•
Granted: 1992-05-19
•
Expires: 2010-04-09
Abstract
Abstract Peroxy compound bleaching is activated by a catalytic amount of a transition metal complex of a transition metal (Mn, Co, Fe or Cu) with a non-(macro)-cyclic ligand of the formula: ##STR1## preferably 2,2'-bispyridylamine. Bleaching agent and bleach detergent compositions are also disclosed comprising a peroxy compound bleach and said transition metal complex. The transition metal complex is an effective catalyst for activating hydrogen peroxide compounds, peroxyacids and peroxyacid bleach precursors on removing a wide class of stains from substrates, especially texiles and fabrics.
Inventors
- 👤 Cornelis G. Van Kralingen
- 👤 Rudolf J. Martens
- 👤 Mark E. Rerek
- 👤 Ton Swarthoff
- 👤 Marten Van Vliet
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 17:55
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/39; C11D3/3902; C11D3/3905; C11D3/3932
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
248 words
Process for the bleaching and cleaning of substrates employing a bleaching agent selected from the group of peroxy compound bleaches consisting of hydrogen peroxide, hydrogen peroxide-liberating compounds, peroxyacids and their salts, and peroxyacid bleach precursors and mixtures thereof, characterized in that said bleaching agent is activated by a catalytic amount of a transition metal complex of the following general formula: [M.sub.n (L).sub.m X.sub.p ].sup.1 Y.sub.z (I) wherein M is a metal ion selected from the group consisting of Mn, Fe, Co, and Du; X is selected from the group consisting of Cl - , Br - , I - , NO 3 - , CLO 4 - , NCS - , OH - , O 2 2- , O 2 - , HO 2 - , H 2 O 2 , H 2 O, NH 3 , and pyridine; n represents an integer from 1 to 2; m is an integer from 1-5; p is an integer from 0-8; Y is a counter ion, the type of which is independent upon the charge z of the complex; z denotes the charge of the complex and is an integer which can be positive or negative, whereby, if z is positive, Y is a common anion as denoted for X and, if z is negative, Y is a common cation selected from the group consisting of alkali metal, alkaline earth metal and an alkyl ammonium cation; and L is a ligand selected from the group consisting of 2,2-bispyridylamine and 2,2-bispyridylmethane.
Claim 2
Dependent Claim
248 words
Process for the bleaching and cleaning of substrates employing a bleaching agent selected from the group of peroxy compound bleaches consisting of hydrogen peroxide, hydrogen peroxide-liberating compounds, peroxyacids and their salts, and peroxyacid bleach precursors and mixtures thereof, characterized in that said bleaching agent is activated by a catalytic amount of a transition metal complex of the following general formula: [M.sub.n (L).sub.m X.sub.p ].sup.1 Y.sub.z (I) wherein M is a metal ion selected from the group consisting of Mn, Fe, Co, and Du; X is selected from the group consisting of Cl - , Br - , I - , NO 3 - , CLO 4 - , NCS - , OH - , O 2 2- , O 2 - , HO 2 - , H 2 O 2 , H 2 O, NH 3 , and pyridine; n represents an integer from 1 to 2; m is an integer from 1-5; p is an integer from 0-8; Y is a counter ion, the type of which is independent upon the charge z of the complex; z denotes the charge of the complex and is an integer which can be positive or negative, whereby, if z is positive, Y is a common anion as denoted for X and, if z is negative, Y is a common cation selected from the group consisting of alkali metal, alkaline earth metal and an alkyl ammonium cation; and L is a ligand selected from the group consisting of 2,2-bispyridylamine and 2,2-bispyridylmethane.
Claim 3
Dependent Claim
35 words
Process according to claim 1, characterized in that an aqueous bleaching solution is used wherein the transition metal complex catalyst is present in an amount corresponding to 0.01 to 100 ppm of the transition metal.
Claim 4
Dependent Claim
19 words
Process according to claim 2, characterized in that the amount of transition metal is from 0.1 to 10 ppm.
Claim 5
Dependent Claim
245 words
A bleaching agent composition comprising a peroxy compound bleach selected from the group consisting of hydrogen peroxide, hydrogen peroxide-liberating compounds, peroxyacids and their salts and peroxyacid bleach precursors and mixtures thereof, and a catalyst for the bleaching action of said peroxy compound bleach, characterized in that said catalyst is a transition metal complex of the following general formula: [M.sub.n (L).sub.m X.sub.p ].sup.z Y.sub.z (I) wherein M is a metal ion selected from the group consisting of Mn, Fe, Co, and Cu; X is selected from the group consisting of Bl - ,Br - , I - , NO 3 - , CLO 4 - , NCS - , OH - , O 2 2- , O 2 - , HO x - , H 2 O 2 , H 2 O, NH 3 , and pyridine; n represents an integer from 1 to 2; m is an integer from 1-5; p is an integer from 0-8; Y is a counter ion, the type of which is dependent upon the charge z of the complex; z denotes the charge of the complex and is an integer which can be positive or negative, whereby, if z is positive, Y is a common anion as denoted for X and, if z is negative, Y is a common cation selected from the group consisting of alkali metal, alkaline earth metal and an alkyl ammonium cation; and L is a ligand selected from the group consisting of 2,2-bispyridylamine and 2,2-bispyridylmethane.
Claim 6
Dependent Claim
245 words
A bleaching agent composition comprising a peroxy compound bleach selected from the group consisting of hydrogen peroxide, hydrogen peroxide-liberating compounds, peroxyacids and their salts and peroxyacid bleach precursors and mixtures thereof, and a catalyst for the bleaching action of said peroxy compound bleach, characterized in that said catalyst is a transition metal complex of the following general formula: [M.sub.n (L).sub.m X.sub.p ].sup.z Y.sub.z (I) wherein M is a metal ion selected from the group consisting of Mn, Fe, Co, and Cu; X is selected from the group consisting of Bl - ,Br - , I - , NO 3 - , CLO 4 - , NCS - , OH - , O 2 2- , O 2 - , HO x - , H 2 O 2 , H 2 O, NH 3 , and pyridine; n represents an integer from 1 to 2; m is an integer from 1-5; p is an integer from 0-8; Y is a counter ion, the type of which is dependent upon the charge z of the complex; z denotes the charge of the complex and is an integer which can be positive or negative, whereby, if z is positive, Y is a common anion as denoted for X and, if z is negative, Y is a common cation selected from the group consisting of alkali metal, alkaline earth metal and an alkyl ammonium cation; and L is a ligand selected from the group consisting of 2,2-bispyridylamine and 2,2-bispyridylmethane.
Claim 7
Dependent Claim
32 words
A composition according to claim 1, characterized in that the transition metal complex catalyst is present in an amount corresponding to a transition metal content of from 0.0002% to 10% by weight.
Claim 8
Dependent Claim
21 words
A composition according to claim 5, characterized in that the amount of transition metal is from 0.002% to 1.0% by weight.
Claim 9
Dependent Claim
19 words
A composition according to claim 4, characterized in that it further comprises a surface-active material and a detergency builder.
References Cited (Backward Citations)
GB984459A
Cited
US3156654A
Cited
US3532634A
Cited
GB1192524A
Cited
DE2054019A1
Cited
US4119557A
Cited
US4427490A
Cited
DE3002271A1
Cited
US4430243A
Cited
EP0124341A2
Cited
US5002682A
Cited
US4728455A
Cited
EP0272030A2
Cited
US4810410A
Cited
US5021187A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1995-05-19 | 1995-11-18 | 1996-05-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1999-05-19 | 1999-11-18 | 2000-05-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2003-05-19 | 2003-11-18 | 2004-05-19 | $7700.00 | Window Closed / Lapsed |