US5111574A
Expired / Lapsed
US
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Method and apparatus for producing superconducting joints
Assignee: Oxford Instruments Inc
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Filing: 1988-12-05
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Granted: 1992-05-12
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Expires: 2008-12-05
Abstract
Abstract A method for joining two or more superconducting wires each comprising a bundle of filaments of tin (Sn) and niobium (Nb) contained within a binder metal with a superconducting joint. The filaments on the ends of the wires to be joined are first exposed by etching the binder metal away with acid and then the exposed filaments are intertwined. The exposed filaments are then sealed in a copper-enriched chamber and heated to a temperature and for a time sufficient for the Sn and Nb to diffuse together and form Nb 3 Sn at their interface. Preferably, the filaments are sealed by forming a tubular jacket, placing the tubular jacket over the exposed filaments and the wire ends adjacent thereto, and swaging the ends of the tubular jacket to the wire ends adjacent the exposed filaments. The jacket can be formed by obtaining wire comprising a thick outer layer and a thin inner layer of copper separated by a thin barrier layer of a material chosen from the group consisting of vanadium, niobium, and tantalum, or the like, all disposed over a tin core, cutting the wire to desired jacket lengths, heating the jacket lengths of the wire to melt the tin cores thereof, and blowing the melted cores from the jacket lengths of the wire to form hollow cored jackets.
Inventors
- 👤 David B. Smathers
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 10:17
CPC Classifications
H; H10; H10N; H10N60/00; H10N60/80; Y; Y10; Y10T; Y10T29/00; Y10T29/49; Y10T29/49002; Y10T29/49014; Y10T29/49117; Y10T29/49194; Y10T29/49201
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
93 words
In unalloyed wires for superconducting said wires comprising a bundle of filaments of tin (Sn) and niobium (Nb) contained within a binder metal, a method of joining two wires with a superconducting joint comprising the steps of: a) exposing the filaments on the ends of the wires to be joined; b) intertwining the exposed filaments; c) sealing the exposed filaments in a copper-enriched chamber; and, d) heating the chamber to a temperature and for a time sufficient for the Sn and Nb to diffuse together and form Nb 3 Sn at their interface.
Claim 2
Dependent Claim
93 words
In unalloyed wires for superconducting said wires comprising a bundle of filaments of tin (Sn) and niobium (Nb) contained within a binder metal, a method of joining two wires with a superconducting joint comprising the steps of: a) exposing the filaments on the ends of the wires to be joined; b) intertwining the exposed filaments; c) sealing the exposed filaments in a copper-enriched chamber; and, d) heating the chamber to a temperature and for a time sufficient for the Sn and Nb to diffuse together and form Nb 3 Sn at their interface.
Claim 3
Dependent Claim
60 words
The method of forming a superconducting joint between two wires of claim 1 wherein said step of heating the chamber to a temperature and for a time sufficient for the Sn and Nb to diffuse together and form Nb 3 Sn at their interface comprises: heating the chamber to a temperature in the range of 600° C. to 700° C.
Claim 4
Dependent Claim
66 words
The method of forming a superconducting joint between two wires of claim 1 wherein said step of sealing the exposed filaments in a copper-enriched chamber comprises the steps of: a) forming a tubular jacket; b) placing the tubular jacket over the exposed filaments and the wire ends adjacent thereto; and c) swaging the ends of the tubular jacket to the wire ends adjacent the exposed filaments.
Claim 5
Dependent Claim
108 words
The method of forming a superconducting joint between two wires of claim 3 wherein said step of forming a tubular jacket comprises the steps of: a) obtaining wire comprising a thick outer layer and a thin inner layer of copper separated by a thin barrier layer of a material chosen from the group consisting of vanadium, niobium, and tantalum, or the like, all disposed over a tin core; b) cutting the wire to desired jacket lengths; c) heating the jacket lengths of the wire to melt the tin cores thereof; and d) blowing the melted cores from the jacket lengths of the wire to form hollow cored jackets.
Claim 6
Dependent Claim
82 words
The method of forming a superconducting joint between two wires of claim 1 wherein the binder metal is copper and said step of exposing the filaments on the ends of the wires to be joined comprises the step of: exposing the wire ends to an acid which will attack the copper at a faster rate than it will attack tin or niobium for a period of time sufficient to remove the copper from the wire end and leave the tin and niobium.
Claim 7
Dependent Claim
33 words
The method of forming a superconducting joint between two superconducting wires of claim 5 wherein said step of exposing the wire ends to an acid comprises: placing the wire ends in nitric acid.
Claim 8
Independent Claim
156 words
A method of joining two non-superconducting wires comprising a bundle of filaments of tin (Sn) unalloyed with niobium and niobium (Nb) unalloyed with tin contained within a copper binder metal, to form a superconducting joint of Nb 3 Sn comprising the steps of: a) exposing the filaments on the ends of the wires to be joined by placing the wire ends in an acid of a type and concentration which will attack the copper at a faster rate than it will attack tin or niobium for a period of time sufficient to remove the copper from the wire end and leave the tin and niobium; b) intertwining the exposed filaments; c) sealing the exposed filaments in a copper-enriched chamber; and, d) heating the chamber to a temperature in the range 600° C. to 700° C. for a time sufficient for the Sn and Nb to diffuse together and simultaneously form Nb 3 Sn at their interface.
Claim 9
Independent Claim
156 words
A method of joining two non-superconducting wires comprising a bundle of filaments of tin (Sn) unalloyed with niobium and niobium (Nb) unalloyed with tin contained within a copper binder metal, to form a superconducting joint of Nb 3 Sn comprising the steps of: a) exposing the filaments on the ends of the wires to be joined by placing the wire ends in an acid of a type and concentration which will attack the copper at a faster rate than it will attack tin or niobium for a period of time sufficient to remove the copper from the wire end and leave the tin and niobium; b) intertwining the exposed filaments; c) sealing the exposed filaments in a copper-enriched chamber; and, d) heating the chamber to a temperature in the range 600° C. to 700° C. for a time sufficient for the Sn and Nb to diffuse together and simultaneously form Nb 3 Sn at their interface.
Claim 10
Dependent Claim
66 words
The method of forming a superconducting joint between two wires of claim 7 wherein said step of sealing the exposed filaments in a copper-enriched chamber comprises the steps of: a) forming a tubular jacket; b) placing the tubular jacket over the exposed filaments and the wire ends adjacent thereto; and c) swaging the ends of the tubular jacket to the wire ends adjacent the exposed filaments.
Claim 11
Dependent Claim
108 words
The method of forming a superconducting joint between two wires of claim 8 wherein said step of forming a tubular jacket comprises the steps of: a) obtaining wire comprising a thick outer layer and a thin inner layer of copper separated by a thin barrier layer of a material chosen from the group consisting of vanadium, niobium, and tantalum, or the like, all disposed over a tin core; b) cutting the wire to desired jacket lengths; c) heating the jacket lengths of the wire to melt the tin cores thereof; and d) blowing the melted cores from the jacket lengths of the wire to form hollow cored jackets.
Claim 12
Dependent Claim
32 words
The method of forming a superconducting joint between two wires of claim 7 wherein said step of placing the wire ends in an acid comprises: placing the wire ends in nitric acid.
Claim 13
Independent Claim
178 words
A method of joining a bundle of wire filaments comprising tin (Sn) unalloyed with niobium and niobium (Nb) unalloyed with tin comprising the steps of: a) exposing the filaments on the ends of the wires to be joined by placing the wire ends in an acid of a type and concentration which will attack the copper at a faster rate than it will attack tin or niobium for a period of time sufficient to remove the copper from the wire end and leave the tin and niobium; b) intertwining the exposed filaments; c) placing a tubular jacket having copper adjacent an inner surface thereof over the exposed filaments and the wire ends adjacent thereto; d) swaging the ends of the tubular jacket to the wire ends adjacent the exposed filaments whereby the exposed filaments are sealed in a copper-enriched chamber; and e) heating the chamber to a temperature in the range of 600° C. to 700° C. for a time sufficient for the Sn and Nb to diffuse together and simultaneously form Nb 3 Sn at their interface.
Claim 14
Independent Claim
178 words
A method of joining a bundle of wire filaments comprising tin (Sn) unalloyed with niobium and niobium (Nb) unalloyed with tin comprising the steps of: a) exposing the filaments on the ends of the wires to be joined by placing the wire ends in an acid of a type and concentration which will attack the copper at a faster rate than it will attack tin or niobium for a period of time sufficient to remove the copper from the wire end and leave the tin and niobium; b) intertwining the exposed filaments; c) placing a tubular jacket having copper adjacent an inner surface thereof over the exposed filaments and the wire ends adjacent thereto; d) swaging the ends of the tubular jacket to the wire ends adjacent the exposed filaments whereby the exposed filaments are sealed in a copper-enriched chamber; and e) heating the chamber to a temperature in the range of 600° C. to 700° C. for a time sufficient for the Sn and Nb to diffuse together and simultaneously form Nb 3 Sn at their interface.
Claim 15
Dependent Claim
109 words
The method of forming a superconducting joint between two wires of claim 11 and additionally including step of forming the tubular jacket comprising the steps of: a) obtaining wire comprising a thick outer layer and a thin inner layer of copper separated by a thin barrier layer of a material chosen from the group consisting of vanadium, niobium, and tantalum, or the like, all disposed over a tin core; b) cutting the wire to desired jacket lengths; c) heating the jacket lengths of the wire to melt the tin cores thereof; and, d) blowing the melted cores from the jacket lengths of the wire to form hollow cored jackets.
Claim 16
Dependent Claim
32 words
The method of forming a superconducting joint between two wires of claim 11 wherein said step of placing the wire ends in an acid comprises: placing the wire ends in nitric acid.
References Cited (Backward Citations)
GB1298068A
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US3703032A
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WO1980002084A1
Cited
JPS57154385A
Cited
US4631808A
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US4794688A
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1995-05-12 | 1995-11-11 | 1996-05-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1999-05-12 | 1999-11-11 | 2000-05-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2003-05-12 | 2003-11-11 | 2004-05-12 | $7700.00 | Window Closed / Lapsed |