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US5111355A Expired / Lapsed US ⏱️ 0.0 years remaining

High value tantalum oxide capacitor

Assignee: National Semiconductor Corp
•
Filing: 1990-09-13
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Granted: 1992-05-05
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Expires: 2010-09-13
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Abstract

Abstract A thin film capacitor for use in an integrated circuit includes a lower plate disposed on the silicon substrate of the integrated circuit. The lower plate comprises a barrier layer of conductive material which prevents transport of silicon from the silicon substrate into a layer of dielectric material which is disposed between the lower plate and an upper plate. A portion of the barrier layer can be consumed and transferred into dielectric material by, for example, high temperature oxidation which generates a symmetric series capacitor with the dielectric layer. A layer comprising an oxide of the barrier layer material is formed between the barrier layer and the dielectric layer by consuming an upper portion of the barrier layer. The capacitor is constructed by forming the barrier layer on at least a portion of the silicon substrate, forming the dielectric layer over an upper surface of the barrier layer, oxidizing the upper surface of the barrier layer and forming a layer of electrically conductive material on an upper surface of the dielectric layer.

Inventors

  • 👤 Kranti V. Anand
  • 👤 Michael E. Thomas

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 17:12
CPC Classifications
H; H10; H10B; H10B12/00; H10B12/30; H10D; H10D1/00; H10D1/60; H10D1/68; H10P; H10P14/00; H10P14/60; H10P14/63; H10P14/6302; H10P14/6304; H10P14/6314; H10P14/69; H10P14/692; H10P14/6938; H10P14/6939; H10P14/69393; Y; Y10; Y10T; Y10T29/00; Y10T29/43; Y10T29/435

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 128 words
In an integrated circuit having a silicon substrate, a thin film capacitor comprising: a) a first layer of dielectric material disposed on said silicon substrate; b) a first layer of electrically conductive material disposed between said dielectric layer and said silicon substrate, said electrically conductive material comprising a material which can be reactively converted with a gas into an electrically insulating dielectric material which, together with said layer of dielectric material, has a predetermined series dielectric constant; c) a second layer of dielectric material disposed between said first dielectric layer and said first layer of electrically conductive material, said second layer of dielectric material comprising said reactively converted electrically conductive material; and d) a second layer of electrically conductive material disposed on said first layer of dielectric material.
Claim 2
Dependent Claim 128 words
In an integrated circuit having a silicon substrate, a thin film capacitor comprising: a) a first layer of dielectric material disposed on said silicon substrate; b) a first layer of electrically conductive material disposed between said dielectric layer and said silicon substrate, said electrically conductive material comprising a material which can be reactively converted with a gas into an electrically insulating dielectric material which, together with said layer of dielectric material, has a predetermined series dielectric constant; c) a second layer of dielectric material disposed between said first dielectric layer and said first layer of electrically conductive material, said second layer of dielectric material comprising said reactively converted electrically conductive material; and d) a second layer of electrically conductive material disposed on said first layer of dielectric material.
Claim 3
Dependent Claim 29 words
The thin film capacitor in accordance with claim 1 wherein said gas comprises oxygen and said second layer of dielectric material comprises an oxide of said electrically conductive material.
Claim 4
Dependent Claim 35 words
The thin film capacitor in accordance with claim 2 wherein said layer of electrically conductive material comprises a barrier layer which prevents transport of silicon from the substrate into the first and second dielectric layers.
Claim 5
Dependent Claim 21 words
The thin film capacitor in accordance with claim 3 wherein said barrier layer comprises tantalum nitride deposited to a predetermined thickness.
Claim 6
Dependent Claim 23 words
The thin film capacitor in accordance with claim 4 wherein said tantalum nitride is deposited to a thickness substantially equal to 500 angstroms.
Claim 7
Dependent Claim 19 words
The thin film capacitor in accordance with claim 4 wherein said first layer of dielectric material comprises tantalum pentoxide.
Claim 8
Dependent Claim 30 words
The thin film capacitor in accordance with claim 6 wherein said layer of dielectric material has a thickness in the range of from approximately 100 angstroms to approximately 500 angstroms.
Claim 9
Dependent Claim 19 words
The thin film capacitor in accordance with claim 4 wherein said second layer of dielectric material comprises tantalum pentoxide.
Claim 10
Dependent Claim 20 words
The thin film capacitor in accordance with claim 1 wherein said second layer of electrically conductive material comprises tantalum nitride.
Claim 11
Dependent Claim 22 words
The thin film capacitor in accordance with claim 9 wherein said tantalum nitride layer has a thickness substantially equal to 500 angstroms.
Claim 12
Independent Claim 155 words
A method of forming a thin film capacitor on a silicon substrate of an integrated circuit, said method comprising the steps of: a) forming a first electrically conductive layer on at least a portion of said silicon substrate, said first electrically conductive layer comprising an electrically conductive material which can be reactively converted with a gas into an electrically insulating dielectric material having a predetermined dielectric constant; b) forming a first dielectric layer over an upper surface of said first electrically conductive layer, said first dielectric layer comprising a material which, together with said reactively converted material of said first electrically conductive layer, has a predetermined series dielectric constant; c) reactively converting an upper surface of said first electrically conductive layer to form a second dielectric layer between said first electrically conductive layer and said first dielectric layer; and d) forming a second electrically conductive layer on an upper surface of said first dielectric layer.
Claim 13
Independent Claim 155 words
A method of forming a thin film capacitor on a silicon substrate of an integrated circuit, said method comprising the steps of: a) forming a first electrically conductive layer on at least a portion of said silicon substrate, said first electrically conductive layer comprising an electrically conductive material which can be reactively converted with a gas into an electrically insulating dielectric material having a predetermined dielectric constant; b) forming a first dielectric layer over an upper surface of said first electrically conductive layer, said first dielectric layer comprising a material which, together with said reactively converted material of said first electrically conductive layer, has a predetermined series dielectric constant; c) reactively converting an upper surface of said first electrically conductive layer to form a second dielectric layer between said first electrically conductive layer and said first dielectric layer; and d) forming a second electrically conductive layer on an upper surface of said first dielectric layer.
Claim 14
Dependent Claim 61 words
The method in accordance with claim 11 wherein said gas comprises oxygen and step c comprises oxidizing an upper surface of said first electrically conductive layer to form a second dielectric layer between said first electrically conductive layer and said first dielectric layer, said second dielectric layer comprising an oxide of the electrically conductive material of said first electrically conductive layer.
Claim 15
Dependent Claim 51 words
The method in accordance with claim 12 wherein step a comprises forming an electrically conductive barrier layer on at least a portion of said silicon substrate, said electrically conductive barrier layer comprising an electrically conductive material which prevents transport of silicon from the substrate into the first and second dielectric layers.
Claim 16
Dependent Claim 27 words
The method in accordance with claim 13 wherein step a comprises depositing tantalum nitride to a predetermined thickness on at least a portion of said silicon substrate.
Claim 17
Dependent Claim 24 words
The method in accordance with claim 14 wherein step a further comprises depositing said tantalum nitride to a thickness substantially equal to 500 angstroms.
Claim 18
Dependent Claim 19 words
The method in accordance with claim 14 wherein step b comprises forming said first dielectric layer comprising tantalum pentoxide.
Claim 19
Dependent Claim 35 words
The method in accordance with claim 16 wherein step b further comprises forming said first dielectric layer of tantalum pentoxide to a thickness in the range of from approximately 100 angstroms to approximately 500 angstroms.
Claim 20
Dependent Claim 26 words
The method in accordance with claim 14 wherein step c comprises oxidizing an upper surface of said barrier layer to form a layer comprising tantalum pentoxide.
Claim 21
Dependent Claim 28 words
The method in accordance with claim 14 wherein step d comprises a forming a layer of tantalum nitride material on an upper surface of said first dielectric layer.
Claim 22
Dependent Claim 25 words
The method in accordance with claim 19 wherein step d comprises forming a layer a tantalum nitride to a thickness substantially equal to 500 angstroms.

References Cited (Backward Citations)

US4539434A Cited
US4959745A Cited
US4882649A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-05-05 1995-11-04 1996-05-05 $2000.00 Window Closed / Lapsed
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