US5104953A
Expired / Lapsed
US
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Hard transparent resins and process for the production thereof
Assignee: Mitsui Chemicals Inc
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Filing: 1989-06-06
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Granted: 1992-04-14
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Expires: 2009-06-06
Abstract
Abstract The present invention relates to a process for preparing a hard transparent resin comprising polymerizing a monomer (A) having both a functional group of the following formula (I): ##STR1## wherein X is selected from the group consisting of an oxygen atom and a sulfur atom, and a functional group selected from the group consisting of a functional group of the formula (II): CH.sub.2 CR--COO-- (II) wherein R is selected from the group consisting of hydrogen and methyl group, and a functional group of the formula (III): ##STR2## The invention also provides a process for preparing a transparent resin comprising copolymerizing monomer (A) with a monomer (B) having at least one functional group selected from the group consisting of CH.sub.2 ═CHCOO--, CH.sub.2 ═C(CH.sub.3)--COO--, and ##STR3## This resin can be suitably used as a glazing material, and in the manufacture of optical lenses, optical information recording medium substrates, etc. It has a crosslinked structure, high surface hardness, and may be easily polymerized.
Inventors
- 👤 Katsuyoshi Sasagawa
- 👤 Yoshinobu Kanemura
- 👤 Masao Imai
- 👤 Toshiyuki Suzuki
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 18:39
CPC Classifications
C; C08; C08F; C08F228/00; C08F20/00; C08F20/02; C08F20/10; C08F20/34; C08F20/36; C08F12/00; C08F12/02; C08F12/04; C08F12/06; C08F12/12; C08F12/14; C08F12/26; G; G02; G02B; G02B1/00; G02B1/04
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
48 words
A hard transparent resin having at least one structural unit selected from the group consisting of: ##STR29## wherein X is selected from the group consisting of an oxygen atom and a sulfur atom, and wherein R is selected from the group consisting of hydrogen and a methyl group.
Claim 2
Dependent Claim
48 words
A hard transparent resin having at least one structural unit selected from the group consisting of: ##STR29## wherein X is selected from the group consisting of an oxygen atom and a sulfur atom, and wherein R is selected from the group consisting of hydrogen and a methyl group.
Claim 3
Dependent Claim
112 words
A hard transparent resin comprising at least one structural unit selected from the group consisting of the formula (IV) and the formula (V), ##STR30## wherein X is selected from the group consisting of an oxygen atom and a sulfur atom, and wherein R is selected from the group consisting of hydrogen and methyl group, said resin being prepared by a process comprising polymerizing a monomer (A) having, in one molecule, a functional group of the formula (I): ##STR31## wherein X is as defined above, and at least one functional group selected from the group consisting of the formula (II) and the formula (III), ##STR32## wherein R is as defined above, and ##STR33##
Claim 4
Dependent Claim
112 words
A hard transparent resin comprising at least one structural unit selected from the group consisting of the formula (IV) and the formula (V), ##STR30## wherein X is selected from the group consisting of an oxygen atom and a sulfur atom, and wherein R is selected from the group consisting of hydrogen and methyl group, said resin being prepared by a process comprising polymerizing a monomer (A) having, in one molecule, a functional group of the formula (I): ##STR31## wherein X is as defined above, and at least one functional group selected from the group consisting of the formula (II) and the formula (III), ##STR32## wherein R is as defined above, and ##STR33##
Claim 5
Dependent Claim
45 words
The hard transparent resin of claim 2 wherein the monomer (A) is selected from the group consisting of N-(3-isopropenyl-α,α-dimethylbenzyl)-2-acryloyloxyethyl carbamate, N-(3-isopropenyl-α,α-dimethylbenzyl)-2-methacryloyloxyethyl carbamate, N-(4-isopropenyl-α,α-dimethylbenzyl)-2-acryloyloxyethyl carbamate, N-(4-isopropenyl-α,α-dimethylbenzyl)-2-methacryloyloxyetheyl carbamate, N-(3-isopropenyl-α,α-dimethylbenzyl)-1-acryloyloxypropan-2-yl carbamate, N-(3-isopropenyl-α,α-dimethylbenzyl)-1-methacryloyloxypropan-2-yl carbamate, N-(4-isopropenyl-α,α-dimethylbenzyl)-1-acryloyloxypropan-2-yl carbamate, N-(3-isopropenyl-α,α-dimethylbenzyl)-1,3-diacryloyloxypropan-2-yl carbamate, N-(3-isopropenyl-α,α-dimethylbenzyl)-1,3-dimethacryloyloxypropan-2-yl carbamate, N-(3-isopropenyl-α,α-dimethylbenzyl)-1-acryloyloxy-3-methacryloyloxypropan-2-yl carbamate, N-(4-isopropenyl-α,α-dimethylbenzyl)-1,3-diacryloxyloxypropan-2-yl carbamate, N-(3-isopropenyl-α,α-dimethylbenzyl)-2,2-diacryloyloxymethyl-3-acryloyloxypropyl carbamate, and N-(4-isopropenyl-α,α-dimethylbenzyl)-2-dimethacryloyloxymethyl-3-methacryloyloxypropyl carbamate.
Claim 6
Dependent Claim
102 words
A hard transparent resin prepared by a process comprising copolymerizing a monomer (A) having in one molecule a first functional group of the formula (I): ##STR34## wherein X is selected from the group consisting of an oxygen atom and a sulfur atom, and a second functional group selected from the group consisting of a functional group of the formula (II): ##STR35## and wherein R is selected from the group consisting of hydrogen and a methyl group, and a functional group of the formula (III): ##STR36## with a monomer (B) having at least one functional group selected from the group consisting of: ##STR37##
Claim 7
Dependent Claim
102 words
A hard transparent resin prepared by a process comprising copolymerizing a monomer (A) having in one molecule a first functional group of the formula (I): ##STR34## wherein X is selected from the group consisting of an oxygen atom and a sulfur atom, and a second functional group selected from the group consisting of a functional group of the formula (II): ##STR35## and wherein R is selected from the group consisting of hydrogen and a methyl group, and a functional group of the formula (III): ##STR36## with a monomer (B) having at least one functional group selected from the group consisting of: ##STR37##
Claim 8
Dependent Claim
45 words
The hard transparent resin of claim 4 wherein the monomer (A) is selected from the group consisting of N-(3-isopropenyl-α,α-dimethylbenzyl)-2-acryloyloxyethyl carbamate, N-(3-isopropenyl-α,α-dimethylbenzyl)-2-methacryloyloxyethyl carbamate, N-(4-isopropenyl-α,α-dimethylbenzyl)-2-acryloyloxyethyl carbamate, N-(4-isopropenyl-α,α-dimethylbenzyl)-2-methacryloyloxyetheyl carbamate, N-(3-isopropenyl-α,α-dimethylbenzyl)-1-acryloyloxypropan-2-yl carbamate, N-(3-isopropenyl-α,α-dimethylbenzyl)-1-methacryloyloxypropan-2-yl carbamate, N-(4-isopropenyl-α,α-dimethylbenzyl)-1-acryloyloxypropan-2-yl carbamate, N-(3-isopropenyl-α,α-dimethylbenzyl)-1,3-diacryloyloxypropan-2-yl carbamate, N-(3-isopropenyl-α,α-dimethylbenzyl)-1,3-dimethacryloyloxypropan-2-yl carbamate, N-(3-isopropenyl-α,α-dimethylbenzyl)-1-acryloyloxy-3-methacryloyloxypropan-2-yl carbamate, N-(4-isopropenyl-α,α-dimethylbenzyl)-1,3-diacryloxyloxypropan-2-yl carbamate, N-(3-isopropenyl-α,α-dimethylbenzyl)-2,2-diacryloyloxymethyl-3-acryloyloxypropyl carbamate, and N-(4-isopropenyl-α,α-dimethylbenzyl)-2-dimethacryloyloxymethyl-3-methacryloyloxypropyl carbamate.
References Cited (Backward Citations)
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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