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US5100933A Expired / Lapsed US ⏱️ 0.0 years remaining

Collapsible gel compositions

Assignee: Massachusetts Institute of Technology
•
Filing: 1990-01-26
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Granted: 1992-03-31
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Expires: 2010-01-26
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Abstract

Abstract Ionized crosslinked polyacrylamide gels are provided that are capable of drastic volume changes in response to minor changes in solvent concentration, temperature of pH or salt concentration of the solvent. The gels can contain a metal ion.

Inventors

  • 👤 Toyoichi Tanaka
  • 👤 Izumi Nishio
  • 👤 Shao-Tang Sun

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 01:34
CPC Classifications
C; C08; C08J; C08J3/00; C08J3/02; C08J3/03; C08J3/075; C08J3/28; A; A61; A61F; A61F2/00; A61F2/02; A61F2/08; A61F2002/0894; C08J2333/00; C08J2333/24; C08J2333/26

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 73 words
A method of causing a discontinuous volume change in a gel, said gel including a polymer network defining an interstitial space and a gel fluid filling the interstitial space, comprising the steps of: a) ionizing the gel sufficient to cause the gel to exhibit a discontinuous volume change upon exposure to sufficient electromagnetic radiation; and b) exposing the gel to electromagnetic radiation sufficient to cause the gel to exhibit a discontinuous volume change.
Claim 2
Independent Claim 73 words
A method of causing a discontinuous volume change in a gel, said gel including a polymer network defining an interstitial space and a gel fluid filling the interstitial space, comprising the steps of: a) ionizing the gel sufficient to cause the gel to exhibit a discontinuous volume change upon exposure to sufficient electromagnetic radiation; and b) exposing the gel to electromagnetic radiation sufficient to cause the gel to exhibit a discontinuous volume change.
Claim 3
Dependent Claim 19 words
A method of claim 1 wherein the electromagnetic radiation is supplied by conducting an electric current through the gel.
Claim 4
Independent Claim 69 words
A method of causing a discontinuous volume change in a gel, said gel including a polymer network defining an interstitial space and a gel fluid filling the interstitial space, comprising the steps of: a) ionizing the gel sufficient to cause the gel to exhibit a discontinuous volume change upon exposure to metal ions; and b) exposing the gel to metal ions, whereby the gel exhibits a discontinuous volume change.
Claim 5
Independent Claim 69 words
A method of causing a discontinuous volume change in a gel, said gel including a polymer network defining an interstitial space and a gel fluid filling the interstitial space, comprising the steps of: a) ionizing the gel sufficient to cause the gel to exhibit a discontinuous volume change upon exposure to metal ions; and b) exposing the gel to metal ions, whereby the gel exhibits a discontinuous volume change.
Claim 6
Independent Claim 105 words
A method of causing a discontinuous volume change in a gel, said gel including a polymer network defining an interstitial space, a concentration of metal ions dispersed within the interstitial space and a gel fluid filling the interstitial space, comprising the steps of: a) ionizing the gel sufficient to cause the gel to exhibit a discontinuous volume change upon sufficiently changing the metal ion concentration to which the gel is exposed to cause the gel to exhibit a discontinuous volume change; and b) changing the metal ion concentration to which the gel is exposed sufficient to cause the gel to exhibit a discontinuous volume change.
Claim 7
Independent Claim 105 words
A method of causing a discontinuous volume change in a gel, said gel including a polymer network defining an interstitial space, a concentration of metal ions dispersed within the interstitial space and a gel fluid filling the interstitial space, comprising the steps of: a) ionizing the gel sufficient to cause the gel to exhibit a discontinuous volume change upon sufficiently changing the metal ion concentration to which the gel is exposed to cause the gel to exhibit a discontinuous volume change; and b) changing the metal ion concentration to which the gel is exposed sufficient to cause the gel to exhibit a discontinuous volume change.

References Cited (Backward Citations)

US2831841A Cited
US3247171A Cited
US4004997A Cited
JPS49124188A Cited
US3993553A Cited
US4172066A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-03-31 1995-09-30 1996-03-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-03-31 1999-09-30 2000-03-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-03-31 2003-09-30 2004-03-31 $7700.00 Window Closed / Lapsed

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