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US5100693A Expired / Lapsed US ⏱️ 0.0 years remaining

Photolytic deposition of metal from solution onto a substrate

Assignee: Research Foundation of the State University of New York
•
Filing: 1990-06-05
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Granted: 1992-03-31
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Expires: 2010-06-05
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Abstract

Abstract Metal is photolytically deposited from solution onto a substrate in contact with the solution by irradiating with light a solution containing a solubilized metal source and an organic compound containing a plurality of proximal Lewis base substituent groups so as to be capable of promoting the photoreduction of the metal onto the substrate.

Inventors

  • 👤 John J. Eisch
  • 👤 Marek P. Boleslawski

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 09:43
CPC Classifications
C; C23; C23C; C23C18/00; C23C18/14; C23C18/143; H; H05; H05K; H05K3/00; H05K3/10; H05K3/18; H05K3/181; H05K3/182; H05K3/185

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 81 words
A process for the substantially photolytic deposition of a metal from a substantially anhydrous solution onto a substrate which comprises the irradiation with light of a solution consisting essentially of a solvent, a solubilized metal source and, as photosensitizer an organic compound containing a plurality of proximal Lewis base groups capable of coordination with the metal species so as to be capable of promoting the photoreduction of the metal onto the substrate when the solution is in contact with the substrate.
Claim 2
Dependent Claim 81 words
A process for the substantially photolytic deposition of a metal from a substantially anhydrous solution onto a substrate which comprises the irradiation with light of a solution consisting essentially of a solvent, a solubilized metal source and, as photosensitizer an organic compound containing a plurality of proximal Lewis base groups capable of coordination with the metal species so as to be capable of promoting the photoreduction of the metal onto the substrate when the solution is in contact with the substrate.
Claim 3
Dependent Claim 19 words
A process as claimed in claim 1 wherein the solubilized metal source is a 1,3-dicarbonyl complex of the metal.
Claim 4
Dependent Claim 19 words
A process as claimed in claim 1 wherein the compound capable of promoting the photoreduction is a vicinal diamine.
Claim 5
Dependent Claim 25 words
A process as claimed in claim 1 wherein the solution is substantially anhydrous and the solubilized metal source is a dicarbonyl complex of the metal.
Claim 6
Dependent Claim 21 words
A process as claimed in claim 4 wherein the compound capable of promoting the photoreduction is an aromatic substituted vicinal diamine.
Claim 7
Dependent Claim 18 words
A process as claimed in claim 1 wherein the compound capable of promoting the photoreduction is a pinacol.
Claim 8
Dependent Claim 15 words
A process as claimed in claim 6 wherein the pinacol is an aromatic substituted pinacol.
Claim 9
Dependent Claim 15 words
A process as claimed in claim 3 wherein the vicinal diamine is an aromatic diamine.
Claim 10
Dependent Claim 15 words
A process as claimed in claim 5 wherein the vicinal diamine is an aromatic diamine.
Claim 11
Dependent Claim 16 words
A process as claimed in claim 1 wherein the organic compound is an aromatic vicinal diamine.

References Cited (Backward Citations)

US3904783A Cited
US3772056A Cited
US4006269A Cited
US4098922A Cited
US4084023A Cited
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US4560643A Cited
US5045348A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-03-31 1995-09-30 1996-03-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-03-31 1999-09-30 2000-03-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-03-31 2003-09-30 2004-03-31 $7700.00 Window Closed / Lapsed

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