US5096739A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Ultrafine fiber composites and method of making the same
Assignee: CONNECTICUT THE, University of
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Filing: 1989-11-27
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Granted: 1992-03-17
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Expires: 2009-11-27
Abstract
Abstract A novel method is presented for synthesizing ultrafine fiber composite materials by laser induced coevaporation of a metallic target and a ceramic target in the presence of a heated tungsten filament, within a reducing environment. The species produced by rapid condensation from the resultant laser plume, along with the products derived from the chemical transport reactions involving the heated filament, form layers of composite material comprising a metal matrix and a random weave fiber network. In a preferred embodiment of the present invention, composite layers are formed on a nickel alloy substrate surface at a rate of about 1 micron per second. The matrix of the composite films is either aluminum or tungsten and the dispersed phase is amorphous silica fibers. The diameter of the fibers are between 25 and 120 nm depending on the laser beam materials interaction time.
Inventors
- 👤 Peter R. Strutt
- 👤 Gan-Moog Chow
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 10:29
CPC Classifications
C; C23; C23C; C23C14/00; C23C14/06; C23C14/0688; C22; C22C; C22C47/00; C23C14/22; C23C14/24; C23C14/28; Y; Y10; Y10T; Y10T428/00; Y10T428/12; Y10T428/12444; Y10T428/12486; Y10T428/29; Y10T428/2913; Y10T428/2933; Y10T428/294; Y10T428/2958
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
213 words
A method for making a composite material, comprising: irradiating a first portion of metallic substrate in a reducing environment within a reaction chamber with a laser beam at an intensity effective to evaporate material from the first portion of the substrate, said substrate comprising a first metal; heating a metallic filament, comprising a second metal, in the reducing environment within the reaction chamber under conditions effective to allow chemical transport of the second metal from the filament to the substrate, said metallic filament being disposed above and spaced apart from the metallic substrate; irradiating a ceramic target in the reducing environment within the reaction chamber with the laser beam at an intensity effective to evaporate material from the ceramic target and form a laser plume, said ceramic target being spaced apart from the substrate; depositing a layer of the composite material on a second portion of the substrate, said composite material comprising ultrafine ceramic fibers distributed within a metallic matrix, said fibers being derived from the evaporated ceramic material of the laser plume and said metallic matrix being selected from the group consisting of the first metal derived from the substrate, the second metal derived from the filament and mixtures thereof, wherein said fibers have fiber diameters between 25 nm and 120 nm.
Claim 2
Independent Claim
213 words
A method for making a composite material, comprising: irradiating a first portion of metallic substrate in a reducing environment within a reaction chamber with a laser beam at an intensity effective to evaporate material from the first portion of the substrate, said substrate comprising a first metal; heating a metallic filament, comprising a second metal, in the reducing environment within the reaction chamber under conditions effective to allow chemical transport of the second metal from the filament to the substrate, said metallic filament being disposed above and spaced apart from the metallic substrate; irradiating a ceramic target in the reducing environment within the reaction chamber with the laser beam at an intensity effective to evaporate material from the ceramic target and form a laser plume, said ceramic target being spaced apart from the substrate; depositing a layer of the composite material on a second portion of the substrate, said composite material comprising ultrafine ceramic fibers distributed within a metallic matrix, said fibers being derived from the evaporated ceramic material of the laser plume and said metallic matrix being selected from the group consisting of the first metal derived from the substrate, the second metal derived from the filament and mixtures thereof, wherein said fibers have fiber diameters between 25 nm and 120 nm.
Claim 3
Dependent Claim
23 words
The method of claim 1, wherein the ceramic target and the ceramic fibers each comprise SiO 2 , silicon nitride or silicon carbide.
Claim 4
Dependent Claim
16 words
The method of claim 1, wherein the ceramic target and the ceramic fibers each comprise silica.
Claim 5
Dependent Claim
36 words
The method of claim 1, wherein the ceramic target comprises 55 weight percent SiO 2 , 42 weight percent Al 2 O 3 and 3 weight percent TiO 2 and the ceramic fibers comprise silica fibers.
Claim 6
Dependent Claim
17 words
The method of claim 1, wherein the metallic filament is disposed about 2 cm from the substrate.
Claim 7
Dependent Claim
25 words
The method of claim 1, wherein the laser beam is generated by a CO 2 laser at an intensity of 2×10 4 W/cm 2 .
Claim 8
Dependent Claim
104 words
The method of claim 1, wherein the substrate is disposed between the laser source and the ceramic target, substrate is heated by irradiating a first portion of the substrate with the laser beam for a time period effective to perforate the first portion of the substrate by evaporating material from the substrate, wherein the composite material is deposited on a second portion of the substrate by simultaneous deposition of the ceramic fibers, said fibers being formed by coagulation and condensation of material evaporated from the ceramic target, and of the metallic matrix, said matrix being formed by condensation of material evaporated from the substrate.
Claim 9
Dependent Claim
23 words
The method of claim 7, wherein the substrate comprises an alloy of nickel, aluminum and chromium and wherein the first metal comprises aluminum.
Claim 10
Dependent Claim
32 words
The method of claim 7, wherein the substrate is perforated by exposure to a CO 2 laser at an intensity of 2×10 4 W/cm 2 for a time period of 2-3 seconds.
Claim 11
Dependent Claim
17 words
The method of claim 9, wherein the ceramic fibers comprises fibers having a diameter of 25 nm.
Claim 12
Dependent Claim
48 words
The method of claim 1, wherein substrate is heated to a temperature between 1200° C. and 1300° C., the metallic filament comprises a tungsten filament, the ceramic target comprises silica, the reducing environment comprises hydrogen gas and the metallic matrix of the layer of composite material comprises tungsten.
Claim 13
Dependent Claim
39 words
The method of claim 1, wherein tungsten and said ceramic fibers are simultaneously deposited on said substrate by coagulation and condensation of material evaporated from the ceramic target and by chemical vapor deposition of tungsten from the heated filament.
Claim 14
Dependent Claim
18 words
The method of claim 12, wherein the ceramic target is irradiated for a time period of 8-9 seconds.
Claim 15
Dependent Claim
17 words
The method of claim 13, wherein the fibers comprise silica fibers having a diameter of 100 nm.
Claim 16
Independent Claim
116 words
A method for making a fiber reinforced metallic matrix composite material, comprising: irradiating a ceramic target in a reducing environment with a CO 2 laser beam at an intensity effective to form a laser plume of material evaporated from the ceramic target; subjecting the material evaporated from the target to a convective current effective to allow coagulation of evaporated material to form ceramic fibers, said fibers having diameters between 25 nm and 120 nm; and depositing the ceramic fibers on a substrate while simultaneously depositing a metal matrix material on the substrate to form the composite material wherein the matrix material is deposited by condensation of evaporated matrix material or by chemical transport of matrix material.
Claim 17
Independent Claim
116 words
A method for making a fiber reinforced metallic matrix composite material, comprising: irradiating a ceramic target in a reducing environment with a CO 2 laser beam at an intensity effective to form a laser plume of material evaporated from the ceramic target; subjecting the material evaporated from the target to a convective current effective to allow coagulation of evaporated material to form ceramic fibers, said fibers having diameters between 25 nm and 120 nm; and depositing the ceramic fibers on a substrate while simultaneously depositing a metal matrix material on the substrate to form the composite material wherein the matrix material is deposited by condensation of evaporated matrix material or by chemical transport of matrix material.
Claim 18
Dependent Claim
21 words
The method of claim 15, wherein the ceramic target and the ceramic fibers each comprise silica, silicon nitride or silicon carbide.
Claim 19
Dependent Claim
27 words
The method of claim 15, wherein said convective current is generated between the substrate and a heated metallic filament disposed above and spaced apart from the substrate.
Claim 20
Dependent Claim
13 words
The method of claim 15, wherein the matrix material comprises aluminum or tungsten.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1995-03-17 | 1995-09-16 | 1996-03-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1999-03-17 | 1999-09-16 | 2000-03-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2003-03-17 | 2003-09-16 | 2004-03-17 | $7700.00 | Window Closed / Lapsed |