US5089588A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Hydroxy-functional poly(amide ethers) as thermoplastic barrier resins
Assignee: Dow Chemical Co
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Filing: 1991-02-26
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Granted: 1992-02-18
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Expires: 2011-02-26
Abstract
Abstract Hydroxy-functional poly(amide-ethers) are fabricated into articles such as rigid containers and flexible films exhibiting high barrier to oxygen transmission in both dry and moist environments. For example, a polymer prepared by reacting the diglycidyl ether of 4,4'-biphenol with N,N'-bis(m-hydroxyphenyl)-adipamide exhibits especially high barrier.
Inventors
- 👤 Jerry E. White
- 👤 David J. Brennan
- 👤 Steven Pikulin
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 21:04
CPC Classifications
C; C08; C08G; C08G59/00; C08G59/18; C08G59/20; C08G59/22; C08G59/28; C08G59/40; C08G59/62; C08G59/621; C08G69/00; C08G69/40
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
65 words
A thermoplastic polymer having excellent barrier to oxygen in both dry and moist environments and having repeating units represented by the formula: ##STR43## wherein each Ar 1 is independently a divalent aromatic moiety, each R 1 is a predominantly hydrocarbylene moiety, each R 2 is independently hydrogen or a monovalent hydrocarbyl or substituted hydrocarbyl moiety, and each R 3 is independently a predominantly hydrocarbylene moiety.
Claim 2
Dependent Claim
65 words
A thermoplastic polymer having excellent barrier to oxygen in both dry and moist environments and having repeating units represented by the formula: ##STR43## wherein each Ar 1 is independently a divalent aromatic moiety, each R 1 is a predominantly hydrocarbylene moiety, each R 2 is independently hydrogen or a monovalent hydrocarbyl or substituted hydrocarbyl moiety, and each R 3 is independently a predominantly hydrocarbylene moiety.
Claim 3
Dependent Claim
57 words
The polymer of claim 1 which is represented by the formula: ##STR44## wherein Ar 1 , R 1 , R 2 and R 3 are as defined in claim 1, Y is a hydrogen or a monovalent organic terminating group, Z is a monovalent terminating group, and n is a whole number from 10 to about 1000.
Claim 4
Dependent Claim
160 words
The polymer of claim 2 wherein R 1 is (1) an alkylene moiety which has from 1 to 4 carbons or a heteroalkylene which contains an alkylene group and a heteroatomic moiety which is oxygen, sulfur, sulfonyl or sulfoxyl or (2) an arylene which has from 5 to 25 carbons or heteroarylene which contains an arylene ring wherein the ring is interrupted with said heteroatomic moiety provided that the arylene group is optionally substituted with alkyl, alkoxy, halo, nitro or cyano, R 2 is hydrogen or a hydrocarbyl or substituted hydrocarbyl wherein the substituent(s) is a monovalent moiety which is inert in the reactions used to prepare the polymer, and R 3 is an arylene which has from 5 to 25 carbons or heteroarylene which contains an arylene ring wherein the ring is interrupted with said heteroatomic moiety, Ar 1 is arylene or substituted arylene wherein the substituent is alkyl, alkoxy, halo, nitro or cyano, Y is hydrogen or ##STR45##
Claim 5
Dependent Claim
34 words
The polymer of claim 3 wherein R 1 is n-butylene, R 2 is hydrogen, R 3 is bisphenyleneisopropylidene, Ar 1 is phenylene, Y is hydrogen, and n is a number from 200 to 4000.
Claim 6
Dependent Claim
12 words
The polymer of claim 1 in the form of a barrier container.
Claim 7
Dependent Claim
12 words
The polymer of claim 1 in the form of a barrier film.
Claim 8
Dependent Claim
23 words
The polymer of claim 1 having an oxygen transmission rate in the range of from about 0.18 to about 1.8 cc/mil/100in 2 /atm/day.
Claim 9
Dependent Claim
68 words
The polymer of claim 3 prepared in the presence of a catalyst which is an onium salt of an acid having a pKa of at least 4, said polymer having an inherent viscosity of at least about 30 percent higher than that of a similar polymer prepared in the presence of a catalyst which is an onium salt of an acid having a pKa of less than 4.
Claim 10
Dependent Claim
12 words
The polymer of claim 1 in the form of a barrier coating.
References Cited (Backward Citations)
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1995-02-17 | 1995-08-19 | 1996-02-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1999-02-17 | 1999-08-19 | 2000-02-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2003-02-17 | 2003-08-19 | 2004-02-18 | $7700.00 | Window Closed / Lapsed |