US5089050A
Expired / Lapsed
US
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Inks containing a water soluble compound as a stabilizer particularly for ink jet printing
Assignee: BASF Corp
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Filing: 1991-05-06
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Granted: 1992-02-18
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Expires: 2011-05-06
Abstract
Abstract Inks, in particular for ink-jet printing, containing, as stabilizer, a water-soluble compound of the formula <IMAGE> in which R1 to R7 are as defined in claim 1, and recording materials containing these compounds.
Inventors
- 👤 Eric Vieira
- 👤 David G. Leppard
- 👤 Hugh S. Laver
- 👤 Vien V. Toan
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 20:29
CPC Classifications
C; C09; C09D; C09D11/00; C09D11/30; C09D11/38
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
283 words
An ink which contains a water soluble dye and at least one water-soluble compound of the formula ##STR8## in which R 1 is hydrogen, alkyl having 1 to 4 carbon atoms, allyl or --CO--CH 3 , R 3 and R 4 , independently of one another, are hydrogen or --CO 2 .sup.⊖ M.sup.⊕, and R 5 , R 6 and R 7 , independently of one another, are hydrogen, alkyl having 1 to 8 carbon atoms which is unsubstituted or substituted by --CO 2 R 8 , --CO 2 .sup.⊖ M.sup.⊕ or phenyl, or are --CO 2 R 8 where R 8 is a group of the formula --CH 2 CH 2 O) 1-20 R 11 in which R 11 is hydrogen, alkyl having 1 to 4 carbon atoms or a group of the formula ##STR9## in which R 1 is as defined above, Y is a direct bond or alkylene having 1 to 8 carbon atoms, and R 60 and R 70 , independently of one another, are hydrogen or alkyl having 1 to 8 carbon atoms, M.sup.⊕ is a monovalent, divalent or trivalent metal cation, H.sup.⊕ or a group of the formula .sup.⊕ N(R 17 )(R 12 )(R 13 )(R 14 ) in which R 17 , R 12 , R 13 and R 14 , independently of one another, are hydrogen, alkyl having 1 to 8 carbon atoms, alkyl having 2 to 8 carbon atoms which is substituted by 1 to 3 hydroxyl groups or is interrupted by oxygen, alkenyl having 3 to 5 carbon atoms or benzyl, at least one of the substituents R 3 to R 7 being --CO 2 .sup.⊖ M.sup.⊕ or --CO 2 R 8 .
Claim 2
Dependent Claim
283 words
An ink which contains a water soluble dye and at least one water-soluble compound of the formula ##STR8## in which R 1 is hydrogen, alkyl having 1 to 4 carbon atoms, allyl or --CO--CH 3 , R 3 and R 4 , independently of one another, are hydrogen or --CO 2 .sup.⊖ M.sup.⊕, and R 5 , R 6 and R 7 , independently of one another, are hydrogen, alkyl having 1 to 8 carbon atoms which is unsubstituted or substituted by --CO 2 R 8 , --CO 2 .sup.⊖ M.sup.⊕ or phenyl, or are --CO 2 R 8 where R 8 is a group of the formula --CH 2 CH 2 O) 1-20 R 11 in which R 11 is hydrogen, alkyl having 1 to 4 carbon atoms or a group of the formula ##STR9## in which R 1 is as defined above, Y is a direct bond or alkylene having 1 to 8 carbon atoms, and R 60 and R 70 , independently of one another, are hydrogen or alkyl having 1 to 8 carbon atoms, M.sup.⊕ is a monovalent, divalent or trivalent metal cation, H.sup.⊕ or a group of the formula .sup.⊕ N(R 17 )(R 12 )(R 13 )(R 14 ) in which R 17 , R 12 , R 13 and R 14 , independently of one another, are hydrogen, alkyl having 1 to 8 carbon atoms, alkyl having 2 to 8 carbon atoms which is substituted by 1 to 3 hydroxyl groups or is interrupted by oxygen, alkenyl having 3 to 5 carbon atoms or benzyl, at least one of the substituents R 3 to R 7 being --CO 2 .sup.⊖ M.sup.⊕ or --CO 2 R 8 .
Claim 3
Dependent Claim
87 words
An ink according to claim 1, in which, in the compound of the formula (1), R 1 is hydrogen or alkyl having 1 to 4 carbon atoms, R 3 and R 4 , independently of one another, are hydrogen or --CO 2 .sup.⊖ M.sup.⊕, R 5 , R 6 and R 7 , independently of one another, are hydrogen, alkyl having 1 to 8 carbon atoms which is unsubstituted or substituted by --CO 2 .sup.⊖ M.sup.⊕ or phenyl, and M.sup.⊕ is a monovalent metal cation or H.sup.⊕.
Claim 4
Dependent Claim
46 words
An ink according to claim 1, in which, in the compound of the formula (1), R 1 , R 3 , R 5 and R 6 are hydrogen, R 7 is alkyl having 1 to 8 carbon atoms, and R 4 is --CO 2 .sup.⊖ M.sup.⊕.
Claim 5
Dependent Claim
30 words
An ink according to claim 1, wherein the compound of the formula (1) is ##STR10## in which R 5 , R 6 and M.sup.⊕ are as defined in claim 1.
Claim 6
Dependent Claim
35 words
An ink according to claim 1, wherein the compound of the formula (1) is ##STR11## in which R 5 and R 6 are as defined in claim 1, and R 11 is hydrogen or methyl.
Claim 7
Dependent Claim
37 words
A process for stabilizing ink-jet prints, which comprises applying the ink of claim 1 to a recording material for ink-jet printing wherein the ink contains at least one compound of the formula (1), and drying the ink.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1995-02-17 | 1995-08-19 | 1996-02-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1999-02-17 | 1999-08-19 | 2000-02-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2003-02-17 | 2003-08-19 | 2004-02-18 | $7700.00 | Window Closed / Lapsed |