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US5087286A Expired / Lapsed US ⏱️ 0.0 years remaining

Heat-curable resinous coating composition

Assignee: Kansai Paint Co Ltd
•
Filing: 1990-03-19
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Granted: 1992-02-11
•
Expires: 2010-03-19
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Abstract

Abstract A heat-curable resinous coating composition comprising as a binder component (A) 5 to 90% by weight of a hydroxyl-containing resin selected from hydroxyl-containing acrylic resins and hydroxyl-containing polyester resins, (B) 5 to 50% by weight of an amino resin, and (C) 1 to 90% by weight of a crosslinkable resin selected from (C-a) polyfunctional resins having a number average molecular weight of at least 1000 and containing at least two carboxyl groups and at least two epoxy groups on an average per molecule and (C-b) polyorganosiloxanes having a number average molecular weight of at least 500 and containing at least two silanol groups on an average per molecule and if required, further containing an epoxy group.

Inventors

  • 👤 Mitsuhiro Fukuda
  • 👤 Hirotoshi Inoue
  • 👤 Akira Kasari
  • 👤 Yuzo Miyamoto
  • 👤 Osamu Isozaki
  • 👤 Noboru Nakai

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 19:19
CPC Classifications
C; C09; C09D; C09D167/00; C09D133/00; C09D133/04; C09D133/06; C09D133/08; C09D163/00; C09D183/00; C09D183/04

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 268 words
A heat-curable resinous coating composition comprising as a binder component (A) 5 to 90% by weight of a hydroxyl-containing resin selected from hydroxyl-containing acrylic resins and hydroxyl-containing polyester resins, (B) 5 to 50% by weight of an amino resin which reacts under heat with the hydroxyl groups of the hydroxyl-containing resin (A) to form a crosslinkage, and (C) 1 to 90% by weight of a crosslinkable and polyorganosiloxanes having a number average molecular weight of at least 500 and containing at least two silanol groups on an average per molecule and optionally containing an epoxy group, said polyoragnosiloxanes being obtained by hydrolyzing and co-condensing a silane represented by the following formula (II) R.sub.x.sup.2 Si(OR.sup.3)4-x (II) wherein R 2 and R 3 are same or different and each represents a monovalent hydrocarbon group having 1 to 13 carbon atoms, and x is 1, 2 or 3, optionally together with an epoxy-containing silane represented by the following formula (III) ##STR7## wherein R 4 and R 5 are same or different and each represents a monovalent hydrocarbon group having 1 to 13 carbon atoms, y is 1, 2 or 3, and G represents an epoxy-containing organic group, for example an organic group of formula (IV) or (V) below ##STR8## wherein R 6 represents a divalent hydrocarbon group having 1 to 13 carbon atoms, and two or more R 7 may be identical or different and each represents a hydrogen atom or a methyl group. and the coating composition optionally comprising as paint additives, at least one of organic solvents, pigments, ultraviolet absorbers, paint surface adjusting agents, curing catalysts and pigment dispersants.
Claim 2
Dependent Claim 268 words
A heat-curable resinous coating composition comprising as a binder component (A) 5 to 90% by weight of a hydroxyl-containing resin selected from hydroxyl-containing acrylic resins and hydroxyl-containing polyester resins, (B) 5 to 50% by weight of an amino resin which reacts under heat with the hydroxyl groups of the hydroxyl-containing resin (A) to form a crosslinkage, and (C) 1 to 90% by weight of a crosslinkable and polyorganosiloxanes having a number average molecular weight of at least 500 and containing at least two silanol groups on an average per molecule and optionally containing an epoxy group, said polyoragnosiloxanes being obtained by hydrolyzing and co-condensing a silane represented by the following formula (II) R.sub.x.sup.2 Si(OR.sup.3)4-x (II) wherein R 2 and R 3 are same or different and each represents a monovalent hydrocarbon group having 1 to 13 carbon atoms, and x is 1, 2 or 3, optionally together with an epoxy-containing silane represented by the following formula (III) ##STR7## wherein R 4 and R 5 are same or different and each represents a monovalent hydrocarbon group having 1 to 13 carbon atoms, y is 1, 2 or 3, and G represents an epoxy-containing organic group, for example an organic group of formula (IV) or (V) below ##STR8## wherein R 6 represents a divalent hydrocarbon group having 1 to 13 carbon atoms, and two or more R 7 may be identical or different and each represents a hydrogen atom or a methyl group. and the coating composition optionally comprising as paint additives, at least one of organic solvents, pigments, ultraviolet absorbers, paint surface adjusting agents, curing catalysts and pigment dispersants.
Claim 3
Dependent Claim 25 words
The composition of claim 1 in which the hydroxyl-containing resin (A) is a copolymer of a hydroxyl-containing acrylic monomer and a copolymerizable other vinyl monomer.
Claim 4
Dependent Claim 19 words
The composition of claim 2 in which the copolymer has a number average molecular weight of 1,000 to 50,000.
Claim 5
Dependent Claim 16 words
The composition of claim 1 in which the hydroxyl-containing resin (A) is an oil-free polyester resin.
Claim 6
Dependent Claim 20 words
The composition of claim 4 in which the polyester resin has a number average molecular weight of 800 to 50,000.
Claim 7
Dependent Claim 29 words
The composition of claim 2 in which the copolymer contains at least 40% by weight of a C 1 -C 12 alkyl acrylate or methacrylate in the constituent monomers.
Claim 8
Dependent Claim 19 words
The composition of claim 1 in which the hydroxyl-containing resin (A) has a hydroxyl value of 20 to 200.
Claim 9
Dependent Claim 20 words
The composition of claim 1 in which the hydroxyl-containing resin (A) has an acid number of not more than 50.
Claim 10
Dependent Claim 17 words
The composition of claim 1 in which the amino resin (B) is a highly etherified melamine resin.
Claim 11
Dependent Claim 21 words
The composition of claim 1 in which the polyorganosiloxanes further contain 1 to 10 epoxy groups on an average per molecule.
Claim 12
Dependent Claim 48 words
The composition of claim 1 in which the total amount of the silane of formula (II) in which x is 1 and the epoxy-containing silane of formula (III) in which y is 1 is at least 30% by weight based on the weight of the entire silanes used.
Claim 13
Dependent Claim 20 words
The composition of claim 11 in which the silane of formula (II) is at least one of methyltrimethoxysilane and phenyltrimethoxysilane.
Claim 14
Dependent Claim 19 words
The composition of claim 1 in which the polyorganosiloxanes have a number average molecular weight of 1,000 to 3,000.
Claim 15
Dependent Claim 43 words
The coating composition of claim 1 in which the binder component contains 30 to 60% by weight of the hydroxyl-containing resin (A), 10 to 40% by weight of the amino resin (B) and 20 to 40% by weight of the crosslinkable resin (C).
Claim 16
Dependent Claim 25 words
The composition of claim 1 in which the crosslinkable resin (C) is a polyorganosiloxane containing 2 to 10 silanol groups on an average per molecule.

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-02-10 1995-08-12 1996-02-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-02-10 1999-08-12 2000-02-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-02-10 2003-08-12 2004-02-11 $7700.00 Window Closed / Lapsed

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