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US5085965A Expired / Lapsed US ⏱️ 0.0 years remaining

Negative toner for developing latent electrostatic images

Assignee: Ricoh Co Ltd
•
Filing: 1990-03-20
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Granted: 1992-02-04
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Expires: 2010-03-20
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Abstract

Abstract A negatively chargeable toner for developing latent electrostatic images comprising a coloring agent, a resin component which comprises a homopolymer of a first monomer having formula (I) or a copolymer of the aforementioned first monomer and a second monomer: <IMAGE> (I) wherein R1 represents -H or -CH3; R2 and R3 each represent -CN, -COOH or -NO2; R4 represents -F, -Cl or -Br; and n is an integer of 1 to 10.

Inventors

  • 👤 Toshiki Nanya
  • 👤 Kimitoshi Yamaguchi
  • 👤 Kazuo Tsubuko
  • 👤 Toshihiko Takahashi
  • 👤 Hiromitsu Kawase
  • 👤 Makoto Ookawara

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 05:43
CPC Classifications
C; C08; C08F; C08F20/00; C08F20/02; C08F20/10; C08F20/26; C08F20/30; C08F20/34; C08F20/36; G; G03; G03G; G03G9/00; G03G9/08; G03G9/087; G03G9/08702; G03G9/08726; G03G9/08728

Claims Analysis

Total Claims: 31
Claim 1
Independent Claim 77 words
A negatively chargeable toner for developing latent electrostatic images comprising a coloring agent and a resin component which comprises a homopolymer of a first monomer of formula (I) or a copolymer of said first monomer and a second monomer: ##STR5## wherein R 1 represents -H or -CH ; R 2 and R 3 each represent -CN, -COOH or -NO 2 ; R 4 represents -F, -Cl or -Br; and n is an integer of 1 to 10.
Claim 2
Dependent Claim 77 words
A negatively chargeable toner for developing latent electrostatic images comprising a coloring agent and a resin component which comprises a homopolymer of a first monomer of formula (I) or a copolymer of said first monomer and a second monomer: ##STR5## wherein R 1 represents -H or -CH ; R 2 and R 3 each represent -CN, -COOH or -NO 2 ; R 4 represents -F, -Cl or -Br; and n is an integer of 1 to 10.
Claim 3
Dependent Claim 17 words
The negatively chargeable toner as claimed in claim 1, wherein said second monomer is a vinyl monomer.
Claim 4
Dependent Claim 33 words
The negatively chargeable toner as claimed in claim 2, wherein said vinyl monomer is selected from the group consisting of styrene, α-methylstyrene, methylstyrene, alkyl acrylate, alkyl methacrylate, acrylonitrile, methacrylonitrile, vinyl acetate and vinylpyridine.
Claim 5
Dependent Claim 36 words
The negatively chargeable toner as claimed in claim 1, wherein said monomer is represented by the following formula: ##STR6## wherein R 1 represents -H or -CH 3 ; and n is an integer of 1to 10.
Claim 6
Dependent Claim 22 words
The negatively chargeable toner as claimed in claim 4, wherein said monomer has a structure selected from the group consisting of: ##STR7##
Claim 7
Dependent Claim 24 words
The negatively chargeable toner as claimed in claim 1, wherein said homopolymer or copolymer has a weight-average molecular weight ranging from 5,000 to 100,000.
Claim 8
Dependent Claim 24 words
The negatively chargeable toner as claimed in claim 6, wherein said homopolymer or copolymer has a weight-average molecular weight ranging from 8,000 to 30,000.
Claim 9
Dependent Claim 35 words
The negatively chargeable toner as claimed in claim 1, wherein the amount of said homopolymer or copolymer is in the range of 0.5 to 20 wt. % of the total amount of said resin component.
Claim 10
Dependent Claim 36 words
The negatively chargeable toner as claimed in claim 1, wherein said resin component comprises at least one resin selected from the group consisting of polystyrene, acrylic resin, styrene - acrylic copolymer, polyester, epoxy resin and polyolefin.
Claim 11
Dependent Claim 40 words
The negatively chargeable toner as claimed in claim 1, wherein said resin component comprises (a) one resin selected from the group consisting of polystyrene, acrylic resin, styrene - acrylic copolymer and epoxy resin, and (b) a low molecular weight polyolefin.
Claim 12
Dependent Claim 19 words
The negatively chargeable toner as claimed in claim 1, further comprising a magnetic material in the toner particles thereof.
Claim 13
Dependent Claim 36 words
The negatively chargeable toner as claimed in claim 11, wherein the amount of said magnetic material is in the range of 40 to 150 parts by weight to 100 parts by weight of said resin component.
Claim 14
Dependent Claim 38 words
The negatively chargeable toner as claimed in claim 1, further comprising a lubricant, an abrasive, a fluidity providing agent, an electroconductivity-imparting agent and a fixing performance promoting agent in the toner particles thereof or at the surfaces thereof.
Claim 15
Dependent Claim 53 words
The negatively chargeable toner as claimed in claim 1, further comprising at least one additive selected from the group consisting of fluoroplastics powder, zinc stearate powder, cerium oxide powder, silicon carbide powder, colloidal silica, aluminum oxide powder, carbon black and tin oxide powder in the toner particles thereof or at the surfaces thereof.
Claim 16
Dependent Claim 30 words
The negatively chargeable toner as claimed in claim 1, wherein said coloring agent is selected form the group consisting of yellow-type coloring agents, magenta-type coloring agents and cyan-type coloring agents.
Claim 17
Dependent Claim 87 words
A two-component type developer for developing latent electrostatic images comprising (i) toner particles which comprise a coloring agent and a resin component which comprises a homopolymer of a first monomer having formula (I) or a copolymer of said first monomer and a second monomer; ##STR8## wherein R 1 represents -H or -CH 3 ; R 2 and R 3 each represent -CN, -COOH or -NO 2 ; R 4 represents -F, -Cl or -Br; and n is an integer of 1 to 10; and (ii) carrier particles.
Claim 18
Dependent Claim 87 words
A two-component type developer for developing latent electrostatic images comprising (i) toner particles which comprise a coloring agent and a resin component which comprises a homopolymer of a first monomer having formula (I) or a copolymer of said first monomer and a second monomer; ##STR8## wherein R 1 represents -H or -CH 3 ; R 2 and R 3 each represent -CN, -COOH or -NO 2 ; R 4 represents -F, -Cl or -Br; and n is an integer of 1 to 10; and (ii) carrier particles.
Claim 19
Dependent Claim 16 words
The two-component type developer as claimed in claim 16, wherein said carrier particles have magnetic properties.
Claim 20
Dependent Claim 17 words
The two-component type developer as claimed in claim 16, wherein said second monomer is a vinyl monomer.
Claim 21
Dependent Claim 33 words
The two-component type developer as claimed in claim 18, wherein said vinyl monomer is selected from the group consisting of styrene, α-methylstyrene, methylstyrene, alkyl acrylate, alkyl methacrylate, acrylonitrile, methacrylonitrile, vinyl acetate and vinylpyridine.
Claim 22
Dependent Claim 37 words
The two-component type developer as claimed in claim 16, wherein said monomer is represented by the following formula: ##STR9## wherein R 1 represents -H or -CH 3 ; and n is an integer of 1 to 10.
Claim 23
Dependent Claim 24 words
The two-component type developer as claimed in claim 20, wherein said monomer has a structure selected from the group consisting of: ##STR10## and ##STR11##
Claim 24
Dependent Claim 24 words
The two-component type developer as claimed in claim 16, wherein said homopolymer or copolymer has a weight-average molecular weight ranging from 5,000 to 100,000.
Claim 25
Dependent Claim 24 words
The two-component type developer as claimed in claim 22, wherein said homopolymer or copolymer has a weight-average molecular weight ranging from 8,000 to 30,000.
Claim 26
Dependent Claim 35 words
The two-component type developer as claimed in claim 16, wherein the amount of said homopolymer or copolymer is in the range of 0.5 to 20 wt. % of the total amount of said resin component.
Claim 27
Dependent Claim 36 words
The two-component type developer as claimed in claim 16, wherein said resin component comprises at least one resin selected from the group consisting of polystyrene, acrylic resin, styrene - acrylic copolymer, polyester, epoxy resin and polyolefin.
Claim 28
Dependent Claim 40 words
The two-component type developer as claimed in claim 16, wherein said resin component comprises (a) one resin selected from the group consisting of polystyrene, acrylic resin, styrene - acrylic copolymer and epoxy resin, and (b) a low molecular weight polyolefin.
Claim 29
Dependent Claim 38 words
The two-component type developer as claimed in claim 16, further comprising a lubricant, an abrasive, a fluidity providing agent, an electroconductivity-imparting agent and a fixing performance promoting agent in said toner particles thereof or at the surfaces thereof.
Claim 30
Dependent Claim 53 words
The two-component type developer as claimed in claim 16, further comprising at least one additive selected from the group consisting of fluoroplastics powder, zinc stearate powder, cerium oxide powder, silicon carbide powder, colloidal silica, aluminum oxide powder, carbon black and tin oxide powder in said toner particles thereof or at the surfaces thereof.
Claim 31
Dependent Claim 30 words
The two-component type developer as claimed in claim 16, wherein said coloring agent is selected form the group consisting of yellow-type coloring agents, magenta-type coloring agents and cyan-type coloring agents.

References Cited (Backward Citations)

US4882258A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-02-03 1995-08-05 1996-02-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-02-03 1999-08-05 2000-02-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-02-03 2003-08-05 2004-02-04 $7700.00 Window Closed / Lapsed

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