US5085918A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Printed retroreflective sheet
Assignee: 3M Innovative Properties Co
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Filing: 1990-05-15
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Granted: 1992-02-04
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Expires: 2010-05-15
Abstract
Abstract A weather resistant sign and a method of printing a sign including the steps of providing a sign component and an image definition, applying dry toner powder to surface portions corresponding to the image definition, and fusing the applied toner. Preferably, the fused toner is protected from weather by a transparent protective layer. A toner composition and a computer program for printing are also disclosed.
Inventors
- 👤 J. Sundar Rajan
- 👤 Vincent J. Mako
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 07:16
CPC Classifications
B; B60; B60R; B60R13/00; B60R13/10; G; G03; G03G; G03G15/00; G03G15/22; B32; B32B; B32B38/00; B32B38/14; B32B38/145; G03G7/00; G03G7/0006; G03G7/002; G03G8/00; G09; G09F; G09F13/00; G09F13/04; G09F13/0418; G09F13/0472; G09F13/16; B32B2307/00; B32B2307/40; B32B2307/412; B32B2311/00; B32B2311/24; B32B2605/00; B32B2605/08; B32B37/00; B32B37/14; B32B37/16; B32B37/20; B32B37/203; B32B38/06; Y; Y10; Y10S; Y10S206/00; Y10S206/807; Y10S428/00; Y10S428/913; Y10S428/916; Y10T; Y10T428/00; Y10T428/24; Y10T428/24802; Y10T428/24851; Y10T428/24868; Y10T428/24876; Y10T428/24893; Y10T428/31504
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
161 words
A reflective sign comprising a retroreflective sheet: A. having an image bearing surface, intended to be seen by an observer, which comprises a polymer selected from the group consisting of polyalkylacrylates, polyalkylmethacrylates, polyesters, vinyl polymers, polyurethanes, cellulose esters, fluoropolymers, polycarbonates, polyolefins, polyvinyl acetals, ionomeric copolymers and copolymers of ethylene or propylene with acrylic acid, methacrylic acid, or vinyl acetate; B. said image bearing surface having printed thereon an image derived from a solid toner comprising: (1) a colorant; (2) a transparent polymeric binding agent, which adheres to said image bearing surface, selected from the group consisting of alkyl substituted acrylic and methacrylate polymers with alkyl groups having 1-9 carbon atoms, polyvinyl acetals, polyolefins, polyesters and vinyl resins; and (3) a charge carrier selected from the group consisting of: acrylic polymers with functional groups having at least an amine nitrogen or quaternary ammonium nitrogen; methacrylic polymers with functional groups having at least an amine nitrogen or quaternary ammonium nitrogen; and azine dyes.
Claim 2
Dependent Claim
161 words
A reflective sign comprising a retroreflective sheet: A. having an image bearing surface, intended to be seen by an observer, which comprises a polymer selected from the group consisting of polyalkylacrylates, polyalkylmethacrylates, polyesters, vinyl polymers, polyurethanes, cellulose esters, fluoropolymers, polycarbonates, polyolefins, polyvinyl acetals, ionomeric copolymers and copolymers of ethylene or propylene with acrylic acid, methacrylic acid, or vinyl acetate; B. said image bearing surface having printed thereon an image derived from a solid toner comprising: (1) a colorant; (2) a transparent polymeric binding agent, which adheres to said image bearing surface, selected from the group consisting of alkyl substituted acrylic and methacrylate polymers with alkyl groups having 1-9 carbon atoms, polyvinyl acetals, polyolefins, polyesters and vinyl resins; and (3) a charge carrier selected from the group consisting of: acrylic polymers with functional groups having at least an amine nitrogen or quaternary ammonium nitrogen; methacrylic polymers with functional groups having at least an amine nitrogen or quaternary ammonium nitrogen; and azine dyes.
Claim 3
Dependent Claim
12 words
The sign of claim 1, wherein the printed image is light transmissive.
Claim 4
Dependent Claim
19 words
The sign of claim 1 wherein the binding agent consists of a copolymer of methyl methacrylate and butyl methacrylate.
Claim 5
Dependent Claim
18 words
The sign of claim 1 which further comprises: a supporting substrate to which the reflective sheet is adhered.
Claim 6
Dependent Claim
23 words
The sign of claim 4 wherein the supporting substrate comprises a material selected from the group consisting of aluminum, steel, and polymeric materials.
Claim 7
Dependent Claim
38 words
The sign of claim 1 further comprising: a light transmitting protective top layer covering the reflective sheet layer and the fused toner so as to place the image between the reflective sheet layer and the transparent top layer.
Claim 8
Dependent Claim
22 words
The sign of claim 1 and further comprising: an embossed area on which the image derived from solid toner has been printed.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1995-02-03 | 1995-08-05 | 1996-02-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1999-02-03 | 1999-08-05 | 2000-02-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2003-02-03 | 2003-08-05 | 2004-02-04 | $7700.00 | Window Closed / Lapsed |