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US5084345A Expired / Lapsed US ⏱️ 0.0 years remaining

Laminates utilizing chemically etchable adhesives

Assignee: EIDP Inc
•
Filing: 1990-11-26
•
Granted: 1992-01-28
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Expires: 2010-11-26
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Abstract

Abstract A multilayer laminate having a metallic layer and a dielectric layer, such as a chemically etchable polyimide, bonded to each other with a chemically etchable adhesive containing phenolic ester groups in the backbone.

Inventors

  • 👤 Philip Manos

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 14:57
CPC Classifications
B; B32; B32B; B32B7/00; B32B7/04; B32B7/12; B32B15/00; B32B15/04; B32B15/08; B32B27/00; B32B27/28; B32B27/281; C; C07; C07C; C07C229/00; C07C229/52; C07C229/54; C07C229/56; C07C229/60; C08; C08G; C08G73/00; C08G73/06; C08G73/10; C08G73/1003; C08G73/1007; C08G73/101; C08G73/16; H; H05; H05K; H05K3/00; H05K3/38; H05K3/386; B32B2307/00; B32B2307/20; B32B2307/204; B32B2311/00; B32B2311/12; B32B2379/00; B32B2379/08; H05K2201/00; H05K2201/01; H05K2201/0137; H05K2201/0154; H05K2201/03; H05K2201/0332; H05K2201/0335; H05K2201/0355; Y; Y10; Y10S; Y10S428/00; Y10S428/91; Y10T; Y10T428/00; Y10T428/26; Y10T428/263; Y10T428/264; Y10T428/31504; Y10T428/31511; Y10T428/31515; Y10T428/31522; Y10T428/31678; Y10T428/31681

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 123 words
A laminate comprising in order a metallic layer, an adhesive composition layer and an etchable polyimide layer, wherein the adhesive composition comprises a cross-linked reactive oligomer having in a backbone hydrolyzable phenolic ester groups of an equivalent weight in a range from 200 to 10,000, with the requirement that a 50 micrometer thick film of the composition after cure disintegrates within 50 cycles of alternatingly submersing the film in a stirred solution containing by weight 13% potassium hydroxide, 11% distilled water, and 76% ethanol at 60° C. for 1 minute, and in a stirred bath of deionized water at 60° C. for 30 seconds, one submersion in the ethanolic potassium hydroxide solution followed by one submersion in the deionized water, constituting one cycle.
Claim 2
Dependent Claim 123 words
A laminate comprising in order a metallic layer, an adhesive composition layer and an etchable polyimide layer, wherein the adhesive composition comprises a cross-linked reactive oligomer having in a backbone hydrolyzable phenolic ester groups of an equivalent weight in a range from 200 to 10,000, with the requirement that a 50 micrometer thick film of the composition after cure disintegrates within 50 cycles of alternatingly submersing the film in a stirred solution containing by weight 13% potassium hydroxide, 11% distilled water, and 76% ethanol at 60° C. for 1 minute, and in a stirred bath of deionized water at 60° C. for 30 seconds, one submersion in the ethanolic potassium hydroxide solution followed by one submersion in the deionized water, constituting one cycle.
Claim 3
Dependent Claim 13 words
A laminate as defined in claim 1, wherein the metallic film is copper.
Claim 4
Dependent Claim 16 words
A laminate as defined in claim 1, wherein the crosslinked reactive oligomer is a cross-linked epoxy.
Claim 5
Dependent Claim 16 words
A laminate as defined in claim 1, wherein the cross-linked reactive oligomer is a cross-linked oligoimide.
Claim 6
Dependent Claim 128 words
A laminate as defined in claim 1, wherein the cross-linked oligoimide has the formula: ##STR4## R 1 is --H, --CH 3 , --C 2 H 5 or --CF 3 ; R 2 is --H, --CH 3 , --C 2 H 5 or --CF 3 ; R3 is a divalent radical having at least an aromatic portion through which it provides at least one of its two valencies; R 3 , R 4 and R 5 have molecular weights so that their sum is less than 2,000; n is 0 to 1; m is 0 to 1, so that m+n=1; p is 0 to 15; v is 0 to 1; t is 0.95 to 0; s is 0.05 to 1, so that t+s=1; and q is greater than 10.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-01-27 1995-07-29 1996-01-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-01-27 1999-07-29 2000-01-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-01-27 2003-07-29 2004-01-28 $7700.00 Window Closed / Lapsed

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