US5082938A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Organic materials containing poly(oxyalkylene) moieties having enhanced functionality and their preparation
Assignee: MILLIKEN RESEARCH Corp A CORPORATION OF
•
Filing: 1990-03-01
•
Granted: 1992-01-21
•
Expires: 2010-03-01
Abstract
Abstract Enhanced branched chain hydroxyl compounds are provided of formula Y--(Z).sub.1-6 wherein Y is the residue of a nucleophile devoid of conjugated divalent linking moieties, and each Z is a poly(oxyalkylene) moiety having a molecular weight of from about 200-10,000 and containing at least one glycidol residue, wherein at least one of the primary oxy sites of said glycidol residue is linked preferably directly to a first epoxide residue of three or more carbons, and wherein said first epoxide residue is linked through a secondary oxy site preferably directly to a second epoxide reside having a primary terminal hydroxyl.
Inventors
- 👤 Edward W. Kluger
- 👤 David J. Moody
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 05:25
CPC Classifications
C; C09; C09B; C09B69/00; C08; C08G; C08G65/00; C08G65/02; C08G65/26; C08G65/2618; C08G65/2621; C08G65/2627
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
183 words
A compound having the formula Y--(Z).sub.1-6 wherein Y is the residue of a reactant selected from: anilines; 1,2,3,4-tetrahydroquinolines; 3,4-dihydro-2H-1,4-benzoxazines; 2-aminothiazoles; indoles; 2,3-dihydroindoles; carbazoles; naphthylamines; phenoxazines; phenothiazines; diphenylamines; julolidines; 2-aminothiophenes; and aminopyridines, and each Z is a poly(oxyalkylene) moiety having a glycidol segment containing one or more glycidol residues, provided that said compound comprises at least two of said glycidol residues, and wherein a primary oxy site of said glycidol segment is linked directly to a first epoxide segment containing at least one residue of an epoxide of three or more carbons, wherein in said first epoxide segment said epoxide residue of three or more carbons is either directly linked to said glycidol segment at said primary oxy site or is positioned in said segment within ten epoxide residues of said primary oxy site, said first epoxide segment being linked through a secondary oxy site directly to a second epoxide segment containing at least one epoxide residue having a primary terminal hydroxyl, and wherein a secondary hydroxyl of said glycidol segment is linked directly to a third epoxide segment having a primary terminal hydroxyl.
Claim 2
Dependent Claim
183 words
A compound having the formula Y--(Z).sub.1-6 wherein Y is the residue of a reactant selected from: anilines; 1,2,3,4-tetrahydroquinolines; 3,4-dihydro-2H-1,4-benzoxazines; 2-aminothiazoles; indoles; 2,3-dihydroindoles; carbazoles; naphthylamines; phenoxazines; phenothiazines; diphenylamines; julolidines; 2-aminothiophenes; and aminopyridines, and each Z is a poly(oxyalkylene) moiety having a glycidol segment containing one or more glycidol residues, provided that said compound comprises at least two of said glycidol residues, and wherein a primary oxy site of said glycidol segment is linked directly to a first epoxide segment containing at least one residue of an epoxide of three or more carbons, wherein in said first epoxide segment said epoxide residue of three or more carbons is either directly linked to said glycidol segment at said primary oxy site or is positioned in said segment within ten epoxide residues of said primary oxy site, said first epoxide segment being linked through a secondary oxy site directly to a second epoxide segment containing at least one epoxide residue having a primary terminal hydroxyl, and wherein a secondary hydroxyl of said glycidol segment is linked directly to a third epoxide segment having a primary terminal hydroxyl.
Claim 3
Dependent Claim
21 words
A compound according to claim 1 wherein each Z moiety has a molecular weight of from about 200 to about 10,000.
Claim 4
Dependent Claim
22 words
A compound according to claim 2 wherein said glycidol segment is linked directly to a nitrogen linked directly to an aromatic compound.
Claim 5
Dependent Claim
28 words
A compound according to claim 2 wherein said glycidol segment is connected directly to an aromatic compound through or by an oxy, thio, sulfinyl, sulfonamido or imido linkage.
Claim 6
Dependent Claim
71 words
A compound according to claim 4 wherein each Z moiety contains in close proximity to said aromatic compound a segment of at least two linked glycidol residues, which segment has been reacted with propylene oxide or butylene oxide in stoichiometric excess of the glycidol residue hydroxyl sites, and wherein the resultant product has been reacted with ethylene oxide reactant to provide at least two terminal --CH 2 CH 2 OH groups.
Claim 7
Dependent Claim
52 words
A compound according to claim 4 wherein said first epoxide segment contains a total of from about 2 to about 15 residues of propylene oxide, butylene oxide or mixtures thereof, and said second epoxide segment and said third epoxide segment each contain from about 2 to about 50 residues of ethylene oxide.
Claim 8
Dependent Claim
109 words
A compound having the formula Y--(Z).sub.1-6 wherein Y is the residue of a reactant selected from: anilines; 1,2,3,4-tetrahydroquinolines; 3,4-dihydro-2H-1,4-benzoxazines; 2-aminothiazoles; indoles; 2,3-dihydroindoles; carbazoles; naphthylamines; phenoxazines; phenothiazines; diphenylamines; julolidines; 2-aminothiophenes; and aminopyridines, and each Z is a poly(oxyalkylene) moiety having a glycidol segment containing one or more glycidol residues, provided that said compound comprises at least three of said glycidol residues, said glycidol segment comprising a primary oxy site and a secondary oxy site, said poly(oxyalkylene) moiety having secondary hydroxyl forming epoxide residues linked to said primary and secondary oxy sites, and each of said secondary hydroxyl forming epoxide residues are terminated with an epoxide residue having a primary hydroxyl.
Claim 9
Dependent Claim
109 words
A compound having the formula Y--(Z).sub.1-6 wherein Y is the residue of a reactant selected from: anilines; 1,2,3,4-tetrahydroquinolines; 3,4-dihydro-2H-1,4-benzoxazines; 2-aminothiazoles; indoles; 2,3-dihydroindoles; carbazoles; naphthylamines; phenoxazines; phenothiazines; diphenylamines; julolidines; 2-aminothiophenes; and aminopyridines, and each Z is a poly(oxyalkylene) moiety having a glycidol segment containing one or more glycidol residues, provided that said compound comprises at least three of said glycidol residues, said glycidol segment comprising a primary oxy site and a secondary oxy site, said poly(oxyalkylene) moiety having secondary hydroxyl forming epoxide residues linked to said primary and secondary oxy sites, and each of said secondary hydroxyl forming epoxide residues are terminated with an epoxide residue having a primary hydroxyl.
Claim 10
Dependent Claim
28 words
A compound according to claim 7 wherein said poly(oxyalkylene) moiety is connected directly to an aromatic compound through or by an oxy, thio, sulfinyl, sulfonamido or imido linkage.
Claim 11
Dependent Claim
22 words
A compound according to claim 7 wherein said secondary hydroxyl forming epoxide residue is a residue of propylene oxide or butylene oxide.
Claim 12
Dependent Claim
21 words
A compound according to claim 8 wherein said secondary hydroxyl forming epoxide residue is terminated with a residue of ethylene oxide.
Claim 13
Dependent Claim
23 words
A compound according to claim 8 wherein said secondary hydroxyl forming epoxide residue is terminated with a plurality of residues of ethylene oxide.
Claim 14
Dependent Claim
38 words
A compound according to claim 11 wherein said glycidol segment is connected directly to an aromatic compound through or by an oxy, thio, sulfinyl, sulfonamido or imido linkage and the number of poly(oxyalkylene) moieties is one or two.
References Cited (Backward Citations)
US3157633A
Cited
US3154535A
Cited
US3446757A
Cited
US3535382A
Cited
US4086151A
Cited
US3945894A
Cited
US4298764A
Cited
US4594454A
Cited
US4812141A
Cited
US4659774A
Cited
US4761502A
Cited
US4751254A
Cited
US4877411A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1995-01-20 | 1995-07-22 | 1996-01-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1999-01-20 | 1999-07-22 | 2000-01-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2003-01-20 | 2003-07-22 | 2004-01-21 | $7700.00 | Window Closed / Lapsed |