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US5075393A Expired / Lapsed US ⏱️ 0.0 years remaining

Thickened moulding compositions

Assignee: Scott Bader Co Ltd
•
Filing: 1989-08-16
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Granted: 1991-12-24
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Expires: 2009-08-16
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Abstract

Abstract A moulding composition comprises a fibrous reinforcement, an ethylenically unsaturated, essentially amorphous, polymer, a cross-linking agent copolymerizable therewith and, as a thickener and low profile/shrinkage control agent, a crystalline saturated polyester which (a) has a number average molecular weight of from 700-10,000 inclusive, (b) has a melting point within a range of from 50°-140° C. inclusive, and (c) is soluble in an equal weight of the cross-linking agent at 100° C. and yet insoluble therein at 30° C.

Inventors

  • 👤 Stephen J. Thompson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 18:03
CPC Classifications
C; C08; C08L; C08L63/00; C08L63/10; C08F; C08F290/00; C08F290/08; C08F290/14; C08F290/147; C08F299/00; C08F299/02; C08F299/04; C08F299/0478; C08L67/00; C08L67/06

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 128 words
A moulding composition comprising a fibrous reinforcement, an ethylenically unsaturated, essentially amorphous polymer, a cross-linking agent copolymerizable therewith and, as a thickener and low profile/shrinkage control agent, a crystalline polyester containing no ethylenic unsaturation, the amorphous polymer being selected from ethylenically unsaturated polyesters, vinyl ester polymers and urethane acrylate polymers, and the crystalline polyester (a) having a number average molecular weight of from 800-4,000 exclusive, (b) having a melting point within a range of from 50°-140° C. inclusive, (c) being soluble in an equal weight of styrene at 100° C. and yet insoluble therein at 30° C., and (d) being present in the composition in an amount, by weight of the total weight of the amorphous polymer, cross-linking agent and crystalline polyester, of from 5 to 50% inclusive.
Claim 2
Dependent Claim 128 words
A moulding composition comprising a fibrous reinforcement, an ethylenically unsaturated, essentially amorphous polymer, a cross-linking agent copolymerizable therewith and, as a thickener and low profile/shrinkage control agent, a crystalline polyester containing no ethylenic unsaturation, the amorphous polymer being selected from ethylenically unsaturated polyesters, vinyl ester polymers and urethane acrylate polymers, and the crystalline polyester (a) having a number average molecular weight of from 800-4,000 exclusive, (b) having a melting point within a range of from 50°-140° C. inclusive, (c) being soluble in an equal weight of styrene at 100° C. and yet insoluble therein at 30° C., and (d) being present in the composition in an amount, by weight of the total weight of the amorphous polymer, cross-linking agent and crystalline polyester, of from 5 to 50% inclusive.
Claim 3
Dependent Claim 35 words
A moulding composition according to claim 1, wherein the crystalline polyester has a melt viscosity within a range of from 1 p (0.1 Pa.s) at 125° C. to 40 p (4 Pa.s) at 150° C.
Claim 4
Dependent Claim 19 words
A moulding composition according to claim 1, wherein the crystalline polyester has a melting point of from 60°-120° C.
Claim 5
Dependent Claim 19 words
A moulding composition according to claim 1, wherein the said amount of the crystalline polyester is from 10-40% inclusive.
Claim 6
Dependent Claim 31 words
A moulding composition according to claim 1, wherein the crystalline polyester has a glycol component derived from at least one of ethylene glycol, propylene glycol, 1,4-butanediol, 1,6-hexanediol, diethylene glycol and 1,4-cyclohexanedimethanol.
Claim 7
Dependent Claim 21 words
A moulding composition according to claim 1, wherein the crystalline polyester has a glycol component derived from at least two glycols.
Claim 8
Dependent Claim 38 words
A moulding composition according to claim 1, wherein the crystalline polyester has an acid component derived from at least one of adipic acid, succinic acid, azelaic acid, terephthalic acid and isophthalic acid, and reactive derivatives of said acids.
Claim 9
Dependent Claim 24 words
A moulding composition according to claim 1, wherein the crystalline polyester has an acid component derived from at least two saturated dibasic carboxylic acids.
Claim 10
Dependent Claim 15 words
A moulding composition according to claim 1, wherein the crosslinking agent is a vinyl monomer.
Claim 11
Dependent Claim 30 words
A moulding composition according to claim 9, wherein the vinyl monomer is selected from styrene, vinyl toluene, p-methyl styrene, chlorostyrene, t-butyl styrene, methyl methacrylate, a glycol diacrylate and diallyl phthalate.
Claim 12
Dependent Claim 13 words
A moulding composition according to claim 10, wherein the vinyl monomer is styrene.
Claim 13
Dependent Claim 13 words
A moulding composition according to claim 1, which is a sheet moulding compound.
Claim 14
Dependent Claim 12 words
A moulding composition according to claim 1, which additionally contains a filler.
Claim 15
Dependent Claim 18 words
A moulding composition according to claim 1, which contains, as an additional thickener, a crystalline ethylenically unsaturated polyester.
Claim 16
Dependent Claim 20 words
A moulding composition according to claim 1, which contains an additional agent selected from low profile and shrinkage control agents.

References Cited (Backward Citations)

GB1318517A Cited
GB1319243A Cited
GB1370138A Cited
US3923927A Cited
US3959209A Cited
EP0083837A1 Cited
US4837270A Cited
EP0271970A2 Cited
US4895895A Cited
WO1989006258A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-12-23 1995-06-24 1995-12-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-12-23 1999-06-24 1999-12-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-12-23 2003-06-24 2003-12-24 $7700.00 Window Closed / Lapsed

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