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US5075370A Expired / Lapsed US ⏱️ 0.0 years remaining

Aqueous coating composition based on specific two-component polyurethanes and to a process for its production

Assignee: Bayer AG
•
Filing: 1989-08-18
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Granted: 1991-12-24
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Expires: 2009-08-18
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Abstract

Abstract The present invention is directed to a two-component coating composition which contains as binder components a) a polyol component containing at least one hydroxyl-containing polymer having chemically incorporated carboxylate and/or sulfonate groups and based on olefinically unsaturated compounds and b) a polyisocyanate component having a viscosity at 23° C. of about 50 to 10,000 mPa.s and based on at least one organic polyisocyanate in quantities corresponding to an NCO/OH equivalent ratio of about 0.5:1 to 5:1, characterized in that component a) is an aqueous solution and/or dispersion of a polymer containing hydroxyl groups in which the polyisocyanate component b) is present in emulsified form. The present invention also relates to a process for the production of this coating composition which is characterized in that a polyisocyanate component having a viscosity at 23° C. of about 50 to 10,000 mPa.s and based on at least one organic polyisocyanate is emulsified in an aqueous solution or dispersion of one or more polymer resins containing hydroxyl groups and chemically incorporated sulfonate and/or carboxylate groups in a quantity which makes them soluble and/or dispersible in water, the quantitative ratios between the two components corresponding to an NCO/OH equivalent ratio, based on the isocyanate groups of the polyisocyanate component and the incorporated hydroxyl groups of the polymer component, of about 0.5:1 to 5:1.

Inventors

  • 👤 Werner Kubitza
  • 👤 Hermann Gruber
  • 👤 Joachim Probst

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 08:29
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/70; C08G18/703; C08G18/705; C08G18/706; C08G18/08; C08G18/0804; C08G18/0819; C08G18/28; C08G18/40; C08G18/62; C08G18/6216; C08G18/622; C08G18/6225; C08G18/6229; C08G18/625; C08G18/6254; C08G18/6287

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 133 words
A two-component coating composition wherein the binder components comprise a) a polyol component comprising an aqueous solution and/or dispersion of at least one polyacrylate containing hydroxyl groups and prepared from olefinically unsaturated compounds, said polyacrylate containing chemically incorporated groups comprising a member selected from the group consisting of carboxylate groups, sulfonate groups and mixtures of carboxylate and sulfonate groups in a quantity which is sufficient to make said polyacrylate soluble and/or dispersible in water and b) a polyisocyanate component containing free isocyanate groups and having a viscosity at 23° C. of about 50 to 10,000 mPa.s and comprising at least one organic polyisocyanate, wherein components a) and b) are present in quantities corresponding to an NCO:OH equivalent ratio of 0.5:1 to 5:1 and component b) is present in emulsified form in component a).
Claim 2
Dependent Claim 133 words
A two-component coating composition wherein the binder components comprise a) a polyol component comprising an aqueous solution and/or dispersion of at least one polyacrylate containing hydroxyl groups and prepared from olefinically unsaturated compounds, said polyacrylate containing chemically incorporated groups comprising a member selected from the group consisting of carboxylate groups, sulfonate groups and mixtures of carboxylate and sulfonate groups in a quantity which is sufficient to make said polyacrylate soluble and/or dispersible in water and b) a polyisocyanate component containing free isocyanate groups and having a viscosity at 23° C. of about 50 to 10,000 mPa.s and comprising at least one organic polyisocyanate, wherein components a) and b) are present in quantities corresponding to an NCO:OH equivalent ratio of 0.5:1 to 5:1 and component b) is present in emulsified form in component a).
Claim 3
Dependent Claim 64 words
The coating composition of claim 1 wherein said polyacrylate has an average molecular weight M n of about 500 to 50,000, a hydroxyl value of 16.5 to 264 mg KOH/g of said polyacrylate, an acid value of 0 to 150 mg KOH/g of said polyacrylate and a content of said chemically incorporated groups of 5 to 417 milliequivalents per 100 g of said polyacrylate.
Claim 4
Dependent Claim 18 words
The coating composition of claim 2 wherein said polyisocyanate component exclusively contains aliphatically or cycloaliphatically bound isocyanate groups.
Claim 5
Dependent Claim 18 words
The coating composition of claim 1 wherein said polyisocyanate component exclusively contains aliphatically or cycloaliphatically bound isocyanate groups.
Claim 6
Dependent Claim 126 words
A process for the production of a two-component coating composition which comprises emulsifying a) a polyisocyanate component containing free isocyanate groups and having a viscosity at 23° C. of about 50 to 10,000 mPa.s and comprising at least one organic polyisocyanate b) in a polyol component comprising an aqueous solution and/or dispersion of at least one polyacrylate containing hydroxyl groups and prepared from olefinically unsaturated compounds, said polyacrylate containing chemically incorporated groups comprising a member selected from the group consisting of carboxylate groups, sulfonate groups and mixtures of sulfonate and carboxylate groups in a quantity which is sufficient to make said polyacrylate soluble and/or dispersible in water, wherein components a) and b) are present in quantities corresponding to an NCO:OH equivalent ratio of 0.5:1 to 5:1.
Claim 7
Dependent Claim 126 words
A process for the production of a two-component coating composition which comprises emulsifying a) a polyisocyanate component containing free isocyanate groups and having a viscosity at 23° C. of about 50 to 10,000 mPa.s and comprising at least one organic polyisocyanate b) in a polyol component comprising an aqueous solution and/or dispersion of at least one polyacrylate containing hydroxyl groups and prepared from olefinically unsaturated compounds, said polyacrylate containing chemically incorporated groups comprising a member selected from the group consisting of carboxylate groups, sulfonate groups and mixtures of sulfonate and carboxylate groups in a quantity which is sufficient to make said polyacrylate soluble and/or dispersible in water, wherein components a) and b) are present in quantities corresponding to an NCO:OH equivalent ratio of 0.5:1 to 5:1.
Claim 8
Dependent Claim 63 words
The process of claim 5 wherein said polyacrylate has an average molecular weight M n of about 500 to 50,000, a hydroxyl value of 16.5 to 264 mg KOH/g of said polyacrylate, an acid value of 0 to 150 mg KOH/g of said polyacrylate and a content of said chemically incorporated groups of 5 to 417 milliequivalents per 100 g of said polyacrylate.
Claim 9
Dependent Claim 17 words
The process of claim 6 wherein said polyisocyanate component exclusively contains aliphatically or cycloaliphatically bound isocyanate groups.
Claim 10
Dependent Claim 17 words
The process of claim 5 wherein said polyisocyanate component exclusively contains aliphatically or cycloaliphatically bound isocyanate groups.

References Cited (Backward Citations)

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GB1530022A Cited
GB1530021A Cited
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US4389509A Cited
US4186118A Cited
US4730021A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-12-23 1995-06-24 1995-12-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-12-23 1999-06-24 1999-12-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-12-23 2003-06-24 2003-12-24 $7700.00 Window Closed / Lapsed

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