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US5071937A Expired / Lapsed US ⏱️ 0.0 years remaining

Coating compositions based on blocked polyisocyanates and sterically hindered aromatic polyamines

Assignee: Bayer Corp
•
Filing: 1990-08-30
•
Granted: 1991-12-10
•
Expires: 2010-08-30
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Abstract

Abstract The present invention is directed to a coating composition which possesses improved storage stability and contains a) a blocked polyisocyanate prepared by blocking the isocyanate groups of an organic polyisocyanate with a blocking agent based on a di-C1-C12-alkyl and/or -alkoxyalkyl malonate or an acetoacetic acid C1-C12-alkyl and/or -alkoxyalkyl ester b) an aromatic polyamine, and c) is free from compounds having monofunctional reactivity towards isocyanate groups.

Inventors

  • 👤 Terry A. Potter
  • 👤 Stephen D. Seneker

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 17:38
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/70; C08G18/72; C08G18/80; C08G18/8061; C08G18/8093; C08G18/08; C08G18/10; C08G18/12; C08G18/28; C08G18/30; C08G18/32; C08G18/3225; C08G18/3237

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 107 words
A coating composition which possesses improved storage stability and comprises a) a blocked polyisocyanate prepared by blocking the isocyanate groups of an organic polyisocyanate with a blocking agent which comprises a member selected from the group consisting of di-C 1 -C 12 -alkyl malonates, di-C 1 -C 12 -alkoxyalkyl malonates, acetoacetic acid C 1 -C 12 -alkyl esters, acetoacetic acid C 1 -C 12 -alkoxyalkyl esters and mixtures thereof, and b) a sterically hindered aromatic polyamine which is sterically hindered by alkyl groups in at least one ortho position to each amino group, wherein said coating composition is free from compounds having monofunctional reactivity towards isocyanate groups.
Claim 2
Dependent Claim 107 words
A coating composition which possesses improved storage stability and comprises a) a blocked polyisocyanate prepared by blocking the isocyanate groups of an organic polyisocyanate with a blocking agent which comprises a member selected from the group consisting of di-C 1 -C 12 -alkyl malonates, di-C 1 -C 12 -alkoxyalkyl malonates, acetoacetic acid C 1 -C 12 -alkyl esters, acetoacetic acid C 1 -C 12 -alkoxyalkyl esters and mixtures thereof, and b) a sterically hindered aromatic polyamine which is sterically hindered by alkyl groups in at least one ortho position to each amino group, wherein said coating composition is free from compounds having monofunctional reactivity towards isocyanate groups.
Claim 3
Dependent Claim 13 words
The composition of claim 1 wherein said organic polyisocyanate contains aromatically-bound isocyanate groups.
Claim 4
Dependent Claim 13 words
The composition of claim 1 wherein said organic polyisocyanate comprises an isocyanate-terminated prepolymer.
Claim 5
Dependent Claim 13 words
The composition of claim 2 wherein said organic polyisocyanate comprises an isocyanate-terminated prepolymer.
Claim 6
Dependent Claim 81 words
A coating composition which possesses improved storage stability and comprises a) a blocked polyisocyanate prepared by blocking the isocyanate groups of an organic polyisocyanate with a blocking agent comprising a member selected from the group consisting of diethyl malonate, ethylacetoacetate and mixtures thereof, and b) a sterically hindered aromatic polyamine which is sterically hindered by alkyl groups in at least one ortho position to each amino group, wherein said coating composition is free from compounds having monofunctional reactivity towards isocyanate groups.
Claim 7
Dependent Claim 81 words
A coating composition which possesses improved storage stability and comprises a) a blocked polyisocyanate prepared by blocking the isocyanate groups of an organic polyisocyanate with a blocking agent comprising a member selected from the group consisting of diethyl malonate, ethylacetoacetate and mixtures thereof, and b) a sterically hindered aromatic polyamine which is sterically hindered by alkyl groups in at least one ortho position to each amino group, wherein said coating composition is free from compounds having monofunctional reactivity towards isocyanate groups.
Claim 8
Dependent Claim 13 words
The composition of claim 5 wherein said organic polyisocyanate contains aromatically-bound isocyanate groups.
Claim 9
Dependent Claim 13 words
The composition of claim 5 wherein said organic polyisocyanate comprises an isocyanate-terminated prepolymer.
Claim 10
Dependent Claim 13 words
The composition of claim 6 wherein an organic polyisocyanate comprises an isocyanate-terminated prepolymer.

References Cited (Backward Citations)

US4480008A Cited
US4500696A Cited
US4980399A Cited
US4935485A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-12-09 1995-06-10 1995-12-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-12-09 1999-06-10 1999-12-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-12-09 2003-06-10 2003-12-10 $7700.00 Window Closed / Lapsed

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