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US5071482A Expired / Lapsed US ⏱️ 0.0 years remaining

Pigment preparations

Assignee: Clariant Produkte Deutschland GmbH
•
Filing: 1989-09-20
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Granted: 1991-12-10
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Expires: 2009-09-20
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Abstract

Abstract Pigment preparations consisting of organic pigments and basic additives of the general formula I (Q-A).sub.x Y (I) in which Q is a radical of the formula II ##STR1## in which R 1 is halogen, an alkyl, alkoxy or cyano group, R 2 is halogen, m and n are integers from 0 to 4, A is a chemical bond or a divalent group from the series consisting of --(CH 2 ) p --, --CR 3 R 4 --, arylene, --S--, --O-- and --NR 5 --, in which p is an integer from 1 to 12, R 3 is hydrogen or alkyl, R 4 is alkyl and R 5 is hydrogen or alkyl, Y is a tertiary nitrogen atom or a group ##STR2## in which R 6 , R 7 and R 8 are alkyl or alkenyl or a cycloaliphatic or araliphatic radical or an alkyleneheteroaryl radical, or Y is a saturated or unsaturated heterocyclic radical in which at least one tertiary nitrogen atom is included in the meanings mentioned for Y and x is a number from 1 to 6.

Inventors

  • 👤 Erwin Dietz
  • 👤 Siegfried Schiessler
  • 👤 Manfred Urban

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 08:23
CPC Classifications
C; C09; C09B; C09B67/00; C09B67/0033; C09B57/00; C09B57/12

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 287 words
A pigment preparation comprising: (a) an organic pigment, and (b) as an additive with dispersant properties for preventing flocculation of a said pigment, a basic compound of the general formula I (Q--A).sub.X Y (I) in which Q is a radical of the general formula II ##STR45## in which R 1 is a halogen atom, a C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy or cyano group, where in the case that m>1, R 1 can have a combination of the meanings mentioned; R 2 is a halogen atom, m and n are integers from 0 to 4, A is a chemical bond or the divalent group, --(CH 2 ) p --, --CR 3 R 4 --, arylene, --S--, --O-- or --NR 5 --, alone or in a chemically reasonable combination, in which p is an integer from 1 to 12, R 3 is a hydrogen atom or a C 1 -C 6 -alkyl group, R 4 is a C 1 -C 6 -alkyl group and R 5 is a hydrogen atom or a C 1 -C 6 -alkyl group, Y is a tertiary nitrogen atom or a group ##STR46## in which R 6 , R 7 and R 8 are C 1 -C 20 -alkyl or C 1 -C 20 -alkenyl groups whose carbon chains are not interrupted or are interrupted by heteroatoms and are unsubstituted or substituted by a terminal hydroxyl, primary amino group or an acylamino group or are cycloaliphatic (C 5 -C 6 ), araliphatic or alkylene-heteroaryl radicals, or Y is a saturated or unsaturated heterocyclic radical in which at least one tertiary nitrogen atom is included in the meanings mentioned for Y, and x is an integer from 1 to 6.
Claim 2
Dependent Claim 287 words
A pigment preparation comprising: (a) an organic pigment, and (b) as an additive with dispersant properties for preventing flocculation of a said pigment, a basic compound of the general formula I (Q--A).sub.X Y (I) in which Q is a radical of the general formula II ##STR45## in which R 1 is a halogen atom, a C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy or cyano group, where in the case that m>1, R 1 can have a combination of the meanings mentioned; R 2 is a halogen atom, m and n are integers from 0 to 4, A is a chemical bond or the divalent group, --(CH 2 ) p --, --CR 3 R 4 --, arylene, --S--, --O-- or --NR 5 --, alone or in a chemically reasonable combination, in which p is an integer from 1 to 12, R 3 is a hydrogen atom or a C 1 -C 6 -alkyl group, R 4 is a C 1 -C 6 -alkyl group and R 5 is a hydrogen atom or a C 1 -C 6 -alkyl group, Y is a tertiary nitrogen atom or a group ##STR46## in which R 6 , R 7 and R 8 are C 1 -C 20 -alkyl or C 1 -C 20 -alkenyl groups whose carbon chains are not interrupted or are interrupted by heteroatoms and are unsubstituted or substituted by a terminal hydroxyl, primary amino group or an acylamino group or are cycloaliphatic (C 5 -C 6 ), araliphatic or alkylene-heteroaryl radicals, or Y is a saturated or unsaturated heterocyclic radical in which at least one tertiary nitrogen atom is included in the meanings mentioned for Y, and x is an integer from 1 to 6.
Claim 3
Dependent Claim 89 words
A pigment preparation as claimed in claim 1, wherein in the radical Q of said general formula II, m is 0 or 1 and n is 0, A is the divalent group --(CH 2 ) 2-4 --, Y is a dialkyl(C 1 -C 6 )amino group whose alkyl groups are unsubstituted or substituted by terminal hydroxyl or primary amino groups or acylamino groups or Y is a saturated or unsaturated heterocyclic radical which contains at least one tertiary nitrogen atom and x is an integer from 1 to 3.
Claim 4
Dependent Claim 21 words
A pigment preparation as claimed in claim 1, wherein a pigment contained therein is an azo pigment or a polycyclic pigment.
Claim 5
Dependent Claim 38 words
A pigment preparation as claimed in claim 1, wherein a pigment contained therein is a polycyclic pigment of the anthraquinone, anthrapyrimidine, anthanthrone, quinacridone, quinophthalone, diketopyrrolopyrrole, dioxazine, flavanthrone, indanthrone, isoindoline, isoindolinone, isoviolanthrone, perinone, perylene, phthalocyanine, pyranthrone or thioindigo series.
Claim 6
Dependent Claim 36 words
A pigment preparation as claimed in claim 1, wherein a pigment contained therein is present as a pure pigment or in the form of a physical mixture or as mixed crystals of two or more pigments.
Claim 7
Dependent Claim 22 words
A pigment preparation as claimed in claim 1, wherein a pigment contained therein is from the series of perinone or anthanthrone pigments.
Claim 8
Dependent Claim 44 words
A pigment preparation as claimed in claim 1, wherein the pigment preparation comprises 99.9 to 85% by weight of one or more organic pigments and 0.1 to 15% by weight of at least one basic additive of said general formula I of claim 1.
Claim 9
Dependent Claim 44 words
A pigment preparation as claimed in claim 1, wherein the pigment preparation comprises 99 to 92% by weight of one or more organic pigments and 1 to 8% by weight of at least one basic additive of said general formula I of claim 1.
Claim 10
Dependent Claim 25 words
A method for the pigmenting of a high-molecular-weight organic material comprising the step of pigmenting the organic material with a pigment preparation of claim 1.
Claim 11
Dependent Claim 24 words
A method for the pigmenting of a lacquer system comprising the step of pigmenting the lacquer system with a pigment preparation of claim 1.
Claim 12
Dependent Claim 155 words
A pigment preparation comprising an organic pigment and a basic additive of the general formula I (Q--A).sub.X Y (I) in which Q is a radical of the general formula II ##STR47## in which R 1 is a halogen atom, a C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy or cyano group, where in the case that m>1 R 1 can have a combination of the meanings mentioned, R 2 is a halogen atom, m and n are integers from 0 to 4, A is a divalent group of the formula --(CH 2 ) p --, where p is 2 or 3, Y is a dimethylamino group, a diethylamino group, an imidazole radical, or a piperazine radical, and x is the number 1 or 2, or Y is the radical ##STR48## or the radical ##STR49## in which case x is 1, or Y is the divalent radical ##STR50## in which case x is 2.
Claim 13
Dependent Claim 155 words
A pigment preparation comprising an organic pigment and a basic additive of the general formula I (Q--A).sub.X Y (I) in which Q is a radical of the general formula II ##STR47## in which R 1 is a halogen atom, a C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy or cyano group, where in the case that m>1 R 1 can have a combination of the meanings mentioned, R 2 is a halogen atom, m and n are integers from 0 to 4, A is a divalent group of the formula --(CH 2 ) p --, where p is 2 or 3, Y is a dimethylamino group, a diethylamino group, an imidazole radical, or a piperazine radical, and x is the number 1 or 2, or Y is the radical ##STR48## or the radical ##STR49## in which case x is 1, or Y is the divalent radical ##STR50## in which case x is 2.
Claim 14
Dependent Claim 56 words
A pigment preparation as claimed in claim 11, wherein in the radical Q of the general formula II mentioned there m and n are zero, A is the divalent group --(CH 2 ) 2-3 --, Y is the dimethylamino or diethylamino group or an imidazole or piperazine radical and x is the number 1 or 2.
Claim 15
Dependent Claim 48 words
A pigment preparation as claimed in claim 11, wherein in the radical Q of the general formula II mentioned there m and n are zero, A is the divalent group --(CH 2 ) 2-3 --, Y is the radical ##STR51## or the radical ##STR52## and x is 1.
Claim 16
Dependent Claim 45 words
A pigment preparation as claimed in claim 11, wherein in the radical Q of the general formula II mentioned there m and n are zero, A is the divalent group --(CH 2 ) 2-3 --, Y is the divalent radical ##STR53## and x is 2.
Claim 17
Dependent Claim 291 words
A pigment preparation comprising a cis- or trans-naphthoylenebisbenzimidazole pigment or a cis/trans mixture of said pigments or the pigment 4,10-dibromoanthanthrone and a basic additive of the general formula I (Q--A).sub.x Y (I) in which Q is a radical of the general formula II ##STR54## in which R 1 is a halogen atom, a C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy or cyano group, where in the case that m>1 R 1 can have a combination of the meanings mentioned, R 2 is a halogen atom, m and n are integers from 0 to 4, A is a chemical bond or one or more of the divalent groups --(CH 2 ) p --, --CR 3 R 4 , arylene, --S--, --O--, or --NR 5 -- or a chemically reasonable combination of these divalent groups, in which p is an integer from 1 to 12, R 3 is a hydrogen atom or a C 1 -C 6 -alkyl group, R 4 is a C 1 -C 6 -alkyl group and R 5 is a hydrogen atom or a C 1 -C 6 -alkyl group, Y is a tertiary nitrogen atom or a group ##STR55## in which R 6 , R 7 and R 8 are C 1 -C 20 -alkyl or C 1 -C 20 -alkenyl groups whose carbon chains are not interrupted or are interrupted by heteroatoms and are unsubstituted or substituted by a terminal hydroxyl, primary amino group or an acylamino group or are cycloaliphatic (C 5 -C 6 ), araliphatic or alkylene-heteroaryl radicals, or Y is a saturated or unsaturated heterocyclic radical in which at least one tertiary nitrogen atom is included in the meanings mentioned for Y, and x is an integer from 1 to 6.
Claim 18
Dependent Claim 291 words
A pigment preparation comprising a cis- or trans-naphthoylenebisbenzimidazole pigment or a cis/trans mixture of said pigments or the pigment 4,10-dibromoanthanthrone and a basic additive of the general formula I (Q--A).sub.x Y (I) in which Q is a radical of the general formula II ##STR54## in which R 1 is a halogen atom, a C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy or cyano group, where in the case that m>1 R 1 can have a combination of the meanings mentioned, R 2 is a halogen atom, m and n are integers from 0 to 4, A is a chemical bond or one or more of the divalent groups --(CH 2 ) p --, --CR 3 R 4 , arylene, --S--, --O--, or --NR 5 -- or a chemically reasonable combination of these divalent groups, in which p is an integer from 1 to 12, R 3 is a hydrogen atom or a C 1 -C 6 -alkyl group, R 4 is a C 1 -C 6 -alkyl group and R 5 is a hydrogen atom or a C 1 -C 6 -alkyl group, Y is a tertiary nitrogen atom or a group ##STR55## in which R 6 , R 7 and R 8 are C 1 -C 20 -alkyl or C 1 -C 20 -alkenyl groups whose carbon chains are not interrupted or are interrupted by heteroatoms and are unsubstituted or substituted by a terminal hydroxyl, primary amino group or an acylamino group or are cycloaliphatic (C 5 -C 6 ), araliphatic or alkylene-heteroaryl radicals, or Y is a saturated or unsaturated heterocyclic radical in which at least one tertiary nitrogen atom is included in the meanings mentioned for Y, and x is an integer from 1 to 6.

References Cited (Backward Citations)

US3931186A Cited
US3973981A Cited
JPH02197461A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-12-09 1995-06-10 1995-12-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-12-09 1999-06-10 1999-12-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-12-09 2003-06-10 2003-12-10 $7700.00 Window Closed / Lapsed

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