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US5068387A Expired / Lapsed US ⏱️ 0.0 years remaining

Production of organofunctional alkoxysilanes

Assignee: Dow Silicones Corp
•
Filing: 1989-12-01
•
Granted: 1991-11-26
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Expires: 2009-12-01
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Abstract

Abstract The present invention relates to a process for the production of mixtures of novel organofunctional alkoxysilanes by the reaction of mixtures of certain substituted organic halides and chlorosilanes with molten sodium dispersed in alkoxysilanes. In the described process, the substituted organic groups of the organic halide replace alkoxy groups of the alkoxysilanes. Also claimed, are organofunctional alkoxysilanes prepared by the claimed process.

Inventors

  • 👤 Don L. Kleyer
  • 👤 John L. Speier

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 22:25
CPC Classifications
C; C07; C07F; C07F7/00; C07F7/02; C07F7/08; C07F7/18; C07F7/1804; C07F7/1872; C07F7/1892; C07F7/1876; C07F7/188

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 133 words
An organofunctional alkoxysilane of formula R.sup.1.sub.a R.sup.2.sub.b (AR).sub.n Si(OR.sup.3).sub.4-a-b-n ; where R 1 and R 2 are independently selected from the group consisting of alkyl, aryl, and AR radicals; R 3 is an alkyl of 1 to 7 carbon atoms; A is a substituent on an organic group, R, said A selected from the group consisting of R 4 O--, C z F 2z+1 --, and alkenyl radicals; R 4 and R 5 are independently selected from the group consisting of alkyl, aryl, and triorganosilyl radicals; z is 1 to 4; R is a divalent radical of the structure --R 6 (CH 2 ) m --, R 6 is selected from a group consisting of aliphatic and aromatic divalent radicals; m=0 to 6; n=2 or 3; a+b+n=2 or 3; and a+b=0 or 1.
Claim 2
Dependent Claim 133 words
An organofunctional alkoxysilane of formula R.sup.1.sub.a R.sup.2.sub.b (AR).sub.n Si(OR.sup.3).sub.4-a-b-n ; where R 1 and R 2 are independently selected from the group consisting of alkyl, aryl, and AR radicals; R 3 is an alkyl of 1 to 7 carbon atoms; A is a substituent on an organic group, R, said A selected from the group consisting of R 4 O--, C z F 2z+1 --, and alkenyl radicals; R 4 and R 5 are independently selected from the group consisting of alkyl, aryl, and triorganosilyl radicals; z is 1 to 4; R is a divalent radical of the structure --R 6 (CH 2 ) m --, R 6 is selected from a group consisting of aliphatic and aromatic divalent radicals; m=0 to 6; n=2 or 3; a+b+n=2 or 3; and a+b=0 or 1.
Claim 3
Dependent Claim 20 words
The organofunctional alkoxysilane of claim 1, where R 3 is selected from the group consisting of methyl and ethyl radicals.
Claim 4
Dependent Claim 29 words
The organofunctional alkoxysilane of claim 2, where R 6 is selected from the group consisting of --CH 2 --, --CH 2 CH 2 --, and phenyl bi-radical, and m=0.
Claim 5
Dependent Claim 21 words
The organofunctional alkoxysilane of claim 3 where substituent A is selected from the group consisting of vinyl, vinylphenyl, and 1-methylethenylphenyl radicals.
Claim 6
Dependent Claim 15 words
The organofunctional alkoxysilane of claim 3, where substituent A is the R 4 O-- radical.
Claim 7
Dependent Claim 17 words
The organofunctional alkoxysilane of claim 3, where substituent A is the C z F 2z+1 -- radical.
Claim 8
Dependent Claim 16 words
The organofunctional alkoxysilane of claim 3, where the C z F 2z+1 -- radical is trifluoromethyl.

References Cited (Backward Citations)

CA598444A Cited
GB573906A Cited
US2521267A Cited
GB668532A Cited
US2985678A Cited
US4683321A Cited
US4888436A Cited
US4897501A Cited
US4921988A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-11-25 1995-05-27 1995-11-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-11-25 1999-05-27 1999-11-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-11-25 2003-05-27 2003-11-26 $7700.00 Window Closed / Lapsed

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