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US5064877A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for fixing inorganic species in an organic matrix

Assignee: Fraunhofer-Gesellschaft zur Förderung der Angewandten Forschung eV
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Filing: 1989-07-17
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Granted: 1991-11-12
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Expires: 2009-07-17
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Abstract

Abstract A process is described for fixing an inorganic species in an organic matr which comprises bringing a compound of the formula MR n in which M is selected from sub-group metals, lanthanides, actinides, Al, Sn, B and Si, and the radicals R can be replaced by a complexing agent, into contact with a complexing agent, the complexing agent containing a functional group which is capable of participating in a polymerization or polycondensation reaction. After complexing, hydrolysis and condensation are preferably first carried out, followed by polymerization or polycondensation.

Inventors

  • 👤 Rudiger Nass
  • 👤 Helmut Schmidt

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 23:18
CPC Classifications
C; C08; C08F; C08F2/00; C08F2/44; C08F230/00; C08F230/04

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 267 words
A process for fixing an inorganic species in an organic matrix, said process comprising: bringing at least one compound of the empirical formula (I) MRn (I) wherein M is selected from sub-group metals, lanthanides, actinides, Al, Sn, B and Si, at least some of the radicals R, which may be identical or different, can be replaced by a complexing agent, and n is the quotient of the valency of M and the mean valency of the radicals R, into contact with at least one organic compound A which contains at least one functional group X which is capable of complexing with M and is capable of replacing at least some of the radicals R, and, in addition, contains at least one functional group Y which is capable of participating in a polymerization or polycondensation reaction, in a molar ratio of the compounds of the formula (I) to the compounds A such that the number of radicals R which can be theoretically replaced is greater than the number of radicals which can theoretically be replaced by the groups X, at least some of the radicals R remaining on M when complexing is complete being radicals R* which can be replaced by OH radicals by reaction with water; when complexing is complete, adding water in amounts such that and under conditions such that at least some of the radicals R* are replaced primarily by OH groups; condensing said so-formed OH groups to form oxygen bridges linking atoms M; and subsequently, carrying out a polymerization or polycondensation in which the at least one functional group Y of compound A participates.
Claim 2
Dependent Claim 267 words
A process for fixing an inorganic species in an organic matrix, said process comprising: bringing at least one compound of the empirical formula (I) MRn (I) wherein M is selected from sub-group metals, lanthanides, actinides, Al, Sn, B and Si, at least some of the radicals R, which may be identical or different, can be replaced by a complexing agent, and n is the quotient of the valency of M and the mean valency of the radicals R, into contact with at least one organic compound A which contains at least one functional group X which is capable of complexing with M and is capable of replacing at least some of the radicals R, and, in addition, contains at least one functional group Y which is capable of participating in a polymerization or polycondensation reaction, in a molar ratio of the compounds of the formula (I) to the compounds A such that the number of radicals R which can be theoretically replaced is greater than the number of radicals which can theoretically be replaced by the groups X, at least some of the radicals R remaining on M when complexing is complete being radicals R* which can be replaced by OH radicals by reaction with water; when complexing is complete, adding water in amounts such that and under conditions such that at least some of the radicals R* are replaced primarily by OH groups; condensing said so-formed OH groups to form oxygen bridges linking atoms M; and subsequently, carrying out a polymerization or polycondensation in which the at least one functional group Y of compound A participates.
Claim 3
Dependent Claim 34 words
The process as claimed in claim 1, wherein said at least one compound of the empirical formula (I) is partially hydrolysed or pre-condensed prior to contact with said at least one organic compound A.
Claim 4
Dependent Claim 20 words
The process as claimed in claim 1, wherein, in order to form said organic matrix, a polymerization is carried out.
Claim 5
Dependent Claim 14 words
The process as claimed in claim 3, wherein said polymerization is a free-radical polymerization.
Claim 6
Dependent Claim 27 words
The process as claimed in claim 3, wherein at least one organic polymerizable compound which is different from the complexing agent is also employed in the polymerization.
Claim 7
Dependent Claim 19 words
The process as claimed in claim 5, wherein said at least one organic polymerizable compound is styrene or acrylonitrile.
Claim 8
Dependent Claim 31 words
The process as claimed in claim 1, wherein M is selected from one or more elements of the group consisting of Al, V, Ti, Zr, HF, Sn, U, B and Si.
Claim 9
Dependent Claim 25 words
The process as claimed in claim 7, wherein M is selected from one or more elements of the group consisting of Al, Ti and Zr.
Claim 10
Dependent Claim 52 words
The process as claimed in claim 7, wherein at least one compound of the formula (I) is a compound of the formula (II) AlR'.sub.3 (II) wherein the radicals R', which may be identical or different, denote halogen, alkoxy having 1 to 8 carbon atoms or alkyl having 1 to 8 carbon atoms.
Claim 11
Dependent Claim 35 words
The process as claimed in claim 9, wherein the radicals R', which may be identical or different, denote chlorine, bromine, alkoxy having 1 to 4 carbon atoms or alkyl having 1 to 4 carbon atoms.
Claim 12
Dependent Claim 51 words
The process as claimed in claim 7, wherein at least one compound of the formula (I) is a compound of the formula (III) M'R".sub.4 (III) wherein M' represents Ti or Zr; and the radicals R", which may be identical or different, denote halogen or alkoxy having 1 to 8 carbon atoms.
Claim 13
Dependent Claim 28 words
The process as claimed in claim 11, wherein the radicals R", which may be identical or different, denote chlorine, bromine or alkoxy having 1 to 4 carbon atoms.
Claim 14
Dependent Claim 25 words
The process as claimed in claim 1, wherein compound A contains, as functional group X, a carboxyl group or the structural unit --CO--CH 2 --CO--.
Claim 15
Dependent Claim 19 words
The process as claimed in claim 1, wherein compound A contains, as functional group Y, an ethylenically unsaturated group.
Claim 16
Dependent Claim 24 words
The process as claimed in claim 14, wherein said ethylenically unsaturated group is CH 2 ═CZ--, where Z represents H or CH 3 .
Claim 17
Dependent Claim 26 words
The process as claimed in claim 1, wherein compound A is selected from the group consisting of acrylic acid, methacrylic acid, alkyl acetoacetate and vinyl acetoacetate.
Claim 18
Dependent Claim 33 words
The process as claimed in claim 1, wherein a polymerization catalyst is used in said polymerization, said polymerization catalyst being selected from the group consisting of benzoyl peroxide, azobisisobutyronitrile and a UV initiator.
Claim 19
Dependent Claim 43 words
The process as claimed in claim 1, wherein the ratio between the compounds of the formula (I) and the compounds A is selected so that, after complexing, two radicals R* remain on each atom M and are then removed by reaction with water.
Claim 20
Dependent Claim 17 words
An organic matrix with inorganic species fixed therein produced by the process as claimed in claim 1.

References Cited (Backward Citations)

US4835231A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-11-11 1995-05-13 1995-11-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-11-11 1999-05-13 1999-11-12 $3760.00 Window Closed / Lapsed
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