US5058514A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for controlling acid gas emissions in power plant flue gases
Assignee: Ontario Power Generation Inc
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Filing: 1990-09-17
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Granted: 1991-10-22
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Expires: 2010-09-17
Abstract
Abstract An in-furnace sorbent slurry injection process for the simultaneous control of SO2 and NOx from power plant flue gases is described. An aqueous slurry of limestone or dolomite-doped limestone and a nitrogenous progenitor compound is injected into the furnace at temperatures ranging between 900 DEG C. and 1350 DEG C. Under optimized operating conditions, with urea selected as the nitrogenous progenitor, about 80% of the SO2 and 90% of the NOx are simultaneously removed.
Inventors
- 👤 Miriam S. Mozes
- 👤 Rene Mangal
- 👤 Raja Thampi
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 03:54
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/46; B01D53/60; F; F23; F23J; F23J7/00; F23J2215/00; F23J2215/10; F23J2215/20; F23J2219/00; F23J2219/20; G; G01; G01N; G01N1/00; G01N1/02; G01N1/22; G01N1/2247; G01N2001/225; Y; Y02; Y02A; Y02A50/00; Y02A50/20
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
146 words
A process for the simultaneous reduction of the SO 2 and NO x content of flue gas from a fossil fuel fired combustion installation, comprising the step of injecting an atomized aqueous slurry composition into the combustion chamber of the installation at a location having a temperature of between about 900° C. and about 1350° C., said aqueous slurry composition comprising a dispersion in water of a finely particulate, calcium-based sorbent for SO 2 and a nitrogenous progenitor compound which produces species reactive with NO x at said temperature, the concentrations of sorbent and said compound in the slurry composition being respectively selected to provide calcium in the amount of between 1.5 and 3.0 moles Ca per mole of SO 2 and said compound in an amount to give a stoichiometric ratio of at least 1.5 moles of nitrogenous progenitor per mole of NO x .
Claim 2
Dependent Claim
146 words
A process for the simultaneous reduction of the SO 2 and NO x content of flue gas from a fossil fuel fired combustion installation, comprising the step of injecting an atomized aqueous slurry composition into the combustion chamber of the installation at a location having a temperature of between about 900° C. and about 1350° C., said aqueous slurry composition comprising a dispersion in water of a finely particulate, calcium-based sorbent for SO 2 and a nitrogenous progenitor compound which produces species reactive with NO x at said temperature, the concentrations of sorbent and said compound in the slurry composition being respectively selected to provide calcium in the amount of between 1.5 and 3.0 moles Ca per mole of SO 2 and said compound in an amount to give a stoichiometric ratio of at least 1.5 moles of nitrogenous progenitor per mole of NO x .
Claim 3
Dependent Claim
29 words
A process according to claim 1, wherein said calcium-based sorbent is selected from the group consisting of limestone and mixtures of limestone with dolomite, sodium hydroxide, or hydrated lime.
Claim 4
Dependent Claim
22 words
A process according to claim 2, wherein said atomized slurry concentration has a droplet size of up to about 150 μm MMD.
Claim 5
Dependent Claim
23 words
A process according to claim 3, wherein said nitrogenous progenitor compound is selected from the group consisting of ammonia, ammonium carbonate and urea.
Claim 6
Dependent Claim
50 words
A process according to claim 4, wherein the concentration of said nitrogenous progenitor compound in said aqueous slurry composition is selected to provide said nitrogenous progenitor compound in an amount providing a stoichiometric ratio of between 1.5 and 2.5 moles of nitrogenous progenitor compound per mole of NO x .
Claim 7
Dependent Claim
13 words
A process according to claim 4, wherein said nitrogenous progenitor compound is urea
Claim 8
Dependent Claim
33 words
A process according to claim 2, claim 3, or claim 4, wherein said atomized aqueous slurry is injected into the combustion chamber in a direction generally co-current with the flow of flue gas.
Claim 9
Dependent Claim
28 words
A process according to claim 2, claim 3, or claim 4, wherein said aqueous slurry composition is injected at a temperature of between 1100° C. and 1300° C.
Claim 10
Dependent Claim
23 words
A process according to claim 4, wherein said calcium-based sorbent is pulverized limestone intimately mixed with up to 15% by weight of dolomite
Claim 11
Dependent Claim
32 words
A process according to claim 2, wherein said nitrogenous progenitor compound is urea and said atomized aqueous slurry composition has a droplet mass median diameter in the range of 3-17 μm MMD.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1994-10-21 | 1995-04-22 | 1995-10-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1998-10-21 | 1999-04-22 | 1999-10-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2002-10-21 | 2003-04-22 | 2003-10-22 | $7700.00 | Window Closed / Lapsed |