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US5047261A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the manufacture of coatings by radiocrosslinking

Assignee: NATIONALE DES POURDRES ET EXPLOSIFS Ste
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Filing: 1990-06-19
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Granted: 1991-09-10
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Expires: 2010-06-19
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Abstract

Abstract The invention relates to a process for the manufacture of coatings by radiocrosslinking. A radio-crosslinkable composition (C) is produced first of all by mixing at least one (meth)acrylic compound (A) with a reactive diluent system comprising at least one mono(meth)acrylic carbonate (B) corresponding to the general formula (I): <IMAGE> in which: R1 denotes H or CH3 R2 denotes an alkylene ether or alkylene chain which has a total number of carbon atoms of between 2 and 6, n denotes an integer between 1 and 6. The composition (C) is next applied onto a substrate and is then radiocrosslinked, preferably using UV radiation. Another subject of the invention is the crosslinkable compositions (C) in which the compound (A) and the carbonate (B) are not simultaneously 2,3-carbonyldioxypropyl 2-methacryloyloxyethyl carbonate, and carbonates of general formula (I) in which R2 denotes (CH2)m and in which m and n are integers such that 2</=m</=6, 1</=n</=6 and n NOTEQUAL 1 when m=2 and R1 denotes CH3. The carbonates of general formula (I) are highly photosensitive, and this allows irradiation times which are very markedly shorter than those used hitherto with mono(meth)acrylic diluents, or else makes it possible to photocrosslink in the absence of photoinitiator.

Inventors

  • 👤 Khalil Moussa
  • 👤 Christian Decker
  • 👤 Jean-Claude Brosse
  • 👤 Sammy Chevalier
  • 👤 Denis Couvert

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 23:03
CPC Classifications
C; C09; C09D; C09D175/00; C09D175/04; C09D175/14; C09D175/16; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/67; C08G18/671; C08G18/672; C09D4/00

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 139 words
Process for the manufacture of coatings by radiocrosslinking, characterized in that the procedure is according to the following successive stages: a) A radiocrosslinkable composition (C) is produced by mixing at least one (meth)acrylic compound (A) with a reactive diluent system comprising at least one mono(meth)acrylic carbonate (B) corresponding to the general formula (I): ##STR17## in which: R 1 denotes hydrogen or the methyl group, R 2 denotes an alkylene ether or alkylene chain, optionally substituted by at least one methyl or ethyl group, which has a total number of carbon atoms of between 2 and 6, preferably an alkylene chain of formula (CH 2 ) m , m being an integer such that 2≦m≦6, n denotes an integer such that 1≦n≦6, b) the radiocrosslinkable composition (C) is applied onto a substrate, c) the composition (C) thus applied is radiocrosslinked.
Claim 2
Dependent Claim 139 words
Process for the manufacture of coatings by radiocrosslinking, characterized in that the procedure is according to the following successive stages: a) A radiocrosslinkable composition (C) is produced by mixing at least one (meth)acrylic compound (A) with a reactive diluent system comprising at least one mono(meth)acrylic carbonate (B) corresponding to the general formula (I): ##STR17## in which: R 1 denotes hydrogen or the methyl group, R 2 denotes an alkylene ether or alkylene chain, optionally substituted by at least one methyl or ethyl group, which has a total number of carbon atoms of between 2 and 6, preferably an alkylene chain of formula (CH 2 ) m , m being an integer such that 2≦m≦6, n denotes an integer such that 1≦n≦6, b) the radiocrosslinkable composition (C) is applied onto a substrate, c) the composition (C) thus applied is radiocrosslinked.
Claim 3
Dependent Claim 52 words
Process according to Claim 1, characterized in that the (meth)acrylic compound (A) is a liquid poly-(meth)acrylic oligomer with (meth)acrylic ends, whose number-average molecular mass is between 500 and 5,000, chosen preferably from the group consisting of (meth)acrylic polyester oligomers, (meth)acrylic epoxy oligomers, (meth)acrylic polycarbonate oligomers, (meth)acrylic polyether oligomers and (meth)acrylic polyurethane oligomers.
Claim 4
Dependent Claim 17 words
Process according to Claim 2, characterized in that the (meth)acrylic polyurethane oligomers are di(meth)acrylic linear polyurethane oligomers.
Claim 5
Dependent Claim 39 words
Process according to claim 1, characterized in that the (meth)acrylic compound (A) represents 25 to 60% by weight of the composition (C) and in that the reactive diluent system represents 75 to 40% by weight of the composition (C).
Claim 6
Dependent Claim 19 words
Process according to Claim 1, characterized in that the (meth)acrylic compound (A) is identical with the mono(meth)acrylic carbonate (B).
Claim 7
Dependent Claim 21 words
Process according to Claim 5, characterized in that the radiocrosslinkable composition (C) consists solely of the said mono(meth)acrylic carbonate compound (B).
Claim 8
Dependent Claim 24 words
Process according to claim 1, characterized in that R 2 denotes (CH 2 ) 2 and n is equal to 1, 2 or 4.
Claim 9
Dependent Claim 30 words
Process according to claim 1, characterized in that the composition (C) applied onto the substrate is crosslinked using UV radiation in the presence or in the absence of a photoinitiator.
Claim 10
Dependent Claim 23 words
Radiocrosslinkable composition (C) such as defined according to claim 1, in which the compound (A) and the carbonate (B) are not simultaneously2,3-carbonyldioxypropyl2-methacryloyloxyethyl carbonate.
Claim 11
Dependent Claim 45 words
Carbonate (B) corresponding to the general formula (I) according to Claim 1, in which R 2 denotes (CH 2 ) m and in which m and n are identical or different integers such that: 2≦m≦6 1≦n≦6 n≠1 when m=2 and R.sub.1 denotes the methyl group.

References Cited (Backward Citations)

US2967173A Cited
US4658001A Cited
US4753990A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-09-09 1995-03-11 1995-09-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-09-09 1999-03-11 1999-09-10 $3760.00 Window Closed / Lapsed
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