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US5036138A Expired / Lapsed US ⏱️ 0.0 years remaining

Elastomeric compositions, process for the preparation thereof and tires containing them

Assignee: Kraton Polymers US LLC
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Filing: 1988-10-11
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Granted: 1991-07-30
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Expires: 2008-10-11
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Abstract

Abstract The present invention relates to an elastomeric composition suitable for tire treads comprising (1) 10-90% wt of a copolymer of a mono-aromatic vinyl compound and having a vinyl content of <50% wt and a Tg<-35 degree C., and (2) 90-10% wt of a hompolymer of a conjugated diene or a copolymer of a mono-aromatic vinyl compound and a conjugated diene, containing <25% wt of mono-aromatic vinyl compound and having a vinyl content <25% wt and a Tg<-55 degree C., both polymer having a differential content of mono-aromatic vinyl compound which is <5 percentage points.

Inventors

  • 👤 Jan E. Stamhuis
  • 👤 Antonius A. Broekhuis
  • 👤 Pieter Luijk

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 10:09
CPC Classifications
C; C08; C08L; C08L9/00; B; B60; B60C; B60C1/00; B60C1/0016; C08L9/06; C08L2205/00; C08L2205/02; Y; Y10; Y10S; Y10S152/00; Y10S152/905; Y10S525/00; Y10S525/941

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 206 words
An elastomeric composition suitable for use in the tread portion of pneumatic tire, said composition comprising: (1) from 10 to 90% by weight of a copolymer A of a mono-aromatic vinyl compound and a conjugated diene and having a content of mono-aromatic vinyl compound in the range of from 10 to 40% by weight, a vinyl content in the conjugated diene units of at least 50% by weight, calculated on total conjugated diene units, and a glass transition temperature above minus 35° C., and (2) from 90 to 10% by weight of a polymer B which is a homopolymer of a conjugated diene or a copolymer of a mono-aromatic vinyl compound and a conjugated diene, said polymer B containing less than 25% by weight of mono-aromatic vinyl compound and having a vinyl content in the conjugated diene units of less than 25% and a glass transition temperature below minus 55° C., said percentages by weight of copolymer A and polymer B being calculated on the total of A and B, and copolymer A and polymer B, if present as a copolymer, having a differential content of the aromatic vinyl compound over the polymer chain which varies less than five percentage points; as determined by monomer conversion.
Claim 2
Dependent Claim 206 words
An elastomeric composition suitable for use in the tread portion of pneumatic tire, said composition comprising: (1) from 10 to 90% by weight of a copolymer A of a mono-aromatic vinyl compound and a conjugated diene and having a content of mono-aromatic vinyl compound in the range of from 10 to 40% by weight, a vinyl content in the conjugated diene units of at least 50% by weight, calculated on total conjugated diene units, and a glass transition temperature above minus 35° C., and (2) from 90 to 10% by weight of a polymer B which is a homopolymer of a conjugated diene or a copolymer of a mono-aromatic vinyl compound and a conjugated diene, said polymer B containing less than 25% by weight of mono-aromatic vinyl compound and having a vinyl content in the conjugated diene units of less than 25% and a glass transition temperature below minus 55° C., said percentages by weight of copolymer A and polymer B being calculated on the total of A and B, and copolymer A and polymer B, if present as a copolymer, having a differential content of the aromatic vinyl compound over the polymer chain which varies less than five percentage points; as determined by monomer conversion.
Claim 3
Dependent Claim 28 words
The elastomeric composition as claimed in claim 1 in which the differential content of the mono-aromatic vinyl compound over the polymer chain is less than two percentage points.
Claim 4
Dependent Claim 34 words
An elastomeric composition as claimed in claim 1 or 2 which contains in the range of from 20 to 50% by weight of copolymer A and 80 to 50% by weight of polymer B.
Claim 5
Dependent Claim 22 words
An elastomeric composition as claimed in claim 1 in which the mono-aromatic vinyl compound is styrene and the conjugated diene is 1,3-butadiene.
Claim 6
Dependent Claim 37 words
An elastomeric composition as claimed in claim 1 in which at least a portion of copolymer A and of polymer B, if present as a copolymer, is a coupled copolymer, coupled by means of a coupling agent.
Claim 7
Dependent Claim 39 words
An elastomeric composition as claimed in claim 1 in which the glass transition temperature of copolymer A is in the range of from minus 25° C. to plus 25° C. and that of polymer B below minus 65° C.
Claim 8
Dependent Claim 20 words
An unvulcanized elastomeric composition comprising a blend of an elastomeric composition as claimed in claim 1 with vulcanization compounding ingredients.
Claim 9
Dependent Claim 17 words
A tire whose tread has been formed by vulcanizing an elastomeric composition as claimed in claim 7.

References Cited (Backward Citations)

GB1283327A Cited
GB2068979A Cited
US4485205A Cited
US4383085A Cited
US4471093A Cited
US4510291A Cited
US4515922A Cited
US4567225A Cited
US4748168A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-07-29 1995-01-28 1995-07-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-07-29 1999-01-28 1999-07-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-07-29 2003-01-28 2003-07-30 $7700.00 Window Closed / Lapsed

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