Patent US4858821A successfully refreshed from Google Patents.
US5035969A
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Electrophotographic photoreceptor containing phthalocyanine
Assignee: Fujifilm Holdings Corp
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Filing: 1990-02-08
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Granted: 1991-07-30
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Expires: 2010-02-08
Abstract
Abstract A novel electrophotographic photoreceptor for copying machine or photoprinter is provided comprising on an electrically conductive support a photoconductive layer, characterized in that said photoconductive layer contains a phthalocyanine pigment and a compound represented by the general formula (I), (II), (III), (IV) or (VI): ##STR1## wherein Z represents a sulfur or oxygen atom; Ar represents a monovalent aromatic hydrocarbon group or monovalent heterocyclic group; R 3 represents a hydrogen atom, alkyl group, aryl group or aralkyl group; Ar and R 3 may together form a ring; and R 1 and R 2 may be the same or different and each represents an alkyl group, aryl group or aralkyl group, ##STR2## wherein Z represents a sulfur or oxygen atom; R 4 represents an alkyl group, alkoxy group, monovalent or bicyclic condensed aryl group, monocyclic or bicyclic condensed aryloxy group or monovalent group derived from heterocyclic group; the two R 4 's in the general formula (IV) being the same or different; R 5 and R 6 may be the same or different and each represents a hydrogen atom, alkyl group, monocyclic or bicyclic condensed aryl group or monovalent group derived from heterocyclic group; R 7 represents a methylene group, polymethylene group, branched alkanediyl group or arylene group; and R 4 and R 5 or R 5 and R 6 may be connected to each other, ##STR3## wherein Z represents a sulfur or oxygen atom; R 8 , R 9 , R 10 , R 11 , R 12 and R 13 may be the same or different and each represents a hydrogen atom, an alkyl group, aryl group or monovalent group derived from heterocyclic group, R 8 and R 9 or R 10 and R 11 being optionally connected to each other; R 8 , R 9 , R 10 and R 11 in the general formula (V) being optionally connected to each other to form a crosslinked ring; and R 14 represents a divalent arylene group, aralkylene group, polymethylene group or alkylene group.
Inventors
- 👤 Syunichi Kondo
- 👤 Hiroaki Yokoya
- 👤 Seiji Horie
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 23:28
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/02; G03G5/04; G03G5/06; G03G5/0622; G03G5/0624; G03G5/0627; G03G5/0629; G03G5/0601; G03G5/0618; G03G5/062; G03G5/0631; G03G5/0635; G03G5/0637; G03G5/0638; G03G5/0644; G03G5/0661
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
360 words
An electrophotographic photoreceptor for copying machine or photoprinter comprising an electrically conductive support having thereon a photoconductive layer, wherein said photoconductive layer contains a phthalocyanine pigment and a compound represented by the general formula (I), (II), (III), (IV) or (VI): ##STR20## wherein z represents a sulfur or oxygen atom; Ar represents a monovalent aromatic hydrocarbon group or monovalent heterocyclic group; R 3 represents a hydrogen atom, alkyl group, aryl group or aralkyl group; Ar and R 3 may together form a ring; and R 1 and R 2 may be the same or different and each represents an alkyl group, aryl group or aralkyl group; ##STR21## wherein Z represents a sulfur or oxygen atom; R 4 represents an alkyl group, akloxy group, monovalent or bicyclic condensed aryl group, monocyclic or bicyclic condensed aryloxy group or monovalent group derived from heterocyclic group, the two R's in the general formula (IV) being the same or different; R 5 and R 6 may be the same or different and each represents a hydrogen atom, alkyl group, monocyclic or bicyclic condensed aryl group or monovalent group derived from heterocyclic group; R 7 represents a methylene group, polymethylene group, branched alkanediyl group or arylene group; and R 4 and R 5 or R 5 and R 6 may be connected to each other: ##STR22## wherein Z represents a sulfur or oxygen atom; R 8 , R 9 , R 10 , R 11 , R 12 and R 13 may be the same or different and each represents a hydrogen atom, an alkyl group, aryl group or monovalent group derived from heterocyclic gruop, R 8 and R 9 or R 10 and R 11 being optionally connected to each other; R 8 , R 9 , R 10 and R 11 in the general formula (V) being optionally connected to each other to form a crosslinked ring; and R 14 represents a divalent arylene group, aralkylene group, polymethylene group or alkylene group; and wherein the content of the compound represented by general formula (I), (II), (III), (IV), (V) or (VI) is in the range of 0.01 to 1.0 times by weight of the phthalocyanine pigment.
Claim 2
Dependent Claim
360 words
An electrophotographic photoreceptor for copying machine or photoprinter comprising an electrically conductive support having thereon a photoconductive layer, wherein said photoconductive layer contains a phthalocyanine pigment and a compound represented by the general formula (I), (II), (III), (IV) or (VI): ##STR20## wherein z represents a sulfur or oxygen atom; Ar represents a monovalent aromatic hydrocarbon group or monovalent heterocyclic group; R 3 represents a hydrogen atom, alkyl group, aryl group or aralkyl group; Ar and R 3 may together form a ring; and R 1 and R 2 may be the same or different and each represents an alkyl group, aryl group or aralkyl group; ##STR21## wherein Z represents a sulfur or oxygen atom; R 4 represents an alkyl group, akloxy group, monovalent or bicyclic condensed aryl group, monocyclic or bicyclic condensed aryloxy group or monovalent group derived from heterocyclic group, the two R's in the general formula (IV) being the same or different; R 5 and R 6 may be the same or different and each represents a hydrogen atom, alkyl group, monocyclic or bicyclic condensed aryl group or monovalent group derived from heterocyclic group; R 7 represents a methylene group, polymethylene group, branched alkanediyl group or arylene group; and R 4 and R 5 or R 5 and R 6 may be connected to each other: ##STR22## wherein Z represents a sulfur or oxygen atom; R 8 , R 9 , R 10 , R 11 , R 12 and R 13 may be the same or different and each represents a hydrogen atom, an alkyl group, aryl group or monovalent group derived from heterocyclic gruop, R 8 and R 9 or R 10 and R 11 being optionally connected to each other; R 8 , R 9 , R 10 and R 11 in the general formula (V) being optionally connected to each other to form a crosslinked ring; and R 14 represents a divalent arylene group, aralkylene group, polymethylene group or alkylene group; and wherein the content of the compound represented by general formula (I), (II), (III), (IV), (V) or (VI) is in the range of 0.01 to 1.0 times by weight of the phthalocyanine pigment.
Claim 3
Dependent Claim
39 words
An electrophotographic receptor for copying machine or photoprinter according to claim 1, wherein said photoconductive layer is a single layer containing a phthalocyanine pigment and a compound represented by the general formula (I), (II), (III), (IV), (V) or (VI)
Claim 4
Dependent Claim
37 words
An electrophotographic photoreceptor for copying machine or photoprinter according to claim 1, generating layer containing a phthalocyanine pigment and a compound represented by the general formula (I), (II), (III), (IV), (V) or (VI) and a charge-transporting layer.
Claim 5
Dependent Claim
25 words
An electrophotographic photoreceptor for copying machine or photoprinter according to claim 1 wherein the light source of said copying machine or photoprinter is a laser.
Claim 6
Dependent Claim
401 words
An electrophotographic photoreceptor for copying machine or photoprinter comprising an electrically conductive support having thereon a photoconductive layer, wherein said photoconductive layer contains a phthalocyanine pigment and a compound represented by the general formula (I), (II), (III), (IV) or (VI): ##STR23## wherein Z represents a sulfur or oxygen atom; Ar represents a monovalent aromatic hydrocarbon group or monovalent heterocyclic group; R 3 represents a hydrogen atom, alkyl group, aryl group or aralkyl group; Ar and R 3 may together form a ring; and R 1 and R 2 may be the same or different and each represents an alkyl group, aryl group or aralkyl group; ##STR24## wherein Z represents a sulfur or oxygen atom; R 4 represents an alkyl group, akloxy group, monovalent or bicyclic condensed aryl group, monocyclic or bicyclic condensed aryloxy group or monovalent group derived from heterocyclic group, the two R's in the general formula (IV) being the same or different; R 5 and R 6 may be the same or different and each represents a hydrogen atom, alkyl group, monocyclic or bicyclic condensed aryl group or monovalent group derived from heterocyclic group; R 7 represents a methylene group, polymethylene group, branched alkanediyl group or arylene group; and R 4 and R 5 or R 5 and R 6 may be connected to each other: ##STR25## wherein Z represents a sulfur or oxygen atom; R 8 , R 9 , R 10 , R 11 , R 12 and R 13 may be the same or different and each represents a hydrogen atom, an alkyl group, aryl group or monovalent group derived from heterocyclic gruop, R 8 and R 9 or R 10 and R 11 being optionally connected to each other; R 8 , R 9 , R 10 and R 11 in the general formula (V) being optionally connected to each other to form a crosslinked ring; and R 14 represents a divalent arylene group, aralkylene group, polymethylene group or alkylene group; and wherein the photoreceptor is of the layer structure type comprising a single photoconductive layer, the content of the compound represented by general formula (I), (II), (III), (IV), (V) or (VI) is in the range of 0.01 to 1 times by weight that of the phthalocyanine pigment, and the proportino of the phthalocyanine pigment in the electrophotographic light-sensitive layer is in the range of 0.01 to 2.0 times by weight that of the binder.
Claim 7
Dependent Claim
401 words
An electrophotographic photoreceptor for copying machine or photoprinter comprising an electrically conductive support having thereon a photoconductive layer, wherein said photoconductive layer contains a phthalocyanine pigment and a compound represented by the general formula (I), (II), (III), (IV) or (VI): ##STR23## wherein Z represents a sulfur or oxygen atom; Ar represents a monovalent aromatic hydrocarbon group or monovalent heterocyclic group; R 3 represents a hydrogen atom, alkyl group, aryl group or aralkyl group; Ar and R 3 may together form a ring; and R 1 and R 2 may be the same or different and each represents an alkyl group, aryl group or aralkyl group; ##STR24## wherein Z represents a sulfur or oxygen atom; R 4 represents an alkyl group, akloxy group, monovalent or bicyclic condensed aryl group, monocyclic or bicyclic condensed aryloxy group or monovalent group derived from heterocyclic group, the two R's in the general formula (IV) being the same or different; R 5 and R 6 may be the same or different and each represents a hydrogen atom, alkyl group, monocyclic or bicyclic condensed aryl group or monovalent group derived from heterocyclic group; R 7 represents a methylene group, polymethylene group, branched alkanediyl group or arylene group; and R 4 and R 5 or R 5 and R 6 may be connected to each other: ##STR25## wherein Z represents a sulfur or oxygen atom; R 8 , R 9 , R 10 , R 11 , R 12 and R 13 may be the same or different and each represents a hydrogen atom, an alkyl group, aryl group or monovalent group derived from heterocyclic gruop, R 8 and R 9 or R 10 and R 11 being optionally connected to each other; R 8 , R 9 , R 10 and R 11 in the general formula (V) being optionally connected to each other to form a crosslinked ring; and R 14 represents a divalent arylene group, aralkylene group, polymethylene group or alkylene group; and wherein the photoreceptor is of the layer structure type comprising a single photoconductive layer, the content of the compound represented by general formula (I), (II), (III), (IV), (V) or (VI) is in the range of 0.01 to 1 times by weight that of the phthalocyanine pigment, and the proportino of the phthalocyanine pigment in the electrophotographic light-sensitive layer is in the range of 0.01 to 2.0 times by weight that of the binder.
Claim 8
Dependent Claim
396 words
An An electrophotographic photoreceptor for copying machine or photoprinter comprising an electrically conductive support having thereon a photoconductive layer, wherein said photoconductive layer contains a phthalocyanine pigment and a compound represented by the general formula (I), (II), (III), (IV) or (V): ##STR26## wherein Z represents a sulfur or oxygen atom; Ar represents a monovalent aromatic hydrocarbon group or monovalent heterocyclic group; R 3 represents a hydrogen atom, alkyl group, aryl group or aralkyl group; Ar and R 3 may together form a ring; and R 1 and R 2 may be the same or different and each represents an alkyl group, aryl group or aralkyl group; ##STR27## wherein Z represents a sulfur or oxygen atom; R 4 represents an alkyl group, akloxy group, monovalent or bicyclic condensed aryl group, monocyclic or bicyclic condensed aryloxy group or monovalent group derived from heterocyclic group, the two R's in the general formula (IV) being the same or different; R 5 and R 6 may be the same or different and each represents a hydrogen atom, alkyl group, monocyclic or bicyclic condensed aryl group or monovalent group derived from heterocyclic group; R 7 represents a methylene group, polymethylene group, branched alkanediyl group or arylene group; and R 4 and R 5 or R 5 and R 6 may be connected to each other: ##STR28## wherein Z represents a sulfur or oxygen atom; R 8 , R 9 , R 10 , R 11 , R 12 and R 13 may be the same or different and each represents a hydrogen atom, an alkyl group, aryl group or monovalent group derived from heterocyclic gruop, R 8 and R 9 or R 10 and R 11 being optionally connected to each other; R 8 , R 9 , R 10 and R 11 in the general formula (V) being optionally connected to each other to form a crosslinked ring; and R 14 represents a divalent arylene group, aralkylene group, polymethylene group or alkylene group; and wherein the photoreceptor is of the type comprising separate charge generating and charge transporting layers, the content of the compound represented by general formula (I), (II), (III), (IV), (V) or (VI) is in the range of 0.01 to 1.0 times by weight that of the phthalocyanine pigment, and the amount of phthalocyanine pigment is in the range of 0.01 to 50.0 times that of the binder resin.
Claim 9
Dependent Claim
396 words
An An electrophotographic photoreceptor for copying machine or photoprinter comprising an electrically conductive support having thereon a photoconductive layer, wherein said photoconductive layer contains a phthalocyanine pigment and a compound represented by the general formula (I), (II), (III), (IV) or (V): ##STR26## wherein Z represents a sulfur or oxygen atom; Ar represents a monovalent aromatic hydrocarbon group or monovalent heterocyclic group; R 3 represents a hydrogen atom, alkyl group, aryl group or aralkyl group; Ar and R 3 may together form a ring; and R 1 and R 2 may be the same or different and each represents an alkyl group, aryl group or aralkyl group; ##STR27## wherein Z represents a sulfur or oxygen atom; R 4 represents an alkyl group, akloxy group, monovalent or bicyclic condensed aryl group, monocyclic or bicyclic condensed aryloxy group or monovalent group derived from heterocyclic group, the two R's in the general formula (IV) being the same or different; R 5 and R 6 may be the same or different and each represents a hydrogen atom, alkyl group, monocyclic or bicyclic condensed aryl group or monovalent group derived from heterocyclic group; R 7 represents a methylene group, polymethylene group, branched alkanediyl group or arylene group; and R 4 and R 5 or R 5 and R 6 may be connected to each other: ##STR28## wherein Z represents a sulfur or oxygen atom; R 8 , R 9 , R 10 , R 11 , R 12 and R 13 may be the same or different and each represents a hydrogen atom, an alkyl group, aryl group or monovalent group derived from heterocyclic gruop, R 8 and R 9 or R 10 and R 11 being optionally connected to each other; R 8 , R 9 , R 10 and R 11 in the general formula (V) being optionally connected to each other to form a crosslinked ring; and R 14 represents a divalent arylene group, aralkylene group, polymethylene group or alkylene group; and wherein the photoreceptor is of the type comprising separate charge generating and charge transporting layers, the content of the compound represented by general formula (I), (II), (III), (IV), (V) or (VI) is in the range of 0.01 to 1.0 times by weight that of the phthalocyanine pigment, and the amount of phthalocyanine pigment is in the range of 0.01 to 50.0 times that of the binder resin.
References Cited (Backward Citations)
US4419429A
Cited
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