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US5035849A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for producing molded article using a releasing agent

Assignee: JNC Corp
•
Filing: 1990-01-31
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Granted: 1991-07-30
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Expires: 2010-01-31
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Abstract

Abstract A process for producing a molded article is provided including a) The surface of a mold is cooled with a releasing agent for powder molding which has, as an essential component, a copolymer AB derived from at least one monomer A represented by the following general formula (I) ##STR1## wherein X is a hydrogen atom or a methyl group, k is an integer of 0-5, l is an integer of 1-3, m is an integer of 1-3, n is an integer of 0-550 and Y is a methyl group or a fluorine atom-containing substituent having 1-20 carbon atoms, and at least one vinyl-polymerizable monomer B containing at least one alkyl acrylate or alkylmethacrylate wherein the alkyl group has 1 to 8 carbon atoms. b) The coated mold is heated. c) A powder of a non-rigid vinyl chloride resin containing a plasticizer is allowed to adhere to the heated mold to melt the powder. d) The mold, releasing agent and powder are cooled to form a molded article. e) The molded article is peeled from the mold. Monomer A and monomer B are combined in proportions within the copolymer AB such that the film of releasing agent has good compatibility with the vinyl chloride resin and sufficient releasability from the mold such that the film migrates to the surface of the molded article at the time of peeling.

Inventors

  • 👤 Katsuoki Uemura
  • 👤 Masaru Ando
  • 👤 Jun-Ichi Yamauchi
  • 👤 Yoshinori Akutsu

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 22:59
CPC Classifications
B; B29; B29C; B29C33/00; B29C33/56; B29C33/60; B29C33/62; B29C33/64; B29C41/00; B29C41/02; B29C41/18

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 219 words
A process for producing a molded article comprising: a) coating the surface of a mold with a releasing agent for powder molding which comprises, as an essential component, a copolymer AB derived from at least one monomer A represented by the following general formula (I) ##STR3## wherein X is a hydrogen atom or a methyl group, k is an integer of 0-5, l is an integer of 1-3, m is a integer of 1-3, n is an integer of 0-550 and Y is a methyl group or a fluorine atom-containing substituent having 1-20 carbon atoms, and at least one vinyl-polymerizable monomer B containing at least one alkyl acrylate or methacrylate wherein the alkyl group has 1-8 carbon atoms; b) heating the coated mold; c) allowing a powder of a non-rigid vinyl chloride resin containing a plasticizer to adhere to the heated mold to melt the powder; d) cooling the mold, releasing agent and powder to form a molded article; and e) peeling the molded article from the mold, monomer A and monomer B being combined in proportions within the copolymer AB such that the film of releasing agent has good compatibility with the vinyl chloride resin and sufficient releasibility from the mold such that the film migrates to the surface of the molded article at the time of peeling.
Claim 2
Dependent Claim 219 words
A process for producing a molded article comprising: a) coating the surface of a mold with a releasing agent for powder molding which comprises, as an essential component, a copolymer AB derived from at least one monomer A represented by the following general formula (I) ##STR3## wherein X is a hydrogen atom or a methyl group, k is an integer of 0-5, l is an integer of 1-3, m is a integer of 1-3, n is an integer of 0-550 and Y is a methyl group or a fluorine atom-containing substituent having 1-20 carbon atoms, and at least one vinyl-polymerizable monomer B containing at least one alkyl acrylate or methacrylate wherein the alkyl group has 1-8 carbon atoms; b) heating the coated mold; c) allowing a powder of a non-rigid vinyl chloride resin containing a plasticizer to adhere to the heated mold to melt the powder; d) cooling the mold, releasing agent and powder to form a molded article; and e) peeling the molded article from the mold, monomer A and monomer B being combined in proportions within the copolymer AB such that the film of releasing agent has good compatibility with the vinyl chloride resin and sufficient releasibility from the mold such that the film migrates to the surface of the molded article at the time of peeling.
Claim 3
Dependent Claim 32 words
A process for producing a molded article according to claim 1 wherein a repeating unit derived from monomer A is contained in the copolymer AB in an amount of 2-50% by weight.
Claim 4
Dependent Claim 34 words
A process for producing a molded article according to claim 1 wherein a repeating unit derived from monomer A is contained in the copolymer AB in an amount of 5 to 35% by weight.
Claim 5
Dependent Claim 62 words
A process for producing a molded article according to claim 1 wherein the vinyl monomer B contains at least one alkyl acrylate or alkylmethacrylate whose alkyl group has 1-8 carbon atoms and a repeating unit derived from alkyl acrylate or alkyl methacrylate in the copolymer AB is contained in an amount of 25-98% by weight based on the weight of copolymer AB.
Claim 6
Dependent Claim 32 words
A process for producing a molded article according to claim 4 wherein the amount of the repeating unit derived from alkyl acrylate or methacrylate in the copolymer AB is 40-95% by weight.
Claim 7
Dependent Claim 63 words
A process for producing a molded article according to claim 2 wherein the vinyl monomer B contains at least one alkyl acrylate or alkyl methacrylate whose alkyl group has 1-8 carbon atoms and a repeating unit derived from alkyl acrylate or alkyl methacrylate in the copolymer AB is contained in an amount of 25-98% by weight based on the weight of copolymer AB.
Claim 8
Dependent Claim 31 words
A process for producing a molded article according to claim 6 wherein the amount of the unit derived from alkyl acrylate or methacrylate in the copolymer AB is 40-95% by weight.
Claim 9
Dependent Claim 17 words
A process for producing a molded article according to claim 1 wherein n is 1 or more.
Claim 10
Dependent Claim 17 words
A process for producing a molded article according to claim 1 wherein X comprises a methyl group.
Claim 11
Dependent Claim 17 words
A process for producing a molded article according to claim 1 wherein Y comprises a methyl group.
Claim 12
Dependent Claim 17 words
A process for producing a molded article according to claim 9 wherein Y comprises a methyl group.
Claim 13
Dependent Claim 15 words
A process for producing a molded article according to claim 1 wherein k is 0.
Claim 14
Dependent Claim 15 words
A process for producing a molded article according to claim 1 wherein l is 3.
Claim 15
Dependent Claim 15 words
A process for producing a molded article according to claim 1 wherein m is 1.
Claim 16
Dependent Claim 29 words
A process for producing a molded article according to claim 1 wherein both X and Y comprise methyl groups, k is 0, l is 3, and m is 1.
Claim 17
Dependent Claim 16 words
A process for producing a molded article according to claim 15 wherein n is about 11.
Claim 18
Dependent Claim 16 words
A process for producing a molded article according to claim 15 wherein n is about 65.
Claim 19
Dependent Claim 16 words
A process for producing a molded article according to claim 15 wherein n is about 132.
Claim 20
Dependent Claim 16 words
A process for producing a molded article according to claim 15 wherein n is about 268.
Claim 21
Dependent Claim 17 words
A process for producing a molded article according to claim 1 wherein Y comprises a heptafluorophenyl group.

References Cited (Backward Citations)

CA481025A Cited
GB828977A Cited
US4082862A Cited
US4434126A Cited
US4664864A Cited
JPS6032611A Cited
EP0177647A2 Cited
US4673621A Cited
EP0218043A1 Cited
WO1988000876A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-07-29 1995-01-28 1995-07-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-07-29 1999-01-28 1999-07-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-07-29 2003-01-28 2003-07-30 $7700.00 Window Closed / Lapsed

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