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US5034058A Expired / Lapsed US ⏱️ 0.0 years remaining

Aqueous ink composition

Assignee: Orient Chemical Industries Ltd
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Filing: 1989-06-15
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Granted: 1991-07-23
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Expires: 2009-06-15
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Abstract

Abstract The present invention provides an aqueous ink composition which has excellent physical properties in all aspects. More specifically, the present invention relates to an aqueous ink composition, comprising (a) an aqueous medium, and (b) and azo dye which has a hydroxyl group and/or an amino group, and also has 1 to 4 phosphorus-containing groups represented by the formula; <IMAGE> [I] wherein x represents an oxygen atom or an alkylene group having 1 to 4 carbon atoms, M represents a hydrogen atom, an alkali metal atom or -NH(R)3 (wherein R, which is the same or different, represents a hydrogen atom, an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group having 1 to 4 carbon atoms), m represents 0 or 1, and n represents 0 or 1.

Inventors

  • 👤 Kazutoshi Akiyama
  • 👤 Takashi Ono
  • 👤 Tatsuya Yagyu

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 09:53
CPC Classifications
C; C09; C09D; C09D11/00; C09D11/16; C09D11/17; C09D11/30; C09D11/32; C09D11/328

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 151 words
An aqueous ink composition, which comprises (a) an aqueous medium, and (b) an effective amount of a monoazo dye, a diazo dye or a triazo dye for improving stability and plugging properties, which have either a hydroxyl group or an amino group, or both a hydroxyl group and an amino group, and which also have 1 to 4 phosphorus-containing groups represented by formula (I): ##STR7## wherein X represents an oxygen atom or an alkylene group having 1 to 4 carbon atoms, M represents a hydrogen atom, an alkali metal atom selected from the group consisting of a lithium atom, a sodium atom and a potassium atom, or --NH(R) 3 , wherein R, which is the same or different, represents a hydrogen atom, an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group having 1 to 4 carbon atoms, represents 0 to 1, and n represents 0 or 1.
Claim 2
Dependent Claim 151 words
An aqueous ink composition, which comprises (a) an aqueous medium, and (b) an effective amount of a monoazo dye, a diazo dye or a triazo dye for improving stability and plugging properties, which have either a hydroxyl group or an amino group, or both a hydroxyl group and an amino group, and which also have 1 to 4 phosphorus-containing groups represented by formula (I): ##STR7## wherein X represents an oxygen atom or an alkylene group having 1 to 4 carbon atoms, M represents a hydrogen atom, an alkali metal atom selected from the group consisting of a lithium atom, a sodium atom and a potassium atom, or --NH(R) 3 , wherein R, which is the same or different, represents a hydrogen atom, an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group having 1 to 4 carbon atoms, represents 0 to 1, and n represents 0 or 1.
Claim 3
Dependent Claim 16 words
The ink composition according to claim 1, which comprises 1 to 4 hydroxyl or amino groups.
Claim 4
Dependent Claim 27 words
The ink composition according to claim 1, wherein the azo dye further comprises --SO 3 M, --COOM, or a combination thereof, wherein M is as defined above.
Claim 5
Dependent Claim 21 words
The ink composition according to claim 1, wherein the azo dye is an acid azo dye or a direct azo dye.
Claim 6
Dependent Claim 79 words
An aqueous ink composition, which comprises (a) an aqueous medium, and (b) an effective amount of a monoazo dye, a diazo dye or a triazo dye for improving stability and plugging properties, which have either a hydroxyl group or an amino group, or both a hydroxyl group and an amino group, and which also have 1 to 4 phosphorus-containing groups represented by formula (I): ##STR8## wherein groups represented by formula (I) are selected from the groups consisting of: ##STR9##
Claim 7
Dependent Claim 79 words
An aqueous ink composition, which comprises (a) an aqueous medium, and (b) an effective amount of a monoazo dye, a diazo dye or a triazo dye for improving stability and plugging properties, which have either a hydroxyl group or an amino group, or both a hydroxyl group and an amino group, and which also have 1 to 4 phosphorus-containing groups represented by formula (I): ##STR8## wherein groups represented by formula (I) are selected from the groups consisting of: ##STR9##
Claim 8
Dependent Claim 90 words
An aqueous ink composition, which comprises (a) an aqueous medium, and (b) an effective amount for improving stability and plugging of an azo dye selected from the group consisting of formulas: ##STR10## wherein M represents a hydrogen atom, an alkali metal atom selected or --NH(R) 3 , wherein R, which is the same or different, represents a hydrogen atom, an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group having 1 to 4 carbon atoms, where m represents 0 to 1, and n represents 0 or 1.
Claim 9
Dependent Claim 90 words
An aqueous ink composition, which comprises (a) an aqueous medium, and (b) an effective amount for improving stability and plugging of an azo dye selected from the group consisting of formulas: ##STR10## wherein M represents a hydrogen atom, an alkali metal atom selected or --NH(R) 3 , wherein R, which is the same or different, represents a hydrogen atom, an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group having 1 to 4 carbon atoms, where m represents 0 to 1, and n represents 0 or 1.
Claim 10
Dependent Claim 22 words
The ink composition according to claim 6, wherein the aqueous medium is water or a mixture of water and an organic solvent.
Claim 11
Dependent Claim 15 words
The ink composition according to claim 7, wherein the organic solvent is a polar solvent.
Claim 12
Dependent Claim 35 words
The ink composition according to claim 7, wherein the organic solvent is selected from the group consisting of a monoalcohol, a polyhydric alcohol, a hydroxyether, a hydroxyether ester ether, formamide, N, N-dimethylformamide, dimethylsulfoxide, and N-methyl-2-pyrrolidone.
Claim 13
Dependent Claim 30 words
The ink composition according to claim 6, wherein said azo dye is present in the ink composition in an amount of 3% to 15% by weight for a ball-point pen.
Claim 14
Dependent Claim 22 words
The ink composition according to claim 10, wherein said azo dye is present in an amount of 5% to 10% by weight.
Claim 15
Dependent Claim 25 words
The ink composition according to claim 6, wherein the azo dye is present in an amount of 1% to 10% by weight for ink-jet recording.
Claim 16
Dependent Claim 22 words
The ink composition according to claim 12, wherein said azo dye is present in an amount of 1% to 3% by weight.
Claim 17
Dependent Claim 32 words
An aqueous ink composition, which comprises: (a) an aqueous medium, and (b) an effective amount for improving stability and plugging of an azo dye selected from the group consisting of formulas: ##STR11##
Claim 18
Dependent Claim 32 words
An aqueous ink composition, which comprises: (a) an aqueous medium, and (b) an effective amount for improving stability and plugging of an azo dye selected from the group consisting of formulas: ##STR11##
Claim 19
Dependent Claim 14 words
An ink for a ball-point pen composed of the composition according to claim 6.
Claim 20
Dependent Claim 14 words
An ink for a ink-jet recording composed of the composition according to claim 6.

References Cited (Backward Citations)

US2959582A Cited
US3531459A Cited
US3945836A Cited
US3945837A Cited
US3947435A Cited
US4287121A Cited
US4091021A Cited
US4286989A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-07-22 1995-01-21 1995-07-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-07-22 1999-01-21 1999-07-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-07-22 2003-01-21 2003-07-23 $7700.00 Window Closed / Lapsed

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