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US5030594A Expired / Lapsed US ⏱️ 0.0 years remaining

Highly transparent, edge colored glass

Assignee: Vitro SAB de CV
•
Filing: 1990-06-29
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Granted: 1991-07-09
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Expires: 2010-06-29
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Abstract

Abstract A clear glass, with the substantial absence of color in transmittance, and with an attractive, bright, pure azure edge coloration is achieved in a glass having greater than 87 percent, preferably greater than 90 percent, luminous transmittance by using very small amounts of iron oxide as the sole essential colorant, with the ratio of iron in the ferrous state to total iron being at least 0.4.

Inventors

  • 👤 Robert B. Heithoff

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 03:22
CPC Classifications
C; C03; C03B; C03B18/00; C03B18/02; C03B18/16; C03B18/12; C03B5/00; C03B5/16; C03B5/18; C03B5/187; C03C; C03C3/00; C03C3/04; C03C3/076; C03C3/078; C03C3/083; C03C3/085; C03C3/087; C03C4/00; C03C4/02; Y; Y02; Y02P; Y02P40/00; Y02P40/50; Y02P40/57

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 126 words
Clear glass with pure edge coloration comprising a soda-lime-silica base glass portion comprising: ______________________________________ Weight % ______________________________________ SiO.sub.2 66-75 Na.sub.2 O 12-20 CaO 7-12 MgO 0-5 Al.sub.2 O.sub.3 0-4 K.sub.2 O 0-3 ______________________________________ and a colorant portion consisting essentially of iron oxide in an amount less than 0.02 percent by weight of the glass expressed as Fe 2 O 3 , the ratio of iron present in the glass in the ferrous state expressed as FeO to the total amount of iron in the glass expressed as Fe 2 O 3 being at least 0.4, whereby the glass exhibits luminous transmittance (illuminant C) of at least 87 percent at a thickness of 0.223 inches (5.66 millimeters), the colorant portion including all essential colorants in the glass.
Claim 2
Dependent Claim 126 words
Clear glass with pure edge coloration comprising a soda-lime-silica base glass portion comprising: ______________________________________ Weight % ______________________________________ SiO.sub.2 66-75 Na.sub.2 O 12-20 CaO 7-12 MgO 0-5 Al.sub.2 O.sub.3 0-4 K.sub.2 O 0-3 ______________________________________ and a colorant portion consisting essentially of iron oxide in an amount less than 0.02 percent by weight of the glass expressed as Fe 2 O 3 , the ratio of iron present in the glass in the ferrous state expressed as FeO to the total amount of iron in the glass expressed as Fe 2 O 3 being at least 0.4, whereby the glass exhibits luminous transmittance (illuminant C) of at least 87 percent at a thickness of 0.223 inches (5.66 millimeters), the colorant portion including all essential colorants in the glass.
Claim 3
Dependent Claim 32 words
The glass of claim 1 wherein the colorant consists essentially of iron oxide in an amount less than 0.015 percent by weight of the glass expressed as Fe 2 O 3 .
Claim 4
Dependent Claim 17 words
The glass of claim 1 wherein the glass exhibits a luminous transmittance of at least 90 percent.
Claim 5
Dependent Claim 17 words
The glass of claim 1 wherein the glass exhibits a luminous transmittance of at least 90.5 percent.
Claim 6
Dependent Claim 19 words
The glass of claim 1 wherein the glass exhibits a dominant wavelength in transmission of 487 to 495 nanometers.
Claim 7
Dependent Claim 19 words
The glass of claim 1 wherein the glass exhibits a dominant wavelength in transmission of 489 to 493 nanometers.
Claim 8
Dependent Claim 16 words
The glass of claim 1 wherein the excitation purity in transmission is less than 1.0 percent.
Claim 9
Dependent Claim 14 words
The glass of claim 1 wherein the excitation purity is less than 0.4 percent.
Claim 10
Dependent Claim 18 words
The glass of claim 1 wherein the glass includes less than 0.05 percent by weight SO 3 .
Claim 11
Independent Claim 167 words
A method of making clear glass having pure edge coloration comprising: feeding batch materials to a melting stage of a glassmaking operation, the batch materials being selected to provide in the final glass product having the following base glass composition: ______________________________________ Weight % ______________________________________ SiO.sub.2 66-75 Na.sub.2 O 12-20 CaO 7-12 MgO 0-5 Al.sub.2 O.sub.3 0-4 K.sub.2 O 0-3 ______________________________________ and a total iron oxide content of no more than 0.02 percent by weight expressed as Fe 2 O 3 ; providing to the glassmaking operation no significant colorant other than iron; controlling redox conditions in the glassmaking operation to maintain the ratio of iron present in the glass in the ferrous state expressed as FeO to the total amount of iron in the glass expressed as Fe 2 O 3 equal to or greater than 0.4; and forming the glass into a clear glass product, whereby the glass has luminous transmittance (illuminant C) of at least 87 percent at a thickness of 0.223 inches (5.66 millimeters).
Claim 12
Independent Claim 167 words
A method of making clear glass having pure edge coloration comprising: feeding batch materials to a melting stage of a glassmaking operation, the batch materials being selected to provide in the final glass product having the following base glass composition: ______________________________________ Weight % ______________________________________ SiO.sub.2 66-75 Na.sub.2 O 12-20 CaO 7-12 MgO 0-5 Al.sub.2 O.sub.3 0-4 K.sub.2 O 0-3 ______________________________________ and a total iron oxide content of no more than 0.02 percent by weight expressed as Fe 2 O 3 ; providing to the glassmaking operation no significant colorant other than iron; controlling redox conditions in the glassmaking operation to maintain the ratio of iron present in the glass in the ferrous state expressed as FeO to the total amount of iron in the glass expressed as Fe 2 O 3 equal to or greater than 0.4; and forming the glass into a clear glass product, whereby the glass has luminous transmittance (illuminant C) of at least 87 percent at a thickness of 0.223 inches (5.66 millimeters).
Claim 13
Dependent Claim 15 words
The method of claim 10 wherein the melting operation includes separate liquefying and refining stages.
Claim 14
Dependent Claim 16 words
The method of claim 10 wherein the batch materials are essentially free of limestone and dolomite.
Claim 15
Dependent Claim 24 words
The method of claim 10 wherein the step of forming the glass into a glass product comprises forming the glass into a flat sheet.
Claim 16
Dependent Claim 22 words
The method of claim 13 wherein the forming of the glass into a flat sheet includes floating the glass on molten metal.
Claim 17
Dependent Claim 19 words
The method of claim 14 wherein controlling the redox conditions includes stirring the glass while supported on molten metal.
Claim 18
Dependent Claim 21 words
The method of claim 10 wherein controlling the redox conditions includes operating combustion means in the melting stage under reducing conditions.

References Cited (Backward Citations)

CA618642A Cited
DE1141417B Cited
US3330638A Cited
US3723142A Cited
US4104076A Cited
US4339541A Cited
US4866010A Cited
US4792536A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-07-08 1995-01-07 1995-07-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-07-08 1999-01-07 1999-07-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-07-08 2003-01-07 2003-07-09 $7700.00 Window Closed / Lapsed

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