← Back to Patent Explorer
US5021537A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyacetoacetate-containing epoxy resin compositions

Assignee: Shell USA Inc
•
Filing: 1990-04-27
•
Granted: 1991-06-04
•
Expires: 2010-04-27
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A coating composition is provided comprising an epoxy resin, a polyacetoacetate, a curing agent for the epoxy resin, and an optional organic solvent. The presence of the polyacetoacetate permits the preparation of a fast-drying high-solids coating formulation.

Inventors

  • 👤 Charles J. Stark
  • 👤 Rita D. Pietruszka

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 22:46
CPC Classifications
C; C08; C08G; C08G59/00; C08G59/18; C08G59/40; C08G59/4007; C09; C09D; C09D163/00

Claims Analysis

Total Claims: 24
Claim 1
Independent Claim 44 words
A composition comprising: (a) a polyglycidyl ether having an average of at least about 1.5 epoxide groups per molecule and (b) a polyacetoacetate having two to four acetoacetate groups per molecule and a molecular weight within the range of about 200 to about 800.
Claim 2
Dependent Claim 44 words
A composition comprising: (a) a polyglycidyl ether having an average of at least about 1.5 epoxide groups per molecule and (b) a polyacetoacetate having two to four acetoacetate groups per molecule and a molecular weight within the range of about 200 to about 800.
Claim 3
Dependent Claim 31 words
The composition of claim 1 in which the polyacetoacetate is present in the composition in an amount of at least 1 weight percent, based on the weight of the polyglycidyl ether.
Claim 4
Dependent Claim 12 words
The composition of claim 2 in which the polyacetoacetate is a trisacetoacetate.
Claim 5
Dependent Claim 12 words
The composition of claim 2 in which the polyacetoacetate is a bisacetoacetate.
Claim 6
Dependent Claim 36 words
The composition of claim 3 in which the trisacetoacetate is present in the composition in an amount within the range of about 2 to about 75 weight percent, based on the weight of the polyglycidyl ether.
Claim 7
Dependent Claim 19 words
The composition of claim 5 in which the trisacetoacetate is selected from trisacetoacetates of trimethylolpropane, trimethylolethane, glycerol and bis(trimethylolpropane).
Claim 8
Dependent Claim 24 words
The composition of claim 2 in which the polyglycidyl ether is a diglycidyl ether of bisphenol-A and the polyacetoacetate is the trisacetoacetate of trimethylolpropane.
Claim 9
Dependent Claim 33 words
The composition of claim 7 in which the trisacetoacetate is present in an amount within the range of about 2 to about 75 weight percent, based on the weight of the diglycidyl ether.
Claim 10
Dependent Claim 33 words
The composition of claim 8 in which the trisacetoacetate is present in an amount within the range of about 4 to about 40 weight percent, based on the weight of the diglycidyl ether.
Claim 11
Dependent Claim 53 words
A composition comprising (a) a polyglycidyl ether having an average of at least about 1.5 epoxide groups per molecule, (b) a polyacetoacetate having two to four acetoacetate groups per molecule and a molecular weight within the range of about 200 to about 800, and (c) an effective amount of an amine curing agent.
Claim 12
Dependent Claim 53 words
A composition comprising (a) a polyglycidyl ether having an average of at least about 1.5 epoxide groups per molecule, (b) a polyacetoacetate having two to four acetoacetate groups per molecule and a molecular weight within the range of about 200 to about 800, and (c) an effective amount of an amine curing agent.
Claim 13
Dependent Claim 36 words
The composition of claim 10 in which the polyacetoacetate is present in the composition in an amount within the range of about 2 to about 75 weight percent, based on the weight of the polyglycidyl ether.
Claim 14
Dependent Claim 12 words
The composition of claim 11 in which the polyacetoacetate is a trisacetoacetate.
Claim 15
Dependent Claim 12 words
The composition of claim 11 in which the polyacetoacetate is a bisacetoacetate.
Claim 16
Dependent Claim 36 words
The composition of claim 12 in which the trisacetoacetate is present in the composition in an amount within the range of about 4 to about 40 weight percent, based on the weight of the polyglycidyl ether.
Claim 17
Dependent Claim 30 words
The composition of claim 10 in which the amine curing agent is selected from the group consisting of polyamine-epoxy adducts, polyamines, cycloaliphatic amines, aromatic amines, polyamides, amidoamines and Mannich bases.
Claim 18
Dependent Claim 26 words
The composition of claim 10 which further comprises (d) up to about 50 weight percent, based on the weight of the composition, of an organic solvent.
Claim 19
Dependent Claim 13 words
The composition of claim 16 in which the organic solvent comprises a ketone.
Claim 20
Dependent Claim 33 words
The composition of claim 16 in which the polyacetoacetate is present in an amount within the range of about 4 to about 40 weight percent, based on the weight of the polyglycidyl ether.
Claim 21
Dependent Claim 22 words
The composition of claim 18 in which the polyacetoacetate is a trisacetoacetate and the polyglycidyl ether is a diglycidyl ether of bisphenol-A.
Claim 22
Dependent Claim 19 words
The composition of claim 19 in which the trisacetoacetate is selected from trisacetoacetates of trimethylolpropane, trimethylolethane, glycerol and bis(trimethylolpropane).
Claim 23
Dependent Claim 14 words
The composition of claim 19 in which the polyacetoacetate is a trisacetoacetate of trimethylolpropane.
Claim 24
Dependent Claim 15 words
The composition of claim 21 in which the amine curing agent is a polyamide resin.

References Cited (Backward Citations)

US3053804A Cited
US4016141A Cited
US4456514A Cited
US4598108A Cited
US4791152A Cited
US4772680A Cited
US4737530A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-06-03 1994-12-03 1995-06-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-06-03 1998-12-03 1999-06-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-06-03 2002-12-03 2003-06-04 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag