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US5021533A Expired / Lapsed US ⏱️ 0.0 years remaining

Crosslinkable poly(thio)ureasilazane composition containing a free radical generator

Assignee: Clariant Finance BVI Ltd
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Filing: 1990-05-23
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Granted: 1991-06-04
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Expires: 2010-05-23
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Abstract

Abstract A composition that comprises a poly(thio)ureasilazane having at least one alkenyl or alkynyl group and a free radical generator can be crosslinked by an energy input provided in the form of heat, ultraviolet radiation, or an electron beam. The crosslinked poly(thio)ureasilazane compositions can be pyrolyzed to form silicon nitride-containing ceramics.

Inventors

  • 👤 Joanne M. Schwark

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 20:02
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/04; C04; C04B; C04B35/00; C04B35/515; C04B35/58; C04B35/584; C04B35/589; C08G18/06; C08G18/28; C08G18/30; C08G18/38; C08G18/3893; C08G77/00; C08G77/60; C08G77/62

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 43 words
A poly(thio)ureasilazane composition that is capable of being crosslinked by an energy input comprising (a) a poly(thio)ureasilazane containing at least one 2-6 carbon alkenyl or alkynyl group, and (b) at least one free radical generator in an amount effective to crosslink the poly(thio)ureasilazane.
Claim 2
Dependent Claim 43 words
A poly(thio)ureasilazane composition that is capable of being crosslinked by an energy input comprising (a) a poly(thio)ureasilazane containing at least one 2-6 carbon alkenyl or alkynyl group, and (b) at least one free radical generator in an amount effective to crosslink the poly(thio)ureasilazane.
Claim 3
Dependent Claim 14 words
The composition according to claim 1, wherein the alkenyl group is a vinyl group.
Claim 4
Dependent Claim 15 words
The composition according to claim 1, wherein the free radical generator is an azo compound.
Claim 5
Dependent Claim 12 words
The composition according to claim 3, wherein the azo compound is 2,2'-azobis(2-methylpropionitrile).
Claim 6
Dependent Claim 14 words
The composition according to claim 1, wherein the free radical generator is a peroxide.
Claim 7
Dependent Claim 12 words
The composition according to claim 5, wherein the peroxide is dicumyl peroxide.
Claim 8
Dependent Claim 10 words
The composition according to claim 1 further comprising a filler.
Claim 9
Dependent Claim 24 words
The composition of claim 1, wherein the free radical generator is present in an amount of 0.01 to 5.0 wt. % of the poly(thio)ureasilazane.
Claim 10
Dependent Claim 51 words
A process for crosslinking a poly(thio)-ureasilazane composition comprising a poly(thio)ureasilazane containing at least one 2-6 carbon alkenyl or alkynyl group and a free radical generator, said process comprising the step of exposing the poly(thio)ureasilazane composition to an energy input in an amount effective to generate free radicals and crosslink the poly(thio)ureasilazane.
Claim 11
Dependent Claim 51 words
A process for crosslinking a poly(thio)-ureasilazane composition comprising a poly(thio)ureasilazane containing at least one 2-6 carbon alkenyl or alkynyl group and a free radical generator, said process comprising the step of exposing the poly(thio)ureasilazane composition to an energy input in an amount effective to generate free radicals and crosslink the poly(thio)ureasilazane.
Claim 12
Dependent Claim 20 words
The process according to claim 9, wherein the poly(thio)ureasilazane composition is heated to a temperature of 30° to 300° c.
Claim 13
Dependent Claim 16 words
The process according to claim 10, wherein the temperature range is from 100° to 200° C.

References Cited (Backward Citations)

US4689252A Cited
US4722988A Cited
US4929704A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-06-03 1994-12-03 1995-06-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-06-03 1998-12-03 1999-06-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-06-03 2002-12-03 2003-06-04 $7700.00 Window Closed / Lapsed

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