US5019642A
Expired / Lapsed
US
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Novel diamine compounds, production of the same and polyamideimide resins produced therefrom
Assignee: Tomoegawa Co Ltd
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Filing: 1990-03-12
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Granted: 1991-05-28
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Expires: 2010-03-12
Abstract
Abstract A diamine compound represented by general formula (I): ##STR1## wherein R is as defined in the specification a group of formula (II) ##STR2## where R 1 and R 2 as defined in the specification or a group of formula (III) ##STR3## where R 1 and R 2 have the same meanings as defined above, and Z is as defined in the specification, or --SO 2 --. The diamine compound is produced by reducing a dinitro compound of general formula (IV) ##STR4## wherein R has the same meaning as defined above. Imidation of the diamine compound with a tetracarboxylic acid dianhydride produces a polyamideimide resin having a repeating unit represented by general formula (V): ##STR5## wherein Ar and Ar 1 , which are as defined in the specification R 3 is a group of general formula (VI) below: ##STR6## where R has the same meaning as defined above; R 4 is as defined in the specification and m and n are each zero or a positive integer which satisfy m≧2n.
Inventors
- 👤 Takeshi Hashimoto
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 03:04
CPC Classifications
C; C07; C07C; C07C235/00; C07C235/42; C07C235/44; C07C235/56; C07C235/50; C07C317/00; C07C317/26; C07C317/32; C07C317/34; C07C317/36; C07C323/00; C07C323/23; C07C323/31; C07C323/33; C07C323/35; C07C323/37; C08; C08G; C08G73/00; C08G73/06; C08G73/10; C08G73/14
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
107 words
A diamine compound represented by general formula (I) below: ##STR52## wherein R is a C 1 -C 12 alkylene group which is unsubstituted or substituted, a group of formula (II) ##STR53## where R 1 and R 2 , which are the same or different, each represents a hydrogen atom, a lower alkyl group, a halogen atom, a nitrile group, a nitro group, an alkoxy group or a hydroxyl group, or a group of formula (III) ##STR54## where R 1 and R 2 have the same meanings as defined above; and Z is a simple chemical bond, --O--, >C═O, --CH 2 --, --S--, --SO--, or --SO 2 --.
Claim 2
Dependent Claim
107 words
A diamine compound represented by general formula (I) below: ##STR52## wherein R is a C 1 -C 12 alkylene group which is unsubstituted or substituted, a group of formula (II) ##STR53## where R 1 and R 2 , which are the same or different, each represents a hydrogen atom, a lower alkyl group, a halogen atom, a nitrile group, a nitro group, an alkoxy group or a hydroxyl group, or a group of formula (III) ##STR54## where R 1 and R 2 have the same meanings as defined above; and Z is a simple chemical bond, --O--, >C═O, --CH 2 --, --S--, --SO--, or --SO 2 --.
Claim 3
Independent Claim
131 words
A method of producing a diamine compound represented by general formula (I) below: ##STR55## wherein R is a C 1 -C 12 alkylene group which is unsubstituted or substituted, a group of formula (II) ##STR56## where R 1 and R 2 , which are the same or different, each represents a hydrogen atom, a lower alkyl group, a halogen atom, a nitrile group, a nitro group, an alkoxy group or a hydroxyl group, or a group of formula (III) ##STR57## where R 1 and R 2 have the same meaning as defined above; and Z is a simple chemical bond, --O--, >C═O, --CH 2 --, --S--, --SO--, or --SO 2 --, which comprises reducing a dinitro compound of general formula (IV) ##STR58## wherein R has the same meaning as defined above.
Claim 4
Independent Claim
131 words
A method of producing a diamine compound represented by general formula (I) below: ##STR55## wherein R is a C 1 -C 12 alkylene group which is unsubstituted or substituted, a group of formula (II) ##STR56## where R 1 and R 2 , which are the same or different, each represents a hydrogen atom, a lower alkyl group, a halogen atom, a nitrile group, a nitro group, an alkoxy group or a hydroxyl group, or a group of formula (III) ##STR57## where R 1 and R 2 have the same meaning as defined above; and Z is a simple chemical bond, --O--, >C═O, --CH 2 --, --S--, --SO--, or --SO 2 --, which comprises reducing a dinitro compound of general formula (IV) ##STR58## wherein R has the same meaning as defined above.
Claim 5
Dependent Claim
124 words
A polyamideimide resin having a repeating unit represented by general formula (IV) below: ##STR59## wherein Ar and Ar 1 , which are the same or different, each represents a tetravalent aromatic residue to which two pairs of carbonyl groups are attached directly at four carbon atoms thereof, respectively, the two carbonyl groups in each one of the two pairs of carbonyl groups being attached to neighboring carbon atoms; R 3 is a group of general formula (VI) below: ##STR60## where R has the same meaning as defined above; R 4 is a divalent organic residue selected from aliphatic, aromatic and alicyclic groups other than those represented by R 3 ; and m and n are each zero or a positive integer which satisfy m≧2n.
Claim 6
Dependent Claim
124 words
A polyamideimide resin having a repeating unit represented by general formula (IV) below: ##STR59## wherein Ar and Ar 1 , which are the same or different, each represents a tetravalent aromatic residue to which two pairs of carbonyl groups are attached directly at four carbon atoms thereof, respectively, the two carbonyl groups in each one of the two pairs of carbonyl groups being attached to neighboring carbon atoms; R 3 is a group of general formula (VI) below: ##STR60## where R has the same meaning as defined above; R 4 is a divalent organic residue selected from aliphatic, aromatic and alicyclic groups other than those represented by R 3 ; and m and n are each zero or a positive integer which satisfy m≧2n.
References Cited (Backward Citations)
US3382261A
Cited
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