US5011812A
Expired / Lapsed
US
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Thermal transfer printing
Assignee: Imperial Chemical Industries Ltd
•
Filing: 1989-07-18
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Granted: 1991-04-30
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Expires: 2009-07-18
Abstract
Abstract A thermal transfer printing sheet comprising a substrate having a coating comprising a binder and a water insoluble dye of Formula I: ##STR1## wherein; R is the residue of an active methylene compound; X is hydrogen; halogen; optionally substituted alkyl; optionally substituted aryl or optionally substituted heteroaryl; Y is --S-- or a group of the formula N--R 1 wherein R 1 represents hydrogen or an optionally substituted C 1-4 -alkyl; and E is the residue of a coupling component. The dyes are suitable for use in dye diffusion thermal transfer printing of the type where a transfer sheet is placed in contact with the material to be printed and selectively heated in accordance with a pattern information signal whereby dye from the selectively heated regions of the transfer sheet is transferred to the material to be printed and forms a pattern thereon the shape and density of which is in accordance with the pattern and intensity of heat applied to the transfer sheet.
Inventors
- 👤 Roy Bradbury
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 06:20
CPC Classifications
B; B41; B41M; B41M5/00; B41M5/26; B41M5/382; B41M5/385; B41M5/388; Y; Y10; Y10S; Y10S428/00; Y10S428/913; Y10S428/914; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31725; Y10T428/31786; Y10T428/31855
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
80 words
A thermal transfer printing sheet comprising a substrate having a coating comprising a binder and at least one azo dye of Formula I: ##STR7## wherein; R is the residue of an active methylene compound; X is hydrogen; halogen; optionally substituted alkyl; optionally substituted aryl or optionally substituted heteroaryl; Y is -S- or a group of the formula >N--R 1 wherein R 1 represents hydrogen or an optionally substituted C 1-4 -alkyl; and E is the residue of a coupling component.
Claim 2
Dependent Claim
80 words
A thermal transfer printing sheet comprising a substrate having a coating comprising a binder and at least one azo dye of Formula I: ##STR7## wherein; R is the residue of an active methylene compound; X is hydrogen; halogen; optionally substituted alkyl; optionally substituted aryl or optionally substituted heteroaryl; Y is -S- or a group of the formula >N--R 1 wherein R 1 represents hydrogen or an optionally substituted C 1-4 -alkyl; and E is the residue of a coupling component.
Claim 3
Dependent Claim
65 words
A thermal transfer printing sheet according to claim 1 wherein R in the azo dyes is a group of Formula II: ##STR8## wherein: R 2 is cyano; acetyl; optionally substituted C 1-10 -alkoxy-carbonyl; optionally substituted C 3-8 -alkenyloxycarbonyl; C 1-4 -alkylsulphonyl; optionally substituted phenylsulphonyl; optionally substituted aminocarbonyl; optionally substituted C 1-4 -alkylamino- carbonyl; optionally substituted di(C 1-4 -alkyl)aminocarbonyl; optionally substituted phenyl or optionally substituted benzoyl.
Claim 4
Dependent Claim
84 words
A thermal transfer printing sheet according to claim 1 or claim 2 wherein E in the azo dyes is a group of Formula III: ##STR9## wherein: R 3 & R 4 are independently hydrogen; optionally substituted C 1-4 -alkyl; C 4-8 -cycloalkyl; C 3-4 -alkenyl; phenyl-C 1-4 -alkyl or phenyl; R 5 is hydrogen; halogen; C 1-4 -alkyl; C 1-4 -alkoxy; C 1-4 -alkylthio; C 1-4 -alkylcarbonylamino; phenylcarbonylamino or C 1-4 -alkylsulphonylamino; and R 6 is hydrogen; C 1-4 -alkyl or C 1-4 -alkoxy.
Claim 5
Dependent Claim
114 words
A thermal transfer printing sheet according to claim 1 or claim 2 wherein E in the azo dyes is a group of Formula III wherein: R 3 & R 4 are independently hydrogen; C 1-4 -alkyl; C 4-8 -cycloalkyl; phenyl or C 1-4 -alkyl substituted by a group selected from --OH, --CN, halogen, C 1-4 -alkoxy, C 1-4 -alkoxy-C 1-4 -alkoxy, C 1-4 -alkyl-CO-, C 1-4 -alkoxy-CO-, C 1-4 -alkyl-COO-, C 1-4 -alkoxy-C 1-4 -alkoxy-CO-, C 1-4 -alkoxy-COO- and C 1-4 -alkoxy-C 1-4 -alkyl-COO-; R 5 is hydrogen; C 1-4 -alkyl; cyano-C 1-4 -alkyl; C 1-4 -alkoxy or --NHCOT 1 wherein T 1 is C 1-4 -alkyl or phenyl; and R 6 is hydrogen.
Claim 6
Dependent Claim
32 words
A thermal transfer printing sheet according to claim 1 wherein the substrate is <20 um in thickness and is capable of withstanding temperatures up to 400° C. for up to 20 milliseconds.
Claim 7
Dependent Claim
50 words
A thermal transfer printing sheet according to claim 5 wherein the substrate is selected from the group consisting of (i) paper, (ii) polyester, polyacrylate, polyamide, cellulosic or polyalkylene films, (iii) metallized forms of polyester, polyacrylate, polyamide, cellulosic or polyalkylene films, (iv) co-polymer films and (v) laminates incorporating polyester receptor layers.
Claim 8
Dependent Claim
24 words
A thermal transfer printing sheet according to claim 1 wherein the binder is a polymeric material suitable for binding the dye to the substrate.
Claim 9
Dependent Claim
55 words
A thermal transfer printing sheet according to claim 7 wherein the binder is selected from ethyl hydroxycellulose, hydroxypropylcellulose, methylcellulose, ethylcellulose, cellulose acetate, cellulose acetate butyrate; starch; alkyd resins; polyvinylalcohol, polyvinyl butyral; polyvinyl pyrrolidone; polyacrylic acid, polymethyl-methacrylate, styreneacrylate co-polymers, polyester resins, polyamide resins, melamines; polyurea and polyurethane resins; polysiloxanes, epoxy resins, gum tragacanth and gum arabic.
Claim 10
Dependent Claim
20 words
A thermal transfer printing sheet according to claim 1 wherein the binder to dye ratio is from 1:1 to 4:1.
Claim 11
Dependent Claim
56 words
A process for the preparation of a thermal transfer printing sheet according to claim 1 which comprises applying an ink comprising 0.1 to 10% of the dye and 0.1 to 10% of the binder dissolved or dispersed in a solvent and evaporating the solvent to produce a coating of the dye and binder on the substrate.
Claim 12
Dependent Claim
54 words
A transfer printing sheet which comprises contacting a transfer sheet according to claim 1 with a receiver sheet so that the dye is in contact with the receiver sheet and selectively heating areas of the transfer sheet whereby dye in the heated areas of the transfer sheet may be transferred to the receiver sheet.
Claim 13
Dependent Claim
50 words
A transfer printing process according to claim 11 wherein the transfer sheet is heated to a temperature from 300° C. to 400° C. for a period of 1 to 20 milliseconds while in contact with the receiver sheet whereby the amount of dye transferred is proportional to the heating period.
Claim 14
Dependent Claim
16 words
A transfer printing process according to claim 12 wherein the receiver sheet is white polyester film.
Claim 15
Dependent Claim
19 words
A transfer printing process according to claim 11 or claim 12 wherein the receiver sheet is white polyester film.
Claim 16
Dependent Claim
144 words
A thermal transfer printing sheet comprising a substrate having a coating comprising a binder and at least one azo dye of the Formula V: ##STR10## wherein: R 2 represents cyano; acetyl and optionally substituted C 1-6 -alkoxycarbonyl; optionally substituted C 3-8 alkenyloxycarbonyl; optionally substituted C 1-4 -alkylsulphonyl; optionally substituted phenylsulphonyl; optionally substituted aminocarbonyl; optionally substituted C 1-4 -alkylaminocarbonyl; optionally substituted di(C 1-4 -alkyl)aminocarbonyl; optionally substituted phenyl and optionally substituted benzoyl; X represents hydrogen; halogen; optionally substituted alkyl; optionally substituted aryl and optionally substituted heteroaryl; Y represents -S- and >N--R 1 wherein R 1 is hydrogen or optionally substituted C 1-4 -alkyl; R 3 and R 4 independently represent H; C 1-4 -alkyl; phenyl; C 4-8 -cycloalkyl and C 1-4 alkyl substituted by a group dispersed in a solvent and evaporating the solvent to produce a coating of the dye and binder on the substrate.
Claim 17
Dependent Claim
144 words
A thermal transfer printing sheet comprising a substrate having a coating comprising a binder and at least one azo dye of the Formula V: ##STR10## wherein: R 2 represents cyano; acetyl and optionally substituted C 1-6 -alkoxycarbonyl; optionally substituted C 3-8 alkenyloxycarbonyl; optionally substituted C 1-4 -alkylsulphonyl; optionally substituted phenylsulphonyl; optionally substituted aminocarbonyl; optionally substituted C 1-4 -alkylaminocarbonyl; optionally substituted di(C 1-4 -alkyl)aminocarbonyl; optionally substituted phenyl and optionally substituted benzoyl; X represents hydrogen; halogen; optionally substituted alkyl; optionally substituted aryl and optionally substituted heteroaryl; Y represents -S- and >N--R 1 wherein R 1 is hydrogen or optionally substituted C 1-4 -alkyl; R 3 and R 4 independently represent H; C 1-4 -alkyl; phenyl; C 4-8 -cycloalkyl and C 1-4 alkyl substituted by a group dispersed in a solvent and evaporating the solvent to produce a coating of the dye and binder on the substrate.
Claim 18
Dependent Claim
75 words
A thermal transfer printing sheet according to claim 15 wherein in the azo dye of Formula V: R 2 is C 1-6 -alkoxycarbonyl or C 1-4 -alkoxy-C 1-4 -alkoxycarbonyl; X is chloro; Y is sulphur; R 3 & R 4 independently are C 1-4 -alkyl or C 1-4 -alkoxy-CO-C 1-4 -alkyl; R 5 is hydrogen; C 1-4 -alkyl or --NHCOT 1 wherein T 1 is C 1-4 -alkyl or phenyl; and R 6 is hydrogen.
Claim 19
Dependent Claim
54 words
A thermal transfer printing sheet according to claim 15 wherein in the azo dye of Formula V: R 2 is ethoxycarbonyl or ethoxyethoxycarbonyl; X is chloro; Y is sulphur; R 3 & R 4 independently are ethyl, butyl, 1-methylpropyl, 2-methylpropyl, acetoxyethyl or acetoxybutyl; R 5 is methyl or acetylamino; and R 6 is hydrogen.
References Cited (Backward Citations)
US4859651A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1994-04-29 | 1994-10-29 | 1995-04-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1998-04-29 | 1998-10-29 | 1999-04-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2002-04-29 | 2002-10-29 | 2003-04-30 | $7700.00 | Window Closed / Lapsed |