Integrated process for the production of aminoacetonitriles

Claim 2

An improved process for the production of aminoacetonitriles prepared by (a) contacting in a reactive absorber, under reactive conditions hydrogen cyanide, formaldehyde, and an additional nitrogen source, (b) scrubbing the reaction products from (a) supra with a pH-controlled, aqueous scrubbing solution to form an aminoacetonitrile product, and (c) recovering the product, wherein the improvement comprises: using as a source of hydrogen cyanide in step (a) the direct unpurified reactor product stream of a hydrogen cyanide production process comprising a gaseous mixture of hydrogen cyanide and ammonia, using as a source of formaldehyde in step (a) the direct unpurified reactor product stream of a formaldehyde production process comprising a gaseous mixture of formaldehyde and water using as an additional nitrogen source a composition represented by the formula ##STR3## wherein R 1 and R 2 are each independently selected from alkyl, alkene, cycloalkyl groups, their amine substituted derivatives, and hydrogen.

Claim 3

An improved process for the production of aminoacetonitriles prepared by (a) contacting in a reactive absorber, under reactive conditions hydrogen cyanide, formaldehyde, and an additional nitrogen source, (b) scrubbing the reaction products from (a) supra with a pH-controlled, aqueous scrubbing solution to from an aminoacetonitrile product, and (c) recovering the product, wherein the improvement comprises: using as a source of hydrogen cyanide in step (a) the direct unpurified reactor product stream of a hydrogen cyanide production process comprising a gaseous mixture of hydrogen cyanide and ammonia, using as a source of formaldehyde in step (a) the aqueous formaldehyde solution obtained from an absorption column of a formaldehyde production process using as an additional nitrogen source a composition represented by the formula ##STR4## wherein R 1 and R 2 are each independently selected from alkyl, alkene, cycloalkyl groups, their amine substituted derivatives, and hydrogen.

Claim 4

An improved process for the production of aminoacetonitriles prepared by (a) contacting in a reactive absorber, under reactive conditions hydrogen cyanide, formaldehyde, and an additional nitrogen source, (b) scrubbing the reaction products from (a) supra with a pH-controlled, aqueous scrubbing solution to from an aminoacetonitrile product, and (c) recovering the product, wherein the improvement comprises: using as a source of hydrogen cyanide in step (a) the direct unpurified reactor product stream of a hydrogen cyanide production process comprising a gaseous mixture of hydrogen cyanide and ammonia, using as a source of formaldehyde in step (a) the aqueous formaldehyde solution obtained from an absorption column of a formaldehyde production process using as an additional nitrogen source a composition represented by the formula ##STR4## wherein R 1 and R 2 are each independently selected from alkyl, alkene, cycloalkyl groups, their amine substituted derivatives, and hydrogen.

Claim 5

The improved process for the production of aminoacetonitriles in claim 1 wherein the process for producing the unpurified hydrogen cyanide reactor product gas stream is the ammoxidation of methane, the ammoxidation of methanol, the reaction of ammonia and propane, the decomposition of formamide, the recovery of hydrogen cyanide from the ammoxidation of propylene, or the process wherein methanol or formaldehyde or a mixture thereof, ammonia and oxygen are reacted in the presence of a metal oxide catalyst simultaneously with the decomposition of formamide.

Claim 6

The improved process for the production of aminoacetonitriles in claim 1 wherein the process for producing the crude formaldehyde reactor product stream is the catalytic oxidation of methanol over ferric molybdate or the catalytic dehydrogenation of methanol over a silver catalyst.

Claim 7

The improved process for the production of aminoacetonitriles according to claim 1 wherein the reactive absorber is maintained at a pressure in the range 5 to 200 psig., at a temperature 50° C., the aqueous scrubber solution has a pH in the range of 0.1 to 2.0, the pH being maintained by the continuous addition of a mineral acid, and additional nitrogen source is ethylenediamine, and wherein the aminoacetonitrile product is ethylenediamine-tetraacetonitrile.

Claim 8

The improved process for the production of ethylenediaminatetraacetonitrile in claim 5 wherein: (a) the reactive absorber is maintained; (1) at a temperature in the range 60° to 85° C.; (2) at a pressure in the range 5 to 100 psig (b) the pH of the aqueous scrubber solution is maintained in the range of 0.5 to 1.0 by the continuous addition of H 2 SO 4 .

Claim 9

The improved process for the production of aminoacetonitriles according to claim 2 wherein the reactive absorber is maintained at a pressure in the range 5 to 200 psig., at a temperature 50° to 90° C., the aqueous scrubber solution has a pH in the range of 0.1 to 2.0, the pH being maintained by the continuous addition of a mineral acid, and the additional nitrogen source is ethylenediamine, and wherein the aminoacetonitrile product is ethylenediamine-tetraacetonitrile.

Claim 10

The improved process for the production of aminoacetonitriles according to claim 1 wherein (a) the reactive absorber is maintained: (a) at a pressure in the range 10 to 200 psig. at a temperature in the range 25° to 90° C., (b) the pH of the aqueous scrubber solution is maintained in the range 0.1 to 1.0 by the continuous addition of H2SO4 and the additional nitrogen source is ammonia and wherein the aminoacetonitrile product is nitrilotriacetonitrile.

Claim 11

The improved process for the production of aminoacetonitriles according to claim 1 wherein (a) the reactive absorber is maintained (1) at a temperature in the range 60° to 85° C.; (2) at a pressure in the range 50 to 200 psig (b) the pH of the aqueous scrubber solution is maintained in the range 0.1 to 0.5 by the continuous addition of H2SO4 and the additional nitrogen source is ammonia and wherein the aminoacetonitrile product is nitrilotriacetonitrile.

Claim 12

The improved process for the production of aminoacetonitriles according to claim 2 wherein (a) the reactive absorber is maintained: (a) at a pressure in the range 10 to 200 psig. at a temperature in the range 25° to 90° C., (b) the pH of the aqueous scrubber solution is maintained in the range 0.1 to 1.0 by the continuous addition of H2SO4 and the additional nitrogen source is ammonia and wherein the aminoacetonitrile product is nitrilotriacetonitrile.

Claim 13

The improved process for the production of aminoacetonitriles according to claim 1 wherein (a) the reactive absorber is maintained: (a) at a pressure in the range 1 to 10 psig. at a temperature in the range 25° to 90° C., (b) the pH of the aqueous scrubber solution is maintained in the range 8 to 12 by the continuous addition of H2SO4 and the additional nitrogen source is ammonia and wherein the aminoacetonitrile product is glycinonitrile.

Claim 14

The improved process for the production of aminoacetonitriles in claim 1 wherein (a) the reactive absorber is maintained (1) at a temperature in the range 60° to 85° C.; (2) at a pressure in the range 5 to 10 psig (b) the pH of the aqueous scrubber solution is maintained in the range 9 to 11 by the continuous addition of H2SO4 and the additional nitrogen source is ammonia and wherein the aminoacetonitrile product is glycinonitrile.

Claim 15

The improved process for the production of aminoacetonitriles according to claim 2 wherein (a) the reactive absorber is maintained; (a) at a pressure in the range 1 to 10 psig. at a temperature in the range 25° to 90° C., (b) the pH of the aqueous scrubber solution is maintained in the range 8 to 12 by the continuous addition of H2SO4 and the additional nitrogen source is ammonia and wherein the aminoacetonitrile product is glycinonitrile.

Claim 16

The improved process for the production of glycinonitrile according to claim 12 wherein the glycinonitrile product stream is passed through a hot tube reactor.

Claim 17

An improved process for the production of aminoacetonitriles prepared by (a) contacting in a reactive absorber, under reactive conditions hydrogen cyanide, formaldehyde, and an additional nitrogen source, (b) scrubbing the reaction products from (a) supra with a pH-controlled, aqueous scrubbing solution to form an aminoacetonitrile product, and (c) recovering the product, wherein the improvement comprises: using as a source of hydrogen cyanide in step (a) the direct unpurified reactor product stream of a hydrogen cyanide production process comprising a gaseous mixture of hydrogen cyanide and ammonia, using as a source of formaldehyde in step (a) the direct unpurified reactor product stream of a formaldehyde production process comprising a gaseous mixture of formaldehyde and water, using as an additional nitrogen source a composition represented by the formula ##STR5## wherein R 1 and R 2 are each independently selected from alkyl, alkene, cycloalkyl groups, their amine substituted derivatives, and hydrogen and wherein the aminoacetonitrile product from step (b) is passed through a hot tube reactor maintained at a temperature in the range 50° to 200° C. to accelerate nitrile formation.

Claim 18

An improved process for the production of aminoacetonitriles prepared by (a) contacting in a reactive absorber, under reactive conditions hydrogen cyanide, formaldehyde, and an additional nitrogen source, (b) scrubbing the reaction products from (a) supra with a pH-controlled, aqueous scrubbing solution to form an aminoacetonitrile product, and (c) recovering the product, wherein the improvement comprises: using as a source of hydrogen cyanide in step (a) the direct unpurified reactor product stream of a hydrogen cyanide production process comprising a gaseous mixture of hydrogen cyanide and ammonia, using as a source of formaldehyde in step (a) the direct unpurified reactor product stream of a formaldehyde production process comprising a gaseous mixture of formaldehyde and water, using as an additional nitrogen source a composition represented by the formula ##STR5## wherein R 1 and R 2 are each independently selected from alkyl, alkene, cycloalkyl groups, their amine substituted derivatives, and hydrogen and wherein the aminoacetonitrile product from step (b) is passed through a hot tube reactor maintained at a temperature in the range 50° to 200° C. to accelerate nitrile formation.

Claim 19

An improved process for the production of aminoacetonitriles prepared by (a) contacting in a reactive absorber, under reactive conditions hydrogen cyanide, formaldehyde, and an additional nitrogen source, (b) scrubbing the reaction products from (a) supra with a pH-controlled, aqueous scrubbing solution to form an aminoacetonitrile product, and (c) recovering the product, wherein the improvement comprises: using as a source of hydrogen cyanide in step (a) the direct unpurified reactor product stream of a hydrogen cyanide production process comprising a gaseous mixture of hydrogen cyanide and ammonia, using as a source of formaldehyde in step (a) the aqueous formaldehyde solution obtained from an absorption column of a formaldehyde production process, and wherein the aminoacetonitrile product from step (b) is passed through a hot tube reactor maintained at a temperature in the range 50° to 200° C. to accelerate nitrile formation using as an additional nitrogen source a composition represented by the formula ##STR6## wherein R 1 and R 2 are each independently selected from alkyl, alkene, cycloalkyl groups, their amine substituted derivatives, and hydrogen.

Claim 20

An improved process for the production of aminoacetonitriles prepared by (a) contacting in a reactive absorber, under reactive conditions hydrogen cyanide, formaldehyde, and an additional nitrogen source, (b) scrubbing the reaction products from (a) supra with a pH-controlled, aqueous scrubbing solution to form an aminoacetonitrile product, and (c) recovering the product, wherein the improvement comprises: using as a source of hydrogen cyanide in step (a) the direct unpurified reactor product stream of a hydrogen cyanide production process comprising a gaseous mixture of hydrogen cyanide and ammonia, using as a source of formaldehyde in step (a) the aqueous formaldehyde solution obtained from an absorption column of a formaldehyde production process, and wherein the aminoacetonitrile product from step (b) is passed through a hot tube reactor maintained at a temperature in the range 50° to 200° C. to accelerate nitrile formation using as an additional nitrogen source a composition represented by the formula ##STR6## wherein R 1 and R 2 are each independently selected from alkyl, alkene, cycloalkyl groups, their amine substituted derivatives, and hydrogen.

Claim 21

An improved process according to claim 1 wherein the additional nitrogen source is selected from the group consisting of ammonia, methylamine, ethylamine, n-propylamine, isopropylamine, n-butylamine, isobutylamine, sec-butylamine, tert-butylamine, pentylamine, pentyl-2-amine, pentyl-3-amine, n-hexylamine, n-heptylamine, n-octylamine, n-nonylamine, n-decylamine and 2-ethylhexylamine; ethylenediamine, propylenediamine, isopropylenediamine, butylenediamine, sec-butylenediamine, isobutylenediamine and tert-butylenediamine; diethylenetriamine, dipropylenetriamine, diisopropylenetriamine, dibutylenetriamine, diisobutylenetriamine, di-sec-butylenetriamine and ditert-butylenetriamine; triethylenetetramine, tripropylenetetramine, triisopropylenetetramine, tributylenetetramine, tri-sec-butylenetetramine, triisobutylenetetramine and tri-tert-butylenetetramine; tetraethylenepentamine, tetrapropylenepentamine, tetraisopropylenepentamine, tetrabutylenepentamine, tetraisobutylenepentamine, tetra-sec-butylenepentamine and tetra-tert-butylenepentamine.

Claim 22

An improved process according to claim 2 wherein the additional nitrogen source is selected from the group consisting of ammonia, methylamine, ethylamine, n-propylamine, isopropylamine, n-butylamine, isobutylamine, sec-butylamine, tert-butylamine, pentylamine, pentyl-2-amine, pentyl-3-amine, n-hexylamine, n-heptylamine, n-octylamine, n-nonylamine, n-decylamine and 2-ethylhexylamine; ethylenediamine, propylenediamine, isopropylenediamine, butylenediamine, sec-butylenediamine, isobutylenediamine and tert-butylenediamine; diethylenetriamine, dipropylenetriamine, diisopropylenetriamine, dibutylenetriamine, diisobutylenetriamine, de-sec-butylenetriamine and ditert-butylenetriamine; triethylenetetramine, tripropylenetetramine, triisopropylenetetramine, tributylenetetramine, tri-sec-butylenetetramine, triisobutylenetetramine and tri-tertbutylenetetramine; tetraethylenepentamine, tetra-propylenepentamine, tetraisopropylenepentamine, tetrabutylenepentamine, tetraisobutylenepentamine, tetra-sec-butylenepentamine and tetra-tert-butylenepentamine.

Claim 23

An improved process according to claim 15 wherein the additional nitrogen source is selected from the group consisting of ammonia, methylamine, ethylamine, n-propylamine, isopropylamine, n-butylamine, isobutylamine, sec-butylamine, tert-butylamine, pentylamine, pentyl-2-amine, pentyl-3-amine, n-hexylamine, n-heptylamine, n-octylamine, n-nonylamine, n-decylamine and 2-ethylhexylamine; ethylenediamine, propylenediamine, isopropylenediamine, butylenediamine, sec-butylenediamine, isobutylenediamine and tert-butylenediamine; diethylenetriamine, dipropylenetriamine, diisopropylenetriamine, dibutylenetriamine, diisobutylenetriamine, di-sec-butylenetriamine and ditert-butylenetriamine; triethylenetetramine, tripropylenetetramine, triisopropylenetetramine, tributylenetetramine, tri-sec-butylenetetramine, triisobutylenetetramine and tri-tert-butylenetetramine; tetraethylenepentamine, tetrapropylenepentamine, tetraisopropylenepentamine, tetrabutylenepentamine, tetraisobutylenepentamine, tetra-sec-butylenepentamine and tetra-tert-butylenepentamine.

Claim 24

An improved process according to claim 16 wherein the additional nitrogen source is selected from the group consisting of ammonia, methylamine, ethylamine, n-propylamine, isopropylamine, n-butylamine, isobutylamine, sec-butylamine, tert-butylamine, pentylamine, pentyl-2-amine, pentyl-3-amine, n-hexylamine, n-heptylamine, n-octylamine, n-nonylamine, n-decylamine and 2-ethylhexylamine; ethylenediamine, propylenediamine, isopropylenediamine, butylenediamine, sec-butylenediamine, isobutylenediamine and tert-butylenediamine; diethylenetriamine, dipropylenetriamine, diisopropylenetriamine, dibutylenetriamine, diisobutylenetriamine, di-sec-butylenetriamine and ditert-butylenetriamine; triethylenetetramine, tripropylenetetramine, triisopropylenetetramine, tributylenetetramine, tri-sec-butylenetetramine, triisobutylenetetramine and tri-tert-butylenetetramine; tetraethylenepentamine, tetrapropylenepentamine, tetraisopropylenepentamine, tetrabutylenepentamine, tetraisobutylenepentamine, tetra-sec-butylenepentamine and tetra-tert-butylenepentamine.