Method for determining the concentration of a plurality of combustible gases in a stream

Claim 3

determining the value of said steady state electrical current flowing through said electrolyte; 2. determining the surge of electrical current flowing through said electrolyte after said flow of electrical current is interrupted and then restored, by: interrupting said electrical current flowing through said electrolyte for a time period, t, after said time period, t, restoring said flow of electrical current through said electrolyte; and measuring the surge of electrical current flowing through said electrolyte over and above said steady state electrical current flow until the electrical current flow attains its steady state value; (d) determining the total pressure of the gases in said gas stream; and (e) converting said total pressure and said electrical current flow measurements into an indication of the concentration of each of the n combustible gases in said gas stream.

Claim 4

determining the value of said steady state electrical current flowing through said electrolyte; 2. determining the surge of electrical current flowing through said electrolyte after said flow of electrical current is interrupted and then restored, by: interrupting said electrical current flowing through said electrolyte for a time period, t, after said time period, t, restoring said flow of electrical current through said electrolyte; and measuring the surge of electrical current flowing through said electrolyte over and above said steady state electrical current flow until the electrical current flow attains its steady state value; (d) determining the total pressure of the gases in said gas stream; and (e) converting said total pressure and said electrical current flow measurements into an indication of the concentration of each of the n combustible gases in said gas stream.

Claim 5

The method of claim 1 wherein said electrical current flow measurements are converted into an indication of the partial pressures of said combustible gases in said gas stream, and the concentration of each of said combustible gases in said gas stream is determined by dividing said partial pressures of each of said combustible gases by said total pressure of said gas stream.

Claim 6

The method of claim 1 wherein two combustible gases are present in said gas stream.

Claim 7

The method of claim 2 wherein two combustible gases are present in said gas stream.

Claim 8

The method of claim 4 wherein said partial pressures of said combustible gases in said gas stream are determined by solving any two of the following equations: i=(F*k*A)*[(h G1* D G1* P.sup.s G1)+(h G2* D G2* P.sup.s G2)]; Q1[(V*F)/(R*T)][(h G1* P.sup.s G1* (1-e.sup.(-k*D G1*A*t1)))+(h G2* P.sup.s G2* (1-e.sup.(-k*D G2*A*t1)))]; Q2=[(V*F)/(R*T)]*[(h G1* P.sup.s G1)+(h G2* P.sup.s G2* (1-e.sup.(-k*D G2*A*t2)))]; and Q3=[(V*F)/(R*T)]*[(h G1* P.sup.s G1)+(h G2* P.sup.s G2)] wherein; V is volume of said electrochemical cell cavity; F is Faraday's number; R is the universal gas constant; T is the absolute temperature of said portion of said gas stream within said cell cavity; h G1 is the number of electrons transferred in the half cell equation when combustible gas 1 is reacted with oxygen ions; h G2 is the number of electrons transferred in the half cell equation when combustible gas 2 is reacted with oxygen ions; P s G1 is the partial pressure of gas 1 in said gas stream; P s G2 is the partial pressure of gas 2 in said gas stream; k=(2*πR 2 )/[(2*r*l)+R 2 ], wherein R is the radius of said electrochemical cell; l is the difference between the length L and the radius R of said electrochemical cell; and r is the radius of said diffusion limiting port; D G1 is the diffusivity of combustible gas 1 in a mixture of combustible gases 1 and 2 having a composition approximating that of said combustible gases in said cell cavity; D G2 is the diffusivity of combustible gas 2 in a mixture of combustible gases 1 and 2 having a composition approximating that of said combustible gases in said cell cavity; A is the area of said diffusion limiting port, or *r 2 , wherein r is the radius of said diffusion limiting port; t1 is a time period, less than that necessary for the combustible gases G1 and G2 to reach equilibrium between said gas stream and said cell cavity, for which the electrical current flowing through said electrolyte was interrupted; and t2 is a time period, less than that necessary for the combustible gas G2 to reach equilibrium between said gas stream and said cell cavity, but greater than that necessary for combustible gas G1 to reach equilibrium between said gas stream and said cell cavity, for which the electrical current flowing through said electrolyte was interrupted.

Claim 9

The method of claim 5 wherein said first combustible gas is hydrogen, said second combustible gas is carbon monoxide, h H 2 is 2, h CO is 2 and said equations are: i=(F*k*A)*[(2* D H.sub.2 * P.sup.s H.sub.2)+(2* D CO* P.sup.s CO)]; Q1=[(V*F)/(R*T)]*[(2* P.sup.s H.sub.2 *(1-e.sup.(-k*D H2*A*t1)))+(2* P.sup.s CO* (1-e(.sup.-k*D CO*A*t1)))]; Q2=[(V*F)/(R*T)]*[(2*P.sup.s H.sub.2)+(2* P.sup.s CO*(1-e.sup.(-k*D CO*A*t2))); and Q3=[(V*F)/(R*T)]*[(2* P.sup.s H.sub.2)+(2*P.sup.s CO)].

Claim 10

The method of claim 1 wherein three combustible gases are present in said gas stream.

Claim 11

The method of claim 2 wherein three combustible gases are present in said gas stream.

Claim 12

The method of claim 8 wherein said partial pressures of said combustible gases in said gas stream are determined by solving any three of the following equations: ##EQU9## wherein; V is volume of said electrochemical cell cavity; F is Faraday's number; R is the universal gas constant; T is the absolute temperature of said portion of said gas stream within said cell cavity; h G1 is the number of electrons transferred in the half cell equation when combustible gas 1 is reacted with oxygen ions; h G2 is the number of electron red in the half cell equation when combustible gas 2 is reacted with oxygen ions; h G3 is the number of electrons transferred in the half cell equation when combustible gas 3 is reacted with oxygen ions; P s G1 is the partial pressure of combustible gas 1 in said gas stream; P s G2 is the partial pressure of combustible gas 2 in said gas stream; P s G3 is the partial pressure of combustible gas 3 in said gas stream; k=(2*π*R 2 )/[(w*r*l)+R 2 ], wherein R is the radius of said electrochemical cell; l is the difference between the length L and the radius R of said electrochemical cell; and r is the radius of said diffusion limiting port; D G1 is the diffusivity of combustible gas 1 in a mixture of combustible gases 1, 2 and 3 having a composition approximating that of said combustible gases in said cell cavity; D G2 is the diffusivity of combustible gas 2 in a mixture of combustible gases 1, 2 and 3 having a composition approximating that of said combustible gases in said cell cavity; D G3 is the diffusivity of combustible gas 3 in a mixture of combustible gases 1, 2 and 3 having a composition approximating that of said combustible gases in said cell cavity; A is the area of said diffusion limiting port, or π*r 2 , wherein r is the radius of said diffusion limiting port; t1 is a time period, less than that necessary for the combustible gases G1, G2 and G3 to reach equilibrium between said gas stream and said cell cavity, for which the electrical current flowing through said electrolyte was interrupted; t2 is a time period, less than that necessary for the combustible gases G2 and G3 to reach equilibrium between said gas stream and said cell cavity, but greater than that necessary for combustible gas G1 to reach equilibrium between said gas stream and said cell cavity, for which the electrical current flowing through said electrolyte was interrupted; and t3 is a time period, less than that necessary for the combustible gas G3 to reach equilibrium between said gas stream and said cell cavity, but greater than that necessary for combustible gases G1 and G2 to reach equilibrium between said gas stream and said cell cavity, for which the electrical current flowing through said electrolyte was interrupted.

Claim 13

The method of claim 9 wherein said first combustible gas is hydrogen, said second combustible gas is methane, said third combustible gas is carbon monoxide, h H 2 is 2, h CH 4 is 8, h CO is 2 and said equations are: ##EQU10##

Claim 14

The method of claim 1 wherein n combustible gases are present in said gas stream.

Claim 15

The method of claim 2 wherein n combustible gases are present in said gas stream.

Claim 16

The method of claim 3 wherein said partial pressures of said combustible gases in said gas stream are determined by solving any n of the following equations: ##EQU11## wherein; V is volume of said electrochemical cell cavity; F is Faraday's number; R is the universal gas constant; T is the absolute temperature of the gas within said cell cavity; h Gy is the number of electrons transferred in the half cell equation when combustible gas Gy is reacted with oxygen ions; P s Gy is the partial pressure of combustible gas Gy in said gas stream; k=(2*π*R 2 )/[(2*r*l)+R 2 ], wherein R is the radius of said electrochemical cell; l is the difference between the length L and the radius R of said electrochemical cell; and r is the radius of said diffusion limiting port; D Gy is the diffusivity of gas Gy in a mixture of combustible gases G1 through Gn having a composition approximating that of said n combustible gases in said cell cavity; A is the area of said diffusion limiting port, or π*r 2 , wherein r is the radius of said diffusion limiting port; and tx is the time period for which the electrical current flowing through said electrolyte was interrupted.