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US5002996A Expired / Lapsed US ⏱️ 0.0 years remaining

Flame retardant olefinic resin composition

Assignee: Sumitomo Bakelite Co Ltd
•
Filing: 1989-03-06
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Granted: 1991-03-26
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Expires: 2009-03-06
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Abstract

Abstract A flame-retardant olefinic resin composition comprising (a) at least one ethylene copolymer selected from the group consisting of ethylene- alpha -olefin copolymers, ethylene-ethyl acrylate copolymer and ethylene-methyl methacrylate copolymer, (b) a silane-grafted polymer obtained by grafting a silane to an olefinic resin, (c) a maleic acid or maleic anhydride derivative of a polyethylene, an ethylene-vinyl acetate copolymer or an ethylene- alpha -olefin copolymer, (d) (i) an ethylene-ethyl acrylate-maleic anhydride copolymer or an ethylene-methyl methacrylate-maleic anhydride copolymer, or (d) (ii) a silicone-modified polymer obtained by graft-polymerizing a reactive polyorganosiloxane to a thermoplastic resin, or (d) (iii) a mixture of (d) (i) and (d) (ii).

Inventors

  • 👤 Nobuaki Okuda
  • 👤 Yasuo Nakagawa

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 18:06
CPC Classifications
C; C08; C08L; C08L23/00; C08L23/02; C08L23/04; C08L23/08; C08K; C08K3/00; C08K3/18; C08K3/20; C08K3/22; C08F; C08F255/00; C08F255/02; C08F255/026; C08L23/0807; C08L23/0815; C08L23/0846; C08L23/0869; C08L51/00; C08L51/06; C08L2201/00; C08L2201/02; C08L2205/00; C08L2205/02; C08L2205/03; C08L2205/035

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 166 words
A flame-retardant olefinic resin composition comprising (a) at least one ethylene copolymer selected from the group consisting of ethylene-α-olefin copolymers, ethylene-ethyl acrylate copolymer and ethylene-methyl methacrylate copolymer, (b) a silane-grafted polymer obtained by grafting a silane to an olefinic resin, (c) a maleic acid or maleic anhydride derivative of a polyethylene, an ethylene-vinyl acetate copolymer or an ethylene-α-olefin copolymer, (d)(i) an ethylene-ethyl acrylate-maleic anhydride copolymer or an ethylene-methyl methacrylatemaleic anhydride copolymer, or (d)(ii) a siliconemodified polymer obtained by graft-polymerizing a reactive polyorganosiloxane to a thermoplastic resin, or (d)(iii) a mixture of (d)(i) and (d)(ii) and (e) a hydrated metal compound, wherein there are incorporated the component (c) in an amount of 0.1-30 parts by weight, the component (d)(i) in an amount of 0.1-30 parts by weight when used, the component (d)(ii) in an amount of 0.1-30 parts by weight when used, and the component (e) in an amount of 50-300 parts by weight, all based on 100 parts by weight of the components (a) and (b).
Claim 2
Dependent Claim 166 words
A flame-retardant olefinic resin composition comprising (a) at least one ethylene copolymer selected from the group consisting of ethylene-α-olefin copolymers, ethylene-ethyl acrylate copolymer and ethylene-methyl methacrylate copolymer, (b) a silane-grafted polymer obtained by grafting a silane to an olefinic resin, (c) a maleic acid or maleic anhydride derivative of a polyethylene, an ethylene-vinyl acetate copolymer or an ethylene-α-olefin copolymer, (d)(i) an ethylene-ethyl acrylate-maleic anhydride copolymer or an ethylene-methyl methacrylatemaleic anhydride copolymer, or (d)(ii) a siliconemodified polymer obtained by graft-polymerizing a reactive polyorganosiloxane to a thermoplastic resin, or (d)(iii) a mixture of (d)(i) and (d)(ii) and (e) a hydrated metal compound, wherein there are incorporated the component (c) in an amount of 0.1-30 parts by weight, the component (d)(i) in an amount of 0.1-30 parts by weight when used, the component (d)(ii) in an amount of 0.1-30 parts by weight when used, and the component (e) in an amount of 50-300 parts by weight, all based on 100 parts by weight of the components (a) and (b).
Claim 3
Dependent Claim 37 words
A flame-retardant olefinic resin composition according to claim 1, wherein the α-olefin of the ethylene-α-olefin copolymers is selected from the group consisting of propylene, butene-1, pentene-1, hexene-1, heptene-1, octene-1, 4-methylpentene-1, 4-methylhexene-1, 4,4-dimethylpentene-1, nonene-1, decene-1, undecene-1 and dodecene-1.
Claim 4
Dependent Claim 51 words
A flame-retardant olefinic resin composition according to claim 1, wherein the olefinic resin to be grafted with a silane is selected from the group consisting of low density polyethylene medium density polyethylene, high density polyethylene ethylene-α-olefin copolymers, ethylene-vinyl acetate copolymer, ethylene-ethyl acrylate copolymer, ethylene-methyl methacrylate copolymer, ethylene-propylene rubber, and ethylene-propylene-diene rubbers.
Claim 5
Dependent Claim 71 words
A flame-retardant olefinic resin composition according to claim 1, wherein the silane-grafted polymer is obtained by reacting an olefinic resin with an organic silane represented by the general formula RR'SiY 2 wherein R is a monovalent olefinically unsaturated hydrocarbon group; Y is a hydrolyzable organic group; and R' is a monovalent hydrocarbon group other than unsaturated aliphatic hydrocarbon groups or is same as Y, in the presence of a free-radical-generating compound.
Claim 6
Dependent Claim 36 words
A flame-retardant olefinic resin composition according to claim 1, wherein the silane-grafted polymer is incorporated in an amount of at least 2 parts by weight per 100 parts by weight of the components (a) and (b).
Claim 7
Dependent Claim 34 words
A flame-retardant olefinic resin composition according to claim 1, wherein the crosslinking degree of the silane-grafted polymer is 20-80% by weight in terms of a gel fraction which is defined as a xylene insoluble.
Claim 8
Dependent Claim 46 words
A flame-retardant olefinic resin composition according to claim 1, wherein the thermoplastic resin to which a reactive polyorganosiloxane is to be graft-polymerized, is selected from the group consisting of polyethylene, polypropylene, ethylene-α-olefin copolymers, ethylene-vinyl acetate copolymer, ethyleneethyl acrylate copolymer, ethylene-methyl methacrylate copolymer, polystyrene and acrylonitrile-butadienestyrene copolymer.
Claim 9
Dependent Claim 77 words
A flame-retardant olefinic resin composition according to claim 1, wherein the hydrated metal compound is a compound having a decomposition-starting temperature of 150°-450° C. and represented by the general formula M m O n .XH 2 O, wherein M is a metal; m and n are each an integer of 1 or more determined by the valency of the metal; and X is the number of molecules of bound water, or a double salt containing said compound
Claim 10
Dependent Claim 30 words
A flame-retardant olefinic resin composition according to claim 8, wherein the M is selected from the metals of groups IA, IIA, IIB, IIIA, IVA and IVB of the periodic table.
Claim 11
Dependent Claim 24 words
A flame-retardant olefinic resin composition according to claim 9, wherein the M is selected from the metals of group IIA of the periodic table.
Claim 12
Dependent Claim 24 words
A flame-retardant olefinic resin composition according to claim 9, wherein the M is selected from the metals of group IIIA of the periodic table.
Claim 13
Dependent Claim 18 words
A flame-retardant olefinic resin composition according to claim 8, wherein the hydrated metal compound is magnesium oxide monohydrate.
Claim 14
Dependent Claim 18 words
A flame-retardant olefinic resin composition according to claim 8, wherein the hydrated metal compound is aluminum oxide trihydrate.

References Cited (Backward Citations)

US4328323A Cited
US4722959A Cited
US4845146A Cited
US4732939A Cited
US4801639A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-03-25 1994-09-24 1995-03-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-03-25 1998-09-24 1999-03-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-03-25 2002-09-24 2003-03-26 $7700.00 Window Closed / Lapsed

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