US4994202A
Expired / Lapsed
US
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Azeotropic compositions of perfluoro-1,2-dimethylcyclobutane with 1,1-dichloro-1-fluoroethane or dichlorotrifluoroethane
Assignee: EIDP Inc
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Filing: 1990-03-12
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Granted: 1991-02-19
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Expires: 2010-03-12
Abstract
Abstract Azeotropic mixtures of perfluoro-dimethylcyclobutane with 1,1-dichloro-1-fluoroethane or dichlorotrifluoroethane, are useful in solvent cleaning applications, and as refrigerants, aerosol propellants and polymer blowing agents.
Inventors
- 👤 Abid N. Merchant
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 22:41
CPC Classifications
C; C11; C11D; C11D7/00; C11D7/50; C11D7/5036; C11D7/504; C11D7/5054; C08; C08J; C08J9/00; C08J9/04; C08J9/12; C08J9/14; C08J9/143; C09; C09K; C09K3/00; C09K3/30; C09K5/00; C09K5/02; C09K5/04; C09K5/041; C09K5/044; C09K5/045; C11D7/5045; C08J2207/00; C08J2207/04; C09K2205/00; C09K2205/10; C09K2205/12; C09K2205/122; C09K2205/124; C09K2205/128; C09K2205/32
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
36 words
An azeotropic composition, consisting essentially of about 50 to 60 weight percent perfluoro-1,2-dimethylcyclobutane and about 40-50 weight percent 1,1-dichloro-1-fluoroethane wherein the composition boils at about 26.7° C. when the pressure is adjusted to substantially atmospheric pressure.
Claim 2
Dependent Claim
36 words
An azeotropic composition, consisting essentially of about 50 to 60 weight percent perfluoro-1,2-dimethylcyclobutane and about 40-50 weight percent 1,1-dichloro-1-fluoroethane wherein the composition boils at about 26.7° C. when the pressure is adjusted to substantially atmospheric pressure.
Claim 3
Dependent Claim
57 words
An azeotropic composition, consisting essentially of about 23 to 33 weight percent perfluoro-1,2-dimethylcyclobutane and from about 67 to 77 weight percent dichlorotrifluoroethane wherein said dichlorotrifluoroethane is 1,1-dichloro-2,2,2,-trifluoroethane or 1,1-dichloro-2,2,2-trifluomethane which contains 1,2-dichloro-1,2,2-trifluoroethane in an amount up to 5 percent, and wherein the composition boils at about 27.0° C. when the pressure is adjusted to substantially atmospheric pressure.
Claim 4
Dependent Claim
57 words
An azeotropic composition, consisting essentially of about 23 to 33 weight percent perfluoro-1,2-dimethylcyclobutane and from about 67 to 77 weight percent dichlorotrifluoroethane wherein said dichlorotrifluoroethane is 1,1-dichloro-2,2,2,-trifluoroethane or 1,1-dichloro-2,2,2-trifluomethane which contains 1,2-dichloro-1,2,2-trifluoroethane in an amount up to 5 percent, and wherein the composition boils at about 27.0° C. when the pressure is adjusted to substantially atmospheric pressure.
Claim 5
Dependent Claim
23 words
The azeotropic composition of claim 2, wherein the composition consists essentially of about 54.5 weight percent perfluoro-1,2-dimethylcyclobutane and about 45.5 weight percent 1,1-dichloro-1-fluoroethane.
Claim 6
Dependent Claim
23 words
The azeotropic composition of claim 3, wherein the composition consists essentially of about 27.7 weight percent perfluoro-1,2-dimethylcyclobutane and about 72.3 weight percent dichlorotrifluoroethane.
Claim 7
Dependent Claim
23 words
The composition of claim 2, consisting essentially of about 52 to 57 weight percent perfluoro1,2-dimethylcyclobutane and about 43 to 48 weight percent 1,1-dichloro-1-fluoroethane.
Claim 8
Dependent Claim
24 words
The composition of claim 3, consisting essentially of about 25 to 30 weight percent perfluoro-1,2,-dimethylcyclobutane and from about 70 to 75 weight percent dichlorotrifluoroethane.
Claim 9
Dependent Claim
10 words
The composition of claim 2, consisting of perfluoro-1,2-dimethylcyclobutane and 1,1-dichloro-1-fluoroethane.
Claim 10
Dependent Claim
10 words
The composition of claim 3, consisting of perfluoro-1,2-dimethylcyclobutane and dichlorotrifluoroethane.
Claim 11
Dependent Claim
22 words
A process for cleaning a solid surface which comprises treating said surface with a azeotropic composition of claim 2 or claim 3.
Claim 12
Dependent Claim
19 words
The process of claim 9, wherein the solid surface is a printed circuit board contaminated with flux and flux-residues.
Claim 13
Dependent Claim
12 words
The process of claim 9, wherein the solid surface is a metal.
Claim 14
Dependent Claim
25 words
A process for producing refrigeration which comprises evaporating a mixture of claim 2 or claim 3 in the vicinity of a body to be cooled.
Claim 15
Dependent Claim
25 words
A process for producing heat which comprises condensing a composition of claim 2 or claim 3 in the vicinity of a body to be heated.
Claim 16
Dependent Claim
31 words
In a process for preparing a polymer foam comprising expanding a polymer with a blowing agent, the improvement wherein the blowing agent is a composition of claim 2 or claim 3.
Claim 17
Dependent Claim
25 words
In an aerosol composition comprising a propellant and an active agent, the improvement wherein the propellant is a composition of claim 2 or claim 3.
Claim 18
Dependent Claim
31 words
A process for preparing aerosol formulations comprising condensing an active ingredient in an aerosol container with an effective amount of the composition of claim 2 or claim 3 as a propellant.
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