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US4990479A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for polymerizing olefins and polymerization catalyst therefor

Assignee: Mitsui Chemicals Inc
•
Filing: 1989-06-15
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Granted: 1991-02-05
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Expires: 2009-06-15
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Abstract

Abstract An olefin polymerization catalyst formed from (A) a solid titanium catalyst component containing magnesium, titanium and halogen as essential ingredients, (B) an organoaluminum compound, and (C) an organosilicon compound containing a cyclopentyl group, a cyclopentenyl group, a cyclopentadienyl group or a derivative derived from any of these groups. A polymerization process which comprises polymerizing or copolymerizing olefins in the presence of the olefin polymerization catalyst to form a homopolyolefin having a high stereoregularity or a copolyolefin having a narrow composition distribution.

Inventors

  • 👤 Naoshi Ishimaru
  • 👤 Mamoru Kioka
  • 👤 Akinori Toyota

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 21:15
CPC Classifications
C; C08; C08F; C08F297/00; C08F297/06; C08F297/08; C08F10/00; Y; Y10; Y10S; Y10S526/00; Y10S526/904

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 260 words
An olefin polymerization catalyst formed from (A) a solid titanium component which contains magnesium, titanium, halogen and an electron donor as the essential components prepared by contacting of a magnesium compound with a titanium compound and an electron donor, said magnesium compound having been for a time in a liquid condition during preparation of said solid titanium component; (B) an organoaluminum compound; and (C) an organosilicon compound represented by the following formula SiR.sup.21 R.sup.22.sub.m (OR.sup.23).sub.3-m wherein R 21 represents a cyclopentyl group, a cyclopentyl group substituted by 1 to 4 alkyl groups having 1 to 4 carbon atoms, an alkyl group having 2 to 4 carbon atoms substituted by a cyclopentyl group or a cyclopentyl group substituted by 1 to 4 alkyl groups having 1 to 4 carbon atoms, a cyclopentenyl group, a cyclopentenyl group substituted by 1 to 4 alkyl groups having 1 to 4 carbon atoms, a cyclopentadienyl group, a cyclopentadienyl group substituted by 1 to 4 alkyl groups having 1 to 4 atoms, an indenyl group, an indenyl group substituted by 1 to 4 alkyl groups having 1 to 4 carbon atoms, an indanyl group, an indanyl group substituted by 1 to 4 alkyl groups having 1 to 4 carbon atoms, a tetrahydroindenyl group, a tetrahydroindenyl group substituted by 1 to 4 alkyl groups having 1 to 4 carbon atoms, a fluorenyl group or a fluorenyl group substituted by 1 to 4 alkyl groups having 1 to 4 carbon atoms; R 22 and R 23 are identical or different and each represents a hydrocarbon group; and 0≦m<3.
Claim 2
Dependent Claim 260 words
An olefin polymerization catalyst formed from (A) a solid titanium component which contains magnesium, titanium, halogen and an electron donor as the essential components prepared by contacting of a magnesium compound with a titanium compound and an electron donor, said magnesium compound having been for a time in a liquid condition during preparation of said solid titanium component; (B) an organoaluminum compound; and (C) an organosilicon compound represented by the following formula SiR.sup.21 R.sup.22.sub.m (OR.sup.23).sub.3-m wherein R 21 represents a cyclopentyl group, a cyclopentyl group substituted by 1 to 4 alkyl groups having 1 to 4 carbon atoms, an alkyl group having 2 to 4 carbon atoms substituted by a cyclopentyl group or a cyclopentyl group substituted by 1 to 4 alkyl groups having 1 to 4 carbon atoms, a cyclopentenyl group, a cyclopentenyl group substituted by 1 to 4 alkyl groups having 1 to 4 carbon atoms, a cyclopentadienyl group, a cyclopentadienyl group substituted by 1 to 4 alkyl groups having 1 to 4 atoms, an indenyl group, an indenyl group substituted by 1 to 4 alkyl groups having 1 to 4 carbon atoms, an indanyl group, an indanyl group substituted by 1 to 4 alkyl groups having 1 to 4 carbon atoms, a tetrahydroindenyl group, a tetrahydroindenyl group substituted by 1 to 4 alkyl groups having 1 to 4 carbon atoms, a fluorenyl group or a fluorenyl group substituted by 1 to 4 alkyl groups having 1 to 4 carbon atoms; R 22 and R 23 are identical or different and each represents a hydrocarbon group; and 0≦m<3.
Claim 3
Dependent Claim 46 words
The catalyst of claim 1 in which the solid titanium catalyst component (A) is obtained by using a titanium compound of the following formula Ti(OR).sub.g X.sub.4-g wherein R represents a hydrocarbon group, X represents a halogen atom and g is a number of 0 to 4.
Claim 4
Dependent Claim 24 words
The catalyst of claim 1 in which the organoaluminum compound (B) is an organoaluminum compound having at least one aluminum-carbon bond in the molecule.

References Cited (Backward Citations)

US4442276A Cited
US4659792A Cited
US4801672A Cited
US4816433A Cited

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