US4990479A
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Process for polymerizing olefins and polymerization catalyst therefor
Assignee: Mitsui Chemicals Inc
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Filing: 1989-06-15
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Granted: 1991-02-05
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Expires: 2009-06-15
Abstract
Abstract An olefin polymerization catalyst formed from (A) a solid titanium catalyst component containing magnesium, titanium and halogen as essential ingredients, (B) an organoaluminum compound, and (C) an organosilicon compound containing a cyclopentyl group, a cyclopentenyl group, a cyclopentadienyl group or a derivative derived from any of these groups. A polymerization process which comprises polymerizing or copolymerizing olefins in the presence of the olefin polymerization catalyst to form a homopolyolefin having a high stereoregularity or a copolyolefin having a narrow composition distribution.
Inventors
- 👤 Naoshi Ishimaru
- 👤 Mamoru Kioka
- 👤 Akinori Toyota
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 21:15
CPC Classifications
C; C08; C08F; C08F297/00; C08F297/06; C08F297/08; C08F10/00; Y; Y10; Y10S; Y10S526/00; Y10S526/904
Claims Analysis
Total Claims: 4
Claim 1
Independent Claim
260 words
An olefin polymerization catalyst formed from (A) a solid titanium component which contains magnesium, titanium, halogen and an electron donor as the essential components prepared by contacting of a magnesium compound with a titanium compound and an electron donor, said magnesium compound having been for a time in a liquid condition during preparation of said solid titanium component; (B) an organoaluminum compound; and (C) an organosilicon compound represented by the following formula SiR.sup.21 R.sup.22.sub.m (OR.sup.23).sub.3-m wherein R 21 represents a cyclopentyl group, a cyclopentyl group substituted by 1 to 4 alkyl groups having 1 to 4 carbon atoms, an alkyl group having 2 to 4 carbon atoms substituted by a cyclopentyl group or a cyclopentyl group substituted by 1 to 4 alkyl groups having 1 to 4 carbon atoms, a cyclopentenyl group, a cyclopentenyl group substituted by 1 to 4 alkyl groups having 1 to 4 carbon atoms, a cyclopentadienyl group, a cyclopentadienyl group substituted by 1 to 4 alkyl groups having 1 to 4 atoms, an indenyl group, an indenyl group substituted by 1 to 4 alkyl groups having 1 to 4 carbon atoms, an indanyl group, an indanyl group substituted by 1 to 4 alkyl groups having 1 to 4 carbon atoms, a tetrahydroindenyl group, a tetrahydroindenyl group substituted by 1 to 4 alkyl groups having 1 to 4 carbon atoms, a fluorenyl group or a fluorenyl group substituted by 1 to 4 alkyl groups having 1 to 4 carbon atoms; R 22 and R 23 are identical or different and each represents a hydrocarbon group; and 0≦m<3.
Claim 2
Dependent Claim
260 words
An olefin polymerization catalyst formed from (A) a solid titanium component which contains magnesium, titanium, halogen and an electron donor as the essential components prepared by contacting of a magnesium compound with a titanium compound and an electron donor, said magnesium compound having been for a time in a liquid condition during preparation of said solid titanium component; (B) an organoaluminum compound; and (C) an organosilicon compound represented by the following formula SiR.sup.21 R.sup.22.sub.m (OR.sup.23).sub.3-m wherein R 21 represents a cyclopentyl group, a cyclopentyl group substituted by 1 to 4 alkyl groups having 1 to 4 carbon atoms, an alkyl group having 2 to 4 carbon atoms substituted by a cyclopentyl group or a cyclopentyl group substituted by 1 to 4 alkyl groups having 1 to 4 carbon atoms, a cyclopentenyl group, a cyclopentenyl group substituted by 1 to 4 alkyl groups having 1 to 4 carbon atoms, a cyclopentadienyl group, a cyclopentadienyl group substituted by 1 to 4 alkyl groups having 1 to 4 atoms, an indenyl group, an indenyl group substituted by 1 to 4 alkyl groups having 1 to 4 carbon atoms, an indanyl group, an indanyl group substituted by 1 to 4 alkyl groups having 1 to 4 carbon atoms, a tetrahydroindenyl group, a tetrahydroindenyl group substituted by 1 to 4 alkyl groups having 1 to 4 carbon atoms, a fluorenyl group or a fluorenyl group substituted by 1 to 4 alkyl groups having 1 to 4 carbon atoms; R 22 and R 23 are identical or different and each represents a hydrocarbon group; and 0≦m<3.
Claim 3
Dependent Claim
46 words
The catalyst of claim 1 in which the solid titanium catalyst component (A) is obtained by using a titanium compound of the following formula Ti(OR).sub.g X.sub.4-g wherein R represents a hydrocarbon group, X represents a halogen atom and g is a number of 0 to 4.
Claim 4
Dependent Claim
24 words
The catalyst of claim 1 in which the organoaluminum compound (B) is an organoaluminum compound having at least one aluminum-carbon bond in the molecule.
References Cited (Backward Citations)
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| 3.5 Years (Year 4) | 1994-02-04 | 1994-08-06 | 1995-02-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1998-02-04 | 1998-08-06 | 1999-02-05 | $3760.00 | Window Closed / Lapsed |
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