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US4985526A Expired / Lapsed US ⏱️ 0.0 years remaining

Curable silicone composition

Assignee: Shin-Etsu Chemical Co Ltd
•
Filing: 1990-05-03
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Granted: 1991-01-15
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Expires: 2010-05-03
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Abstract

Abstract A curable silicone composition comprising; (a) an organopolysiloxane having at least two silicon-bonded C 2 to C 8 alkenyl groups and containing a particular silicon-bonded fluorine-containing substituent; (b) an organohydrogenpolysiloxane having at least three silicon-bonded hydrogen atoms and a particular silicon-bonded fluorine-containing substituent; and (c) a catalyst; the proportion of said silicon-bonded hydrogen atoms in Component (b) to said silicon-bonded alkenyl groups in Component (a) being at least 0.5. This composition can form a film, on various substrates, having good release properties, water repellency and oil repellency.

Inventors

  • 👤 Hirofumi Kishita
  • 👤 Kouichi Yamaguchi
  • 👤 Toshio Takago

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 10:28
CPC Classifications
C; C08; C08L; C08L83/00; C08L83/04; C08L83/08; C08G; C08G77/00; C08G77/04; C08G77/22; C08G77/24; C08L83/10; C08L83/12

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 239 words
A curable silicone composition, comprising: (a) an organopolysiloxane having in its molecule at least two silicon-bonded C 2 to C 8 alkenyl groups and containing in its molecule at least one substituent selected from the group consisting of silicon-bonded fluorine-containing substituents represented by Formulas (1) to (4) in an amount of 3 mole % or more of all of the silicon-bonded organic groups in the molecule: ##STR29## where n is an integer of 1 to 5, ##STR30## where n is an integer of 1 to 5, C.sub.m F.sub.2m+1 CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2 CH.sub.2 --(3) where m is an integer of 3 to 10, and C.sub.m F.sub.2m+1 CH.sub.2 OCH.sub.2 CH.sub.2 CH.sub.2 -- (4) where m is an integer of 3 to 10; (b) an organohydrogenpolysiloxane having in its molecule at least three silicon-bonded hydrogen atoms and containing in its molecule at least one substituent selected from the group consisting of silicon-bonded fluorine-containing substituents represented by said Formulas (1) to (4) and Formula (14): R.sup.5 CH.sub.2 CH.sub.2 -- (14) where R 5 represents a C 1 to C 8 perfluoroalkyl group in an amount of 3 mole % or more of all of the silicon-bonded organic groups in the molecule; and (c) a catalyst for promoting the addition reaction between said silicon-bonded alkenyl groups and said silicon-bonded hydrogen atoms; the proportion of said silicon-bonded hydrogen atoms in Component (b) to said silicon-bonded alkenyl groups in Component (a) being at least 0.5.
Claim 2
Dependent Claim 239 words
A curable silicone composition, comprising: (a) an organopolysiloxane having in its molecule at least two silicon-bonded C 2 to C 8 alkenyl groups and containing in its molecule at least one substituent selected from the group consisting of silicon-bonded fluorine-containing substituents represented by Formulas (1) to (4) in an amount of 3 mole % or more of all of the silicon-bonded organic groups in the molecule: ##STR29## where n is an integer of 1 to 5, ##STR30## where n is an integer of 1 to 5, C.sub.m F.sub.2m+1 CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2 CH.sub.2 --(3) where m is an integer of 3 to 10, and C.sub.m F.sub.2m+1 CH.sub.2 OCH.sub.2 CH.sub.2 CH.sub.2 -- (4) where m is an integer of 3 to 10; (b) an organohydrogenpolysiloxane having in its molecule at least three silicon-bonded hydrogen atoms and containing in its molecule at least one substituent selected from the group consisting of silicon-bonded fluorine-containing substituents represented by said Formulas (1) to (4) and Formula (14): R.sup.5 CH.sub.2 CH.sub.2 -- (14) where R 5 represents a C 1 to C 8 perfluoroalkyl group in an amount of 3 mole % or more of all of the silicon-bonded organic groups in the molecule; and (c) a catalyst for promoting the addition reaction between said silicon-bonded alkenyl groups and said silicon-bonded hydrogen atoms; the proportion of said silicon-bonded hydrogen atoms in Component (b) to said silicon-bonded alkenyl groups in Component (a) being at least 0.5.
Claim 3
Dependent Claim 89 words
The composition according to claim 1, wherein said Component (a) is represented by Formula (5): ##STR31## wherein R 1 represents a C 2 to C 8 alkenyl group; R 2 may be the same or different and represents a C 1 to C 8 alkyl group or a phenyl group; Rf represents at least one selected from the fluorine-containing substituents represented by the above Formulas (1) to (4); a is an integer of from 1 to 3; and x, y and z are integers of x≧0, Y≧1and z≧0, respectively.
Claim 4
Dependent Claim 31 words
The composition according to claim 2, wherein said component (a) is represented by Formula (6): ##STR32## wherein R 2 , Rf, x, y and z are as defined in Formula (5).
Claim 5
Dependent Claim 127 words
The composition according to claim 1, wherein said Component (b) is represented by Formula (13): ##STR33## wherein R 3 may be the same or different and represent a hydrogen atom, a C 1 to C 8 alkyl group or a phenyl group; R 4 may be the same or different and represent a C 1 to C 8 alkyl group, a phenyl group, or at least one substituent selected from the group consisting of the fluorine-containing containing substituents of the above Formulas (1) to (4) and said Formula (14); and x is an integer of 1 or more, and y is an integer of 0 or more, provided that x is a number that makes the number of the silicon-bonded hydrogen atoms come to 3 or more.
Claim 6
Dependent Claim 29 words
The composition according to claim 1, wherein the proportion of said silicon-bonded hydrogen atoms in Component (b) to said silicon-bonded alkenyl groups in Component (a) is 0.5:1 to 10:1.
Claim 7
Dependent Claim 14 words
The composition according to claim 1, wherein said Component (c) is a platinum catalyst.
Claim 8
Dependent Claim 37 words
The composition according to claim 6, wherein the amount of said catalyst of the component (c) ranges from 1 to 1,000 ppm in terms of platinum based on the total weight of Component (a) and Component (b).

References Cited (Backward Citations)

US3012006A Cited
GB2096631A Cited
US4585848A Cited
US4549004A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-01-14 1994-07-16 1995-01-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-01-14 1998-07-16 1999-01-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-01-14 2002-07-16 2003-01-15 $7700.00 Window Closed / Lapsed

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