US4985526A
Expired / Lapsed
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Curable silicone composition
Assignee: Shin-Etsu Chemical Co Ltd
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Filing: 1990-05-03
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Granted: 1991-01-15
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Expires: 2010-05-03
Abstract
Abstract A curable silicone composition comprising; (a) an organopolysiloxane having at least two silicon-bonded C 2 to C 8 alkenyl groups and containing a particular silicon-bonded fluorine-containing substituent; (b) an organohydrogenpolysiloxane having at least three silicon-bonded hydrogen atoms and a particular silicon-bonded fluorine-containing substituent; and (c) a catalyst; the proportion of said silicon-bonded hydrogen atoms in Component (b) to said silicon-bonded alkenyl groups in Component (a) being at least 0.5. This composition can form a film, on various substrates, having good release properties, water repellency and oil repellency.
Inventors
- 👤 Hirofumi Kishita
- 👤 Kouichi Yamaguchi
- 👤 Toshio Takago
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 10:28
CPC Classifications
C; C08; C08L; C08L83/00; C08L83/04; C08L83/08; C08G; C08G77/00; C08G77/04; C08G77/22; C08G77/24; C08L83/10; C08L83/12
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
239 words
A curable silicone composition, comprising: (a) an organopolysiloxane having in its molecule at least two silicon-bonded C 2 to C 8 alkenyl groups and containing in its molecule at least one substituent selected from the group consisting of silicon-bonded fluorine-containing substituents represented by Formulas (1) to (4) in an amount of 3 mole % or more of all of the silicon-bonded organic groups in the molecule: ##STR29## where n is an integer of 1 to 5, ##STR30## where n is an integer of 1 to 5, C.sub.m F.sub.2m+1 CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2 CH.sub.2 --(3) where m is an integer of 3 to 10, and C.sub.m F.sub.2m+1 CH.sub.2 OCH.sub.2 CH.sub.2 CH.sub.2 -- (4) where m is an integer of 3 to 10; (b) an organohydrogenpolysiloxane having in its molecule at least three silicon-bonded hydrogen atoms and containing in its molecule at least one substituent selected from the group consisting of silicon-bonded fluorine-containing substituents represented by said Formulas (1) to (4) and Formula (14): R.sup.5 CH.sub.2 CH.sub.2 -- (14) where R 5 represents a C 1 to C 8 perfluoroalkyl group in an amount of 3 mole % or more of all of the silicon-bonded organic groups in the molecule; and (c) a catalyst for promoting the addition reaction between said silicon-bonded alkenyl groups and said silicon-bonded hydrogen atoms; the proportion of said silicon-bonded hydrogen atoms in Component (b) to said silicon-bonded alkenyl groups in Component (a) being at least 0.5.
Claim 2
Dependent Claim
239 words
A curable silicone composition, comprising: (a) an organopolysiloxane having in its molecule at least two silicon-bonded C 2 to C 8 alkenyl groups and containing in its molecule at least one substituent selected from the group consisting of silicon-bonded fluorine-containing substituents represented by Formulas (1) to (4) in an amount of 3 mole % or more of all of the silicon-bonded organic groups in the molecule: ##STR29## where n is an integer of 1 to 5, ##STR30## where n is an integer of 1 to 5, C.sub.m F.sub.2m+1 CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2 CH.sub.2 --(3) where m is an integer of 3 to 10, and C.sub.m F.sub.2m+1 CH.sub.2 OCH.sub.2 CH.sub.2 CH.sub.2 -- (4) where m is an integer of 3 to 10; (b) an organohydrogenpolysiloxane having in its molecule at least three silicon-bonded hydrogen atoms and containing in its molecule at least one substituent selected from the group consisting of silicon-bonded fluorine-containing substituents represented by said Formulas (1) to (4) and Formula (14): R.sup.5 CH.sub.2 CH.sub.2 -- (14) where R 5 represents a C 1 to C 8 perfluoroalkyl group in an amount of 3 mole % or more of all of the silicon-bonded organic groups in the molecule; and (c) a catalyst for promoting the addition reaction between said silicon-bonded alkenyl groups and said silicon-bonded hydrogen atoms; the proportion of said silicon-bonded hydrogen atoms in Component (b) to said silicon-bonded alkenyl groups in Component (a) being at least 0.5.
Claim 3
Dependent Claim
89 words
The composition according to claim 1, wherein said Component (a) is represented by Formula (5): ##STR31## wherein R 1 represents a C 2 to C 8 alkenyl group; R 2 may be the same or different and represents a C 1 to C 8 alkyl group or a phenyl group; Rf represents at least one selected from the fluorine-containing substituents represented by the above Formulas (1) to (4); a is an integer of from 1 to 3; and x, y and z are integers of x≧0, Y≧1and z≧0, respectively.
Claim 4
Dependent Claim
31 words
The composition according to claim 2, wherein said component (a) is represented by Formula (6): ##STR32## wherein R 2 , Rf, x, y and z are as defined in Formula (5).
Claim 5
Dependent Claim
127 words
The composition according to claim 1, wherein said Component (b) is represented by Formula (13): ##STR33## wherein R 3 may be the same or different and represent a hydrogen atom, a C 1 to C 8 alkyl group or a phenyl group; R 4 may be the same or different and represent a C 1 to C 8 alkyl group, a phenyl group, or at least one substituent selected from the group consisting of the fluorine-containing containing substituents of the above Formulas (1) to (4) and said Formula (14); and x is an integer of 1 or more, and y is an integer of 0 or more, provided that x is a number that makes the number of the silicon-bonded hydrogen atoms come to 3 or more.
Claim 6
Dependent Claim
29 words
The composition according to claim 1, wherein the proportion of said silicon-bonded hydrogen atoms in Component (b) to said silicon-bonded alkenyl groups in Component (a) is 0.5:1 to 10:1.
Claim 7
Dependent Claim
14 words
The composition according to claim 1, wherein said Component (c) is a platinum catalyst.
Claim 8
Dependent Claim
37 words
The composition according to claim 6, wherein the amount of said catalyst of the component (c) ranges from 1 to 1,000 ppm in terms of platinum based on the total weight of Component (a) and Component (b).
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1994-01-14 | 1994-07-16 | 1995-01-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1998-01-14 | 1998-07-16 | 1999-01-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2002-01-14 | 2002-07-16 | 2003-01-15 | $7700.00 | Window Closed / Lapsed |