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US4983494A Expired / Lapsed US ⏱️ 0.0 years remaining

Image forming process including heating step

Assignee: Fujifilm Corp
•
Filing: 1989-10-18
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Granted: 1991-01-08
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Expires: 2009-10-18
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Abstract

Abstract An image is formed in a photographic element by a process comprising a step of heating a heat-developable photosensitive material in the presence of a specific compound which typically releases a phenylmercaptotetrazole having a substituted benzene ring and serving as a development retarder.

Inventors

  • 👤 Hiroshi Kitaguchi
  • 👤 Masatoshi Kato

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 23:32
CPC Classifications
G; G03; G03C; G03C7/00; G03C7/30; G03C7/305; G03C7/30511; G03C1/00; G03C1/494; G03C1/498; G03C1/49836; G03C1/49845; Y; Y10; Y10S; Y10S430/00; Y10S430/156; Y10S430/158; Y10S430/161

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 445 words
A process for forming an image comprising a step of heating a heat-developable photosensitive material containing a silver halide in the presence of a compound selected from the group consisting of compounds of general formula (I-II): ##STR51## wherein Z represents a group of nonmetallic atoms necessary to complete a phenyltetrazole ring in which the phenyl radical has attached thereto a substituent selected from the group consisting of: ##STR52## wherein R' is a substituted or unsubstituted alkyl radical having 3 to 20 carbon atoms or a substituted or unsubstituted aryl radical, and R" is a hydrogen atom or a radical as defined for R', L 1 is a valence bond or a substituted or unsubstituted divalent radical, p and q each are an integer of 1 or 2, and n is an integer of 0 or 1; compounds of general formula (II--II): ##STR53## wherein Z represents a group of nonmetallic atoms necessary to complete a phenyltetrazole ring in which the phenyl radical has attached thereto a substituent selected from the group consisting of: ##STR54## wherein R' is a substituted or unsubstituted alkyl radical having 3 to 20 carbon atoms or a substituted or unsubstituted aryl radical, and R" is a hydrogen atom or a radical as defined for R', R 1 and R 2 may be the same or different and are individually selected from a hydrogen atom and an alkyl radical having 1 to 4 carbon atoms, s and t each are an integer of 0 to 3 and may be the same or different, X 1 and X 2 may be the same or different and individually selected from an ester linkage, a substituted or unsubstituted amide linkage, and an ether linkage, L 2 is selected from an alkylene, phenylene, and xylylene radical, when X 1 and X 2 are amide linkages, the substituents on the nitrogen may be bonded to form a heterocyclic ring together with parts of L 2 , X 1 , and X 2 , and m and r each are an integer of 0 or 1; and compounds of general formula (III-I): ##STR55## wherein u is an integer of 1 or 2, R 5 represents a substituted or unsubstituted alkyl, cycloalkyl, aralkyl, or phenyul radical when u is 1, and R 5 represents a substituted or unsubstituted phenylene or alkylene radical when u is 2, R 6 represents a substituted or unsubstituted alkyl having at least 3 carbon atoms or a cycloalky1 radical, and --(L)13 represents a valence bond or ##STR56## wherein R 7 is selected from a hydrogen atom and the radicals defined for R 6 and may be the same as or different from R 6 .
Claim 2
Dependent Claim 445 words
A process for forming an image comprising a step of heating a heat-developable photosensitive material containing a silver halide in the presence of a compound selected from the group consisting of compounds of general formula (I-II): ##STR51## wherein Z represents a group of nonmetallic atoms necessary to complete a phenyltetrazole ring in which the phenyl radical has attached thereto a substituent selected from the group consisting of: ##STR52## wherein R' is a substituted or unsubstituted alkyl radical having 3 to 20 carbon atoms or a substituted or unsubstituted aryl radical, and R" is a hydrogen atom or a radical as defined for R', L 1 is a valence bond or a substituted or unsubstituted divalent radical, p and q each are an integer of 1 or 2, and n is an integer of 0 or 1; compounds of general formula (II--II): ##STR53## wherein Z represents a group of nonmetallic atoms necessary to complete a phenyltetrazole ring in which the phenyl radical has attached thereto a substituent selected from the group consisting of: ##STR54## wherein R' is a substituted or unsubstituted alkyl radical having 3 to 20 carbon atoms or a substituted or unsubstituted aryl radical, and R" is a hydrogen atom or a radical as defined for R', R 1 and R 2 may be the same or different and are individually selected from a hydrogen atom and an alkyl radical having 1 to 4 carbon atoms, s and t each are an integer of 0 to 3 and may be the same or different, X 1 and X 2 may be the same or different and individually selected from an ester linkage, a substituted or unsubstituted amide linkage, and an ether linkage, L 2 is selected from an alkylene, phenylene, and xylylene radical, when X 1 and X 2 are amide linkages, the substituents on the nitrogen may be bonded to form a heterocyclic ring together with parts of L 2 , X 1 , and X 2 , and m and r each are an integer of 0 or 1; and compounds of general formula (III-I): ##STR55## wherein u is an integer of 1 or 2, R 5 represents a substituted or unsubstituted alkyl, cycloalkyl, aralkyl, or phenyul radical when u is 1, and R 5 represents a substituted or unsubstituted phenylene or alkylene radical when u is 2, R 6 represents a substituted or unsubstituted alkyl having at least 3 carbon atoms or a cycloalky1 radical, and --(L)13 represents a valence bond or ##STR56## wherein R 7 is selected from a hydrogen atom and the radicals defined for R 6 and may be the same as or different from R 6 .
Claim 3
Dependent Claim 38 words
The image forming process of claim 1 wherein the heat-developable photosensitive material further comprises a dye-providing substance which produces or releases a mobile dye in proportion or counter-proportion to the reducing reaction of the silver halide to silver.
Claim 4
Dependent Claim 16 words
The image forming process of claim 1 wherein said compound is of the general formula (I-II).
Claim 5
Dependent Claim 16 words
The image forming process of claim 1, wherein said compound is of the general formula (II--II).
Claim 6
Dependent Claim 16 words
The image forming process of claim 1, wherein said compound is of the general formula (III-I).

References Cited (Backward Citations)

US4562138A Cited
US4472493A Cited
US4584257A Cited
US4612277A Cited
US4678735A Cited
US4639408A Cited
US4677051A Cited
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